Heptacyclo[14.11.1.02,15.04,13.06,11.018,23.024,28]octacosa-1(27),2,4(13),6,8,10,14,16,18,20,22,24(28),25-tridecaene-5,12-dione | 1228304-84-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Heptacyclo[14.11.1.02,15.04,13.06,11.018,23.024,28]octacosa-1(27),2,4(13),6,8,10,14,16,18,20,22,24(28),25-tridecaene-5,12-dione
• CAS: 1228304-84-4
• 化学式: C₂₈H₁₄O₂
• 分子量: 382.418
• InChiKey: NQJUQSCFLWQFRJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Heptacyclo[14.11.1.02,15.04,13.06,11.018,23.024,28]octacosa-1(27),2,4(13),6,8,10,14,16,18,20,22,24(28),25-tridecaene-5,12-dione 、 苯基锂 在 水 作用下， 以 四氢呋喃 为溶剂， 以45%的产率得到5,12-Diphenylheptacyclo[14.11.1.02,15.04,13.06,11.018,23.024,28]octacosa-1(27),2,4(13),6,8,10,14,16,18,20,22,24(28),25-tridecaene-5,12-diol
  参考文献：
  名称：

  [EN] NOVEL FUSED POLYCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING ELEMENT
  [FR] NOUVEAU COMPOSÉ POLYCYCLIQUE FUSIONNÉ ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE

  摘要：

  一个融合的多环化合物由通式[1]表示：[Chem. 1]其中R1到R16中至少有一个选自卤素原子、具有1至20个碳原子的烷基基团、取代氨基团、可能具有取代基的芳基团和可能具有取代基的杂环基团。有机发光元件包括该融合的多环化合物。

  公开号：

  WO2010061952A1
• 作为产物：
  描述：

  2-Bromo-3-phenanthren-9-ylanthracene-9,10-dione 在 bis-triphenylphosphine-palladium(II) chloride 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以60%的产率得到Heptacyclo[14.11.1.02,15.04,13.06,11.018,23.024,28]octacosa-1(27),2,4(13),6,8,10,14,16,18,20,22,24(28),25-tridecaene-5,12-dione
  参考文献：
  名称：

  [EN] NOVEL FUSED POLYCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING ELEMENT
  [FR] NOUVEAU COMPOSÉ POLYCYCLIQUE FUSIONNÉ ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE

  摘要：

  一个融合的多环化合物由通式[1]表示：[Chem. 1]其中R1到R16中至少有一个选自卤素原子、具有1至20个碳原子的烷基基团、取代氨基团、可能具有取代基的芳基团和可能具有取代基的杂环基团。有机发光元件包括该融合的多环化合物。

  公开号：

  WO2010061952A1

文献信息

• NOVEL FUSED POLYCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING ELEMENT
  申请人：Hashimoto Masashi

  公开号：US20110260151A1

  公开（公告）日：2011-10-27

  A fused polycyclic compound is represented by general formula [1]: wherein at least one of R 1 to R 16 is selected from a halogen atom, an alkyl group having 1 to 20 carbon atoms, a substituted amino group, an aryl group which may have a substituent, and a heterocyclic group which may have a substituent. An organic light-emitting element includes the fused polycyclic compound.
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Tomono Hiroyuki

  公开号：US20120168737A1

  公开（公告）日：2012-07-05

  An organic light-emitting device includes an anode, a cathode, and an organic compound layer including at least a light-emitting sublayer and being arranged between the anode and the cathode, the light-emitting sublayer containing a host serving as a main component, a first dopant, and a second dopant, in which for the host, the first dopant, and the second dopant, the following relationships (a) to (c) hold, whereby only the second dopant emits light: (a) first maximum emission wavelength (H)
• US8642191B2
  申请人：——

  公开号：US8642191B2

  公开（公告）日：2014-02-04
• US8921834B2
  申请人：——

  公开号：US8921834B2

  公开（公告）日：2014-12-30
• [EN] ORGANIC LIGHT-EMITTING DEVICE<br/>[FR] DISPOSITIF LUMINESCENT ORGANIQUE
  申请人：CANON KK

  公开号：WO2011036868A1

  公开（公告）日：2011-03-31

  An organic light-emitting device includes an anode, a cathode, and an organic compound layer including at least a light-emitting sublayer and being arranged between the anode and the cathode, the light-emitting sublayer containing a host serving as a main component, a first dopant, and a second dopant, in which for the host, the first dopant, and the second dopant, the following relationships (a) to (c) hold, whereby only the second dopant emits light: (a) first maximum emission wavelength (H) < first maximum emission wavelength (D1) < first maximum emission wavelength (D2), (b) LUMO (D2) < LUMO (D1) < LUMO (H), and (c) HOMO (D2) is equal to or lower than HOMO (H) < HOMO (D1).