Propane, 1,1,1,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoropropoxy)- | 25352-92-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Propane, 1,1,1,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoropropoxy)-
• 英文别名: 1,1,1,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoropropoxy)propane
• CAS: 25352-92-5
• 化学式: C₆H₂F₁₂O
• 分子量: 318.062
• InChiKey: CWWALFPKUNDCES-UHFFFAOYSA-N

物化性质

• 沸点：
  86.7±40.0 °C(Predicted)
• 密度：
  1.588±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  六氟丙烯 、 六氟异丙醇 在 四(三苯基膦)钯 作用下， 以 乙腈 为溶剂， 反应 46.0h， 以100%的产率得到Propane, 1,1,1,3,3,3-hexafluoro-2-(1,1,2,3,3,3-hexafluoropropoxy)-
  参考文献：
  名称：

  钯（0）催化的六氟丙烯加氢烷氧基化：在中性条件下合成氢氟醚。

  摘要：

  DOI：

  10.1002/anie.200462200

文献信息

• METHOD FOR PRODUCING FLUORINE-CONTAINING CARBOXYLIC ACID ESTER
  申请人：Central Glass Company, Limited

  公开号：EP2161249A1

  公开（公告）日：2010-03-10

  [Task] It is to provide a production method that the target fluorine-containing carboxylic acid ester can be obtained from a fluorine-containing ether by a one-step reaction, that a complicated step and a troublesome operation are not necessary, and that an excessive energy is not consumed. [Solving Means] A fluorine-containing carboxylic acid ester represented by the general formula R1HCFCOOR2 is produced by reacting a fluorine-containing ether represented by the general formula R1HCFCF2OR2 (R1 represents either of a fluorine atom and a C1-4 perfluoroalkyl group, and R2 represents a monovalent organic group) with water in the presence of a solid catalyst.

  [任务]提供一种生产方法，它可以通过一步反应从含氟醚中获得目标含氟羧酸酯，不需要复杂的步骤和麻烦的操作，也不会消耗过多的能量。 [解决方法]通式 R1HCFCOOR2 所代表的含氟羧酸酯是由通式 R1HCFCF2OR2 所代表的含氟醚（R1 代表氟原子和 C1-4 全氟烷基中的任一个，R2 代表一价有机基团）在固体催化剂存在下与水反应制得的。
• Method for Producing Fluorine-Containing Carboxylic Acid Ester
  申请人：Kondo Takeshi

  公开号：US20100197957A1

  公开（公告）日：2010-08-05

  [Task] It is to provide a production method that the target fluorine-containing carboxylic acid ester can be obtained from a fluorine-containing ether by a one-step reaction, that a complicated step and a troublesome operation are not necessary, and that an excessive energy is not consumed. [Solving Means] A fluorine-containing carboxylic acid ester represented by the general formula R 1 HCFCOOR 2 is produced by reacting a fluorine-containing ether represented by the general formula R 1 HCFCF 2 OR 2 (R 1 represents either of a fluorine atom and a C 1-4 perfluoroalkyl group, and R 2 represents a monovalent organic group) with water in the presence of a solid catalyst.
• US8039665B2
  申请人：——

  公开号：US8039665B2

  公开（公告）日：2011-10-18