1,2-bis(1,3,2-dithiaphospholan-2-ylithiolo)ethane | 4824-97-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1,2-bis(1,3,2-dithiaphospholan-2-ylithiolo)ethane
• 英文别名: S,S'-bis-(1,3,2-dithiaphospholane)-1,2-ethanedithiol；1,2-bis(1,3,2-dithiaphospholan-2-ylthio)ethane；2,2'-(ethylenedithio)bis(1,3,2-dithiaphospholane)；Ethylenbis-(ethylenphosphortrithioit)；1.2-Bis-<1.3-dithia-2-phospha-cyclopent-2-ylthio>-aethan；2,2'-ethane-1,2-diylbissulfanyl-bis-[1,3,2]dithiaphospholane；1,2-bis-([1,3,2]dithiaphospholan-2-ylmercapto)-ethane；2,2'-(Ethylenedithio)bis-1,3-dithia-2-phospholan；2,2'-(Ethylendothio)bis-1,3,2-dithiaphospholan；1,2-Bis-([1,3,2]dithiaphospholan-2-ylmercapto)-aethan；Triaethylen-bis-trithiophosphit；2,3,2-Dithiaphospholane；2-[2-(1,3,2-dithiaphospholan-2-ylsulfanyl)ethylsulfanyl]-1,3,2-dithiaphospholane
• CAS: 4824-97-9
• 化学式: C₆H₁₂P₂S₆
• 分子量: 338.505
• InChiKey: WJGGOYKBLGLCAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  152
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 1,2-bis(1,3,2-dithiaphospholan-2-ylithiolo)ethane 以 四氢呋喃 为溶剂， 以96%的产率得到dichloro(μ-[1,2-bis(1,3,2-dithiaphospholan-2-ylthio)ethane])gold(I)
  参考文献：
  名称：

  The preparation, properties and X-ray structures of gold(I) trithiophosphite complexes

  摘要：

  The first gold(I) trithiophosphite complexes were synthesised and fully characterised. Reaction of (tht)AuX (X = Cl, C6F5; tht = tetrahydrothiophene) with trithiophosphites (RS)(3)P (R = Me, Ph) and the bicyclic [(SCH2CH2S)PSCH2](2) (L-2) afforded the corresponding molecular complexes (RS)(3)PAuX [R = Me, X = Cl (1); R = Me, X = C6F5 (2); R = Ph, X = Cl (3); R = Ph, X = C6F5 (4)], and L-2(AuX)(2) [X = Cl (5), X = C6F5 (6)]. Reacting (tht)AuCl consecutively with two mole equivalents of (MeS)(3)P and then AgOTf, gave the ionic compound {[(MeS)(3)P](2)Au}OTf (7). The compounds were characterised by multinuclear NMR spectroscopy, IR measurements and mass spectrometry, and the crystal and molecular structures of 1, 3, 6, two polymorphs of 2 as well as the known (MeO)(3)PAuCl (8) were determined by X-ray diffraction. The halide complexes 1 and 8 are isostructural and exhibit infinite chains of "crossed-sword"-type aurophilic interactions with Au center dot center dot center dot Au contact distances of 3.2942(3) and 3.1635(4) angstrom, respectively. Complex 6 exhibits a long Au center dot center dot center dot Au contact of 3.4671(9) angstrom. Au center dot center dot center dot S interactions between 3.3455(7) and 3.520(2) angstrom are present in the structures of 1 and one polymorph of 2. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.07.034
• 作为产物：
  描述：

  1,2-乙二硫醇 在 三氯化磷 作用下， 反应 1.0h， 以97%的产率得到1,2-bis(1,3,2-dithiaphospholan-2-ylithiolo)ethane
  参考文献：
  名称：

  Lima, Luiz Carlos Gomez de; Lima, Miriam Bernardes Gomes de; Matos, Robson Mendes, Phosphorus, Sulfur and Silicon and the Related Elements, 2000, vol. 166, p. 1 - 14

  摘要：

  DOI：

文献信息

• Nifant'ev, E. E.; Chechetkin, A. S.; Blagoveshchenskii, V. S., Journal of general chemistry of the USSR, 1983, vol. 53, # 12, p. 2429 - 2431
  作者：Nifant'ev, E. E.、Chechetkin, A. S.、Blagoveshchenskii, V. S.、Sokurenko, A. M.

  DOI：——

  日期：——
• Goncalves,H. et al., Bulletin de la Societe Chimique de France, 1975, p. 621 - 627
  作者：Goncalves,H. et al.

  DOI：——

  日期：——
• Akhmetkhanova, F. M.; Proskurnina, M. V.; Zlot-skii, S. S., Journal of general chemistry of the USSR, 1987, vol. 57, p. 204
  作者：Akhmetkhanova, F. M.、Proskurnina, M. V.、Zlot-skii, S. S.、Rakhmankulov, D. L.

  DOI：——

  日期：——
• Nifant'ev,E.E. et al., Journal of general chemistry of the USSR, 1976, vol. 46, p. 469 - 474
  作者：Nifant'ev,E.E. et al.

  DOI：——

  日期：——
• Arbusow; Soroastrowa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1952, p. 453,456;engl.Ausg.S.437
  作者：Arbusow、Soroastrowa

  DOI：——

  日期：——