di[(1-chloro-2,2-bis(indol-1-ylmethyl))propoxy]diphenylsilane | 1314235-55-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: di[(1-chloro-2,2-bis(indol-1-ylmethyl))propoxy]diphenylsilane
• 英文别名: Bis[2-(chloromethyl)-3-indol-1-yl-2-(indol-1-ylmethyl)propoxy]-diphenylsilane；bis[2-(chloromethyl)-3-indol-1-yl-2-(indol-1-ylmethyl)propoxy]-diphenylsilane
• CAS: 1314235-55-6
• 化学式: C₅₄H₅₀Cl₂N₄O₂Si
• 分子量: 886.008
• InChiKey: KLBIKAVJLCDJFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.35
• 重原子数：
  63
• 可旋转键数：
  18
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  38.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,3-bis(indol-1-ylmethyl)oxetane 、 二苯二氯硅烷 在 四丁基溴化铵 作用下， 以 四氢呋喃 为溶剂， 反应 24.5h， 以32%的产率得到di[(1-chloro-2,2-bis(indol-1-ylmethyl))propoxy]diphenylsilane
  参考文献：
  名称：

  Branched diphenylsilane derivatives containing electronically isolated indolyl moieties as host materials for blue organic light emitting diodes

  摘要：

  Branched diphenylsilane derivatives with pendent indolyl fragments were synthesized and characterized. The compounds show high thermal stability with thermal decomposition starting at temperatures above 367 degrees C and ability to form glasses with glass-transition temperatures of 53-58 degrees C. The electron photoemission spectra of the layers of the synthesized compounds showed ionization potentials of ca. 5.85 eV. The derivatives were tested as host materials in phosphorescent OLEDs with iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N.C2']picolinate as the guest. The device with the host derivative containing four electronically isolated indolyl fragments exhibited the best overall performance with maximum current efficiency of about 12 cd/A. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.03.020

文献信息

• Branched diphenylsilane derivatives containing electronically isolated indolyl moieties as host materials for blue organic light emitting diodes
  作者：R. Zostautiene、G. Krucaite、J. Simokaitiene、J.V. Grazulevicius、Y.M. Lai、W.B. Wang、J.H. Jou、S. Grigalevicius

  DOI：10.1016/j.dyepig.2011.03.020

  日期：2011.11

  Branched diphenylsilane derivatives with pendent indolyl fragments were synthesized and characterized. The compounds show high thermal stability with thermal decomposition starting at temperatures above 367 degrees C and ability to form glasses with glass-transition temperatures of 53-58 degrees C. The electron photoemission spectra of the layers of the synthesized compounds showed ionization potentials of ca. 5.85 eV. The derivatives were tested as host materials in phosphorescent OLEDs with iridium(III)[bis(4,6-difluorophenyl)-pyridinato-N.C2']picolinate as the guest. The device with the host derivative containing four electronically isolated indolyl fragments exhibited the best overall performance with maximum current efficiency of about 12 cd/A. (C) 2011 Elsevier Ltd. All rights reserved.