2-(trifluoro methyl) 1,1,1,2-tetrafluoro 3-hydroxy pentane | 680-04-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: 2-(trifluoro methyl) 1,1,1,2-tetrafluoro 3-hydroxy pentane
• 英文别名: 1,1,1,2-tetrafluoro-2-trifluoromethyl-pentan-3-ol；1,1,1,2-Tetrafluor-2-trifluormethyl-pentanol-(3)；1,1,1,2-Tetrafluoro-2-(trifluoromethyl)-3-pentanol；1,1,1,2-tetrafluoro-2-(trifluoromethyl)pentan-3-ol
• CAS: 680-04-6
• 化学式: C₆H₇F₇O
• 分子量: 228.11
• InChiKey: PQCDHXNEFDPCGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  七氟-2-碘代丙烷 、 丙醛 生成 2-(trifluoro methyl) 1,1,1,2-tetrafluoro 3-hydroxy pentane
  参考文献：
  名称：

  372.由七氟-2-碘丙烷制得的有机金属和准金属化合物及其性质

  摘要：

  DOI：

  10.1039/jr9620001993

文献信息

• Processes for production and purification of hydrofluoroolefins
  申请人：Miller Newton Ralph

  公开号：US20060106263A1

  公开（公告）日：2006-05-18

  Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文公开了通过脱氟制备氢氟烯的工艺。本文还公开了从氢氟碳和氟化氢中分离氢氟烯的工艺。
• Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
  申请人：E. I. du Pont de Nemours and Company

  公开号：US07897823B2

  公开（公告）日：2011-03-01

  Disclosed herein is a process to produce an azeotrope composition comprising a hydrofluoroolefin and hydrogen fluoride, said process comprising, dehydrofluorinating a hydrofluorocarbon containing at least one hydrogen and at least one fluorine on adjacent carbons, thereby forming a mixture comprising said hydrofluoroolefin, unreacted hydrofluorocarbon and hydrogen fluoride, and distilling the mixture to produce a distillate composition comprising an azeotrope composition containing said hydrofluoroolefin and hydrogen fluoride and a column bottoms composition comprising said hydrofluorocarbon essentially free of hydrogen fluoride. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文公开了一种生产含有氢氟烯和氟化氢的共沸组成物的方法，该方法包括：脱氟化至少含有一个相邻碳上的氢和至少一个氟的氢氟碳化物，从而形成包括所述氢氟烯、未反应的氢氟碳化物和氟化氢的混合物，并蒸馏该混合物以产生包含所述氢氟烯和氟化氢的共沸组成物的馏分组成物和包含基本不含氟化氢的所述氢氟碳化物的柱底组成物。本文还公开了从氢氟碳化物和氟化氢中分离氢氟烯的方法。
• PROCESSES FOR PRODUCTION AND PURIFICATION OF HYDROFLUOROOLEFINS
  申请人：MILLER RALPH NEWTON

  公开号：US20110118512A1

  公开（公告）日：2011-05-19

  Disclosed herein are processes for the production of hydrofluoroolefins by dehydrofluorination. Also disclosed herein are processes for separation of hydrofluoroolefins from hydrofluorocarbons and from hydrogen fluoride.

  本文揭示了通过脱氟制备氢氟烯的过程。同时，还揭示了从氢氟碳化物和氢氟酸中分离氢氟烯的过程。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.4, 2.2.4, page 68 - 115
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.4, 1.3.3.8, page 33 - 59
  作者：

  DOI：——

  日期：——