4,4,4-trifluoro-2-methyl-3,3-bis(trifluoromethyl)-2-butanol | 129282-28-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4,4-trifluoro-2-methyl-3,3-bis(trifluoromethyl)-2-butanol
• 英文别名: 4,4,4-Trifluoro-2-methyl-3,3-bis(trifluoromethyl)butan-2-ol
• CAS: 129282-28-6
• 化学式: C₇H₇F₉O
• 分子量: 278.118
• InChiKey: MKVGGZUNYXLZFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  全氟叔丁基碘化物 、 丙酮 在 magnesium 、 1,2-二溴乙烷 作用下， 生成 4,4,4-trifluoro-2-methyl-3,3-bis(trifluoromethyl)-2-butanol
  参考文献：
  名称：

  Dormidontov, Yu. P.; Kazakov, A. F.; Shadrina, L. P., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 3.1, p. 456 - 458

  摘要：

  DOI：

文献信息

• DORMIDONTOV, YU. P.;KAZAKOV, A. F.;SHADRINA, L. P.;SIMONOV, A. R.;PONOMAR+, ZH. ORGAN. XIMII, 26,(1990) N, S. 553-536
  作者：DORMIDONTOV, YU. P.、KAZAKOV, A. F.、SHADRINA, L. P.、SIMONOV, A. R.、PONOMAR+

  DOI：——

  日期：——
• PRODUCTION PROCESS OF OLEFIN POLYMERIZATION CATALYST AND OLEFIN POLYMER
  申请人：TAKAOKI Kazuo

  公开号：US20110144274A1

  公开（公告）日：2011-06-16

  A process for producing an olefin polymerization catalyst, comprising steps of (1) contacting a defined amount of a zinc compound represented by the defined formula, Zn(L 1 ) 2 , with a defined amount of a halogenated alcohol represented by the defined formula, R 1 R 2 R 3 C—OH, thereby forming a zinc atom-containing compound, and (2) contacting the zinc atom-containing compound, a solid catalyst component containing a titanium atom, a magnesium atom and a halogen atom, an organoaluminum compound, and an external electron donor with one another; and a production process of an olefin polymer, comprising a step of polymerizing an olefin in the presence of an olefin polymerization catalyst produced by the above process.
• [EN] POLYMERIZED CYCLOOLEFINS USING TRANSITION METAL CATALYST AND END PRODUCTS THEREOF<br/>[FR] CYCLOOLEFINES DE POLYMERISATION UTILISANT UN CATALYSEUR DE METAL DE TRANSITION ET PRODUITS FINIS OBTENUS
  申请人：PROMERUS LLC

  公开号：WO2004035636A2

  公开（公告）日：2004-04-29

  Articles. Especially in electronic, optical and opoelectronic applications, comprising an optical polymer containing polycyclic repeating units, said optical polymer being obtained through the addition polymerization of cycloolefins using a cationic group 10 metal complex and a weakly coordinating anion of the formula: [(R')ZM(L')X(L'')y]b [WCA]d wherein [(R')ZM(L')x(L'')y] is a cation complex where M represents a Group 10 transition metal; R' represents an anionic hydrocarbyl containing ligand; L' represents a Group 15 neutral electron donor ligand; L' represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
• Dormidontov, Yu. P.; Kazakov, A. F.; Shadrina, L. P., Journal of Organic Chemistry USSR (English Translation), 1990, vol. 26, # 3.1, p. 456 - 458
  作者：Dormidontov, Yu. P.、Kazakov, A. F.、Shadrina, L. P.、Simonov, A. R.、Ponomarev, V. G.

  DOI：——

  日期：——