1-(methylphenyl)-5-hexen-1-one | 83845-55-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(methylphenyl)-5-hexen-1-one
• 英文别名: 1-(2-Methylphenyl)hex-5-en-1-one
• CAS: 83845-55-0
• 化学式: C₁₃H₁₆O
• 分子量: 188.269
• InChiKey: AQOLQTPQFSMLMA-UHFFFAOYSA-N

物化性质

• 沸点：
  98-99 °C(Press: 1.1 Torr)
• 密度：
  0.949±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(methylphenyl)-5-hexen-1-one 在 sodium hydride 、 对苯二甲醚 作用下， 以 苯 为溶剂， 生成 1-hepta-2,6-dien-2-yl-2-methylbenzene
  参考文献：
  名称：

  Photochemistry of (o-methylphenyl)alkadienes: attempted intramolecular trapping of the resulting o-xylylenes

  摘要：

  DOI：

  10.1021/jo00149a018
• 作为产物：
  描述：

  5-己烯醛 在 magnesium 、 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 生成 1-(methylphenyl)-5-hexen-1-one
  参考文献：
  名称：

  Photochemistry of (o-methylphenyl)alkadienes: attempted intramolecular trapping of the resulting o-xylylenes

  摘要：

  DOI：

  10.1021/jo00149a018

文献信息

• Oxidation of Silyl Enol Ethers by Using IBX and IBX⋅N-Oxide Complexes: A Mild and Selective Reaction for the Synthesis of Enones
  作者：K. C. Nicolaou、David L. F. Gray、Tamsyn Montagnon、Scott T. Harrison

  DOI：10.1002/1521-3773(20020315)41:6<996::aid-anie996>3.0.co;2-i

  日期：2002.3.15
• HORNBACK, J. M.;BARROWS, R. D., J. ORG. CHEM., 1983, 48, N 1, 90-98
  作者：HORNBACK, J. M.、BARROWS, R. D.

  DOI：——

  日期：——
• MODIFIED NAPHTHALENE FORMALDEHYDE RESIN, TRICYCLODECANE SKELETON-CONTAINING NAPHTHOL COMPOUND AND ESTER COMPOUND
  申请人：Kita Seiji

  公开号：US20110009574A1

  公开（公告）日：2011-01-13

  A modified dimethylnaphthalene formaldehyde resin is disclosed, which is excellent in heat resistance and useful for thermosetting resins which are used for an electrical insulating material, a resin for resist, a semiconductor sealing resin, an adhesive for printed wiring board, a matrix resin for electrical laminate or prepreg to be mounted in electrical instruments, electronic instruments, industrial instruments, etc., a buildup laminate material, a resin for fiber-reinforced plastic, a sealing resin for liquid crystal display panel, a paint, a variety of coating agents, an adhesive, a laminate for electrical or electronic parts, a molded article, a coating material, a sealing material and the like, the modified dimethylnaphthalene formaldehyde resin being obtained by modifying a polyfunctional dimethylnaphthalene formaldehyde resin having a constituent unit represented by the following general formula [1] in a molecule thereof with at least one member selected from the group consisting of a phenol represented by the following general formula [2], a naphthol represented by the following general formula [3] and a naphthol represented by the following general formula [4] (provided that at least any of the naphthol represented by the general formula [3] or the naphthol represented by the general formula [4] must be included).
• US8524952B2
  申请人：——

  公开号：US8524952B2

  公开（公告）日：2013-09-03
• US8563665B2
  申请人：——

  公开号：US8563665B2

  公开（公告）日：2013-10-22