Triallylsilane | 1116-62-7

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: Triallylsilane
• 英文别名: all3SiH；triallyl-silane；Triallyl-silan；Tris(prop-2-enyl)silane
• CAS: 1116-62-7
• 化学式: C₉H₁₆Si
• mdl: MFCD00800603
• 分子量: 152.312
• InChiKey: HKILWKSIMZSWQX-UHFFFAOYSA-N

物化性质

• 沸点：
  45 °C (9 mmHg)
• 密度：
  0.80142 g/cm3
• 闪点：
  22 °C
• 稳定性/保质期：
  避免与不相容材料接触，特别是强氧化剂。

计算性质

• 辛醇/水分配系数(LogP)：
  2.35
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• 海关编码：
  2931900090
• 安全说明：
  S16,S26,S37/39
• 储存条件：
  密封储存于阴凉、干燥的库房，远离火源和易燃易爆区域。

SDS

Name:	Triallylsilane Material Safety Data Sheet
Synonym:	None Known
CAS:	1116-62-7

Section 1 - Chemical Product MSDS Name:Triallylsilane Material Safety Data Sheet
Synonym:None Known

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
1116-62-7	Triallylsilane		unlisted

Hazard Symbols: T
Risk Phrases: 23/24/25 48

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger of serious damage to health by prolonged exposure.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Toxic in contact with skin.
Ingestion:
May cause irritation of the digestive tract. Poison by ingestion.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Toxic if inhaled.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1116-62-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight: 152.31

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not currently available.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1116-62-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Triallylsilane - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 48 Danger of serious damage to health by prolonged
exposure.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1116-62-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1116-62-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1116-62-7 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  Triallylsilane 在 N,N-二异丙基乙胺 、 copper dichloride 作用下， 以 乙腈 为溶剂， 以79%的产率得到氯三烯丙基硅烷
  参考文献：
  名称：

  Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers

  摘要：

  The new organosilane 4-triallylsilylphenol (1) can be synthesised in high yield via two routes using either 4-bromophenol or its silyl-group protected derivative as starting materials. Compound 1 can be used in the divergent or convergent synthesis of carbosilane dendrimers or conversely as a readily functionalisable dendrimer core unit. An improved synthesis of chlorotriallylsilane is also presented. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00208-1
• 作为产物：
  描述：

  氯丙烯镁 在 三氯硅烷 、 3-氯丙烯 作用下， 以 乙醚 为溶剂， 反应 3.0h， 以64.3%的产率得到Triallylsilane
  参考文献：
  名称：

  Zhun', V.I.; Tsvetkov, A. L.; Sheludyakov, V. D., Journal of general chemistry of the USSR, 1988, vol. 58, # 7, p. 1425 - 1431

  摘要：

  DOI：

文献信息

• Rh-catalyzed 1,4-addition of triallyl(aryl)silanes to α,β-unsaturated carbonyl compounds
  作者：Toshiyuki Kamei、Mizuho Uryu、Toyoshi Shimada

  DOI：10.1016/j.tetlet.2016.03.002

  日期：2016.4

  4-addition of triallyl(aryl)silane to α,β-unsaturated carbonyl compounds was developed. Triallyl(aryl)silanes were used as air- and moisture-stable silicon nucleophiles. Allylsilanes were converted to silanols in situ and underwent transmetalation. This method can accept a wide range of functionalized triallyl(aryl)silane and α,β-unsaturated carbonyl compounds.

  开发了Rh催化的三烯丙基（芳基）硅烷向α，β-不饱和羰基化合物的1,4-加成反应。三烯丙基（芳基）硅烷被用作对空气和水分稳定的硅亲核试剂。将烯丙基硅烷原位转化为硅烷醇并进行金属转移。该方法可以接受各种官能化的三烯丙基（芳基）硅烷和α，β-不饱和羰基化合物。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 36, page 111 - 115
  作者：

  DOI：——

  日期：——
• STUDIES IN SILICO-ORGANIC COMPOUNDS. VII. THE PREPARATION AND PROPERTIES OF CERTAIN SUBSTITUTED SILANES¹
  作者：JAMES W. JENKINS、NALO L. LAVERY、PAUL R. GUENTHER、HOWARD W. POST

  DOI：10.1021/jo01164a013

  日期：1948.11
• A Novel Phenol for Use in Convergent and Divergent Dendrimer Synthesis: Access to Core Functionalisable Trifurcate Carbosilane Dendrimers—The X-ray Crystal Structure of [1,3,5-Tris{4-(triallylsilyl)phenylester}benzene]
  作者：Robert A. Gossage、Elena Muñoz-Martínez、Holger Frey、Armin Burgath、Martin Lutz、Anthony L. Spek、Gerard van Koten

  DOI：10.1002/(sici)1521-3765(19990702)5:7<2191::aid-chem2191>3.0.co;2-j

  日期：1999.7.2
• ZHUN, V. I.;TSVETKOV, A. L.;SHELUDYAKOV, V. D.;LAVYGIN, I. A.;LEJTAN, O. +, ZH. OBSHCH. XIMII, 58,(1988) N 7, 1599-1606
  作者：ZHUN, V. I.、TSVETKOV, A. L.、SHELUDYAKOV, V. D.、LAVYGIN, I. A.、LEJTAN, O. +

  DOI：——

  日期：——