(3Z,5E)-hepta-3,5-dien-1-ol | 86742-51-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (3Z,5E)-hepta-3,5-dien-1-ol
• 英文别名: (Z,E)-3,5-heptadien-1-ol
• CAS: 86742-51-0
• 化学式: C₇H₁₂O
• 分子量: 112.172
• InChiKey: WOWTZARDJWWOTN-IAROGAJJSA-N

物化性质

• 沸点：
  182.2±9.0 °C(Predicted)
• 密度：
  0.870±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-hept-5-en-3-yn-1-ol 、 (3Z,5E)-hepta-3,5-dien-1-ol 在 咪唑 、 碘 作用下， 以 甲苯 为溶剂， 反应 3.0h， 生成 7-iodo-hept-2t-en-4-yne 、 (2E,4Z)-7-iodohepta-2,4-diene
  参考文献：
  名称：

  Stereocontrolled synthesis of cis-fused hydroisoquinolines by an intramolecular Diels-Alder reaction of (Z)-dienes

  摘要：

  DOI：

  10.1021/jo00220a026
• 作为产物：
  描述：

  tert-Butyl-[((3Z,5E)-hepta-3,5-dienyl)oxy]-diphenyl-silane 在 四丁基氟化铵 、 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成 (E)-hept-5-en-3-yn-1-ol 、 (3Z,5E)-hepta-3,5-dien-1-ol
  参考文献：
  名称：

  Stereocontrolled synthesis of cis-fused hydroisoquinolines by an intramolecular Diels-Alder reaction of (Z)-dienes

  摘要：

  DOI：

  10.1021/jo00220a026

文献信息

• [EN] FRAGRANCE AND FLAVOR COMPOSITIONS CONTAINING ISOMERIC ALKADIENYL ESTERS<br/>[FR] COMPOSITIONS DE PARFUM ET D'ARÔME CONTENANT DES ESTERS D'ALCADIÉNYLE ISOMÈRES
  申请人：BEDOUKIAN RES INC

  公开号：WO2018022580A1

  公开（公告）日：2018-02-01

  A composition containing at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the composition. A fragrance or flavor composition containing at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the composition. A consumer product containing the fragrance or flavor composition having at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the composition. A method of imparting a fragrance or flavor to a consumer product by adding to the consumer product a fragrance or flavor composition containing at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the consumer product.

  一种含有至少一种异构的烯二酸酯的组合物，其含量足以赋予组合物香味或味道。一种香味或味道组合物，其含有至少一种异构的烯二酸酯，其含量足以赋予组合物香味或味道。一种消费品，其含有香味或味道组合物，其中至少含有一种异构的烯二酸酯，其含量足以赋予组合物香味或味道。一种通过向消费品添加至少一种异构的烯二酸酯的香味或味道组合物的方法，其含量足以赋予消费品香味或味道。
• Fragrance and flavor compositions containing isomeric alkadienyl esters
  申请人：BEDOUKIAN RESEARCH, INC.

  公开号：US10863758B2

  公开（公告）日：2020-12-15

  A composition containing at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the composition. A fragrance or flavor composition containing at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the composition. A consumer product containing the fragrance or flavor composition having at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the composition. A method of imparting a fragrance or flavor to a consumer product by adding to the consumer product a fragrance or flavor composition containing at least one isomeric alkadienyl ester in an amount effective to impart a fragrance or flavor to the consumer product.

  一种含有至少一种异构烷二烯酯的组合物，其有效用量可为该组合物带来香味或风味。一种香料或香精组合物，含有至少一种异构烷二烯酯，其有效用量可赋予组合物香味或风味。含有至少一种异构烷二烯基酯的香料或香精组合物的消费品，其含量能有效地赋予组合物香味或风味。一种向消费品中添加香料或香精组合物的方法，该香料或香精组合物含有至少一种异构烷二烯酯，其用量可有效地向消费品中添加香料或香精。
• Tandem Wittig–intramolecular Diels–Alder cycloaddition of ester-tethered 1,3,9-decatrienes under microwave heating
  作者：Jinlong Wu、Xiuqing Jiang、Jingjing Xu、Wei-Min Dai

  DOI：10.1016/j.tet.2010.10.088

  日期：2011.1

  Intramolecular Diels Alder (IMDA) cycloaddition of the ester-tethered 1,3,9,-decatrienes possessing a carbonyl substituent at C10 has been investigated under controlled microwave heating (MeCN, 180 degrees C) to afford a variety of 3,4,4a,7,8,8a-hexahydroisochromen-1-ones in 53-89% yields and in 64:36-79:21 ratios for the cis and trans isomers. Under the same microwave heating conditions, a tandem Wittig-IMDA cycloaddition, starting from the alpha-bromoacetates of 3,5-hexadien-1-ols and glyoxalate/phenylglyoxal hydrates in the presence of PPh3 and 2,6-lutidine, has been demonstrated, furnishing 3,4,4a,7,8,8a-hexahydroisochromen-1-one adducts in 73-91% yields in favor of the cis isomers. During this tandem process, three consecutive carbon carbon bonds in the end products were efficiently formed with the aid of microwave irradiation within short reaction times. (C) 2010 Elsevier Ltd. All rights reserved.
• Formal total synthesis of (.+-.)-pseudomonic acids A and C. The quasi-intramolecular Lewis acid catalyzed Diels-Alder reaction
  作者：Barry B. Snider、Gary B. Phillips、Robert Cordova

  DOI：10.1021/jo00166a013

  日期：1983.9
• FRAGRANCE AND FLAVOR COMPOSITIONS CONTAINING ISOMERIC ALKADIENYL ESTERS
  申请人：Bedoukian Research, Inc.

  公开号：EP3490389A1

  公开（公告）日：2019-06-05