N-Phenacyldiallylamin | 33777-39-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N-Phenacyldiallylamin
• 英文别名: 2-[Bis(prop-2-enyl)amino]-1-phenylethanone
• CAS: 33777-39-8
• 化学式: C₁₄H₁₇NO
• 分子量: 215.295
• InChiKey: NELQVUCYADBARR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-Phenacyldiallylamin 在 吡啶 、 四(三苯基膦)钯 、 1,3-二甲基巴比妥酸 、 盐酸羟胺 、 三乙胺 作用下， 以 乙醇 、 二氯甲烷 、 氯仿 、 甲苯 为溶剂， 反应 24.0h， 生成 tert-butyl-6a-phenyl-3,3a,4,6-tetrahydro-1H-pyrrolo[3,4-c]isoxazole-5-carboxylate
  参考文献：
  名称：

  TETRAHYDROPYRROLOTHIAZINE COMPOUNDS

  摘要：

  本发明提供了以下式I的化合物： 其中A选自以下组合之一； R1为H或F； R2为H，—CH2OH，C1-C3烷基， R3为H，F或CN； R4为H，F；或CN；和 R5为H，—CH3，或—OCH3； 或其药学上可接受的盐。

  公开号：

  US20130261111A1
• 作为产物：
  描述：

  2-溴苯乙酮 、 二烯丙基胺 以 乙腈 为溶剂， 反应 96.0h， 生成 N-Phenacyldiallylamin
  参考文献：
  名称：

  TETRAHYDROPYRROLOTHIAZINE COMPOUNDS

  摘要：

  本发明提供了以下式I的化合物： 其中A选自以下组合之一； R1为H或F； R2为H，—CH2OH，C1-C3烷基， R3为H，F或CN； R4为H，F；或CN；和 R5为H，—CH3，或—OCH3； 或其药学上可接受的盐。

  公开号：

  US20130261111A1

文献信息

• Synthesis of α-Amino Acids by Umpolung of Weinreb Amide Enolates
  作者：Sebastian Hirner、Donata K. Kirchner、Peter Somfai

  DOI：10.1002/ejoc.200800683

  日期：2008.11

  An efficient and diastereoselective synthesis of alpha-amino acids from readily available starting materials has been developed. The key feature of this reaction is an umpolung of a glycine-derived ...

  已经开发出一种从容易获得的起始材料高效和非对映选择性合成 α-氨基酸的方法。该反应的主要特征是甘氨酸衍生的...
• PHOTOCURABLE COMPOSITION, ARTICLE WITH FINE PATTERN AND METHOD FOR PRODUCING SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP1873174A1

  公开（公告）日：2008-01-02

  A photocurable composition capable of producing a micropattern-formed product efficiently, which is excellent in physical properties such as heat resistance, chemical resistance, releasability and optical characteristics (transmittance and low refractive index), and a process for producing a micropattern-formed product, capable of highly precisely transferring a micropattern of a mold to its surface are provided. A photocurable composition which comprises from 50 to 98 mass% of a monomer containing no fluorine atom and having a viscosity at 25°C of from 0.1 to 100 mPa·s, from 0.1 to 45 mass% of a fluoromonomer, from more than 0.1 to 20 mass% of a fluorinated surfactant and/or a fluoropolymer and from 1 to 10 mass% of a photopolymerization initiator, and contains substantially no solvent. A process for producing a micropattern-formed product comprising a cured product having a micropattern of a mold transferred on its surface, or such a micropattern-formed product integrated with a substrate, which uses the photocurable composition, a substrate and a mold having a micropattern.

  本发明提供了一种能够高效生产微图案成型产品的光固化组合物，该组合物具有优异的物理性能，如耐热性、耐化学性、脱模性和光学特性（透光率和低折射率），还提供了一种生产微图案成型产品的工艺，该工艺能够高精度地将模具的微图案转移到其表面。 一种光固化组合物，它包含 50 至 98 质量％的不含氟原子且在 25°C 时粘度为 0.1 至 100 mPa-s的单体、0.1 至 45 质量％的氟单体、大于 0.1 至 20 质量％的含氟表面活性剂和/或含氟聚合物以及 1 至 10 质量％的光聚合引发剂，并且基本上不含溶剂。一种用于生产微图案成型产品的工艺，该产品包括在其表面转印有模具微图案的固化产品，或与基材集成的微图案成型产品，该工艺使用光固化组合物、基材和具有微图案的模具。
• WIRE GRID POLARIZER AND METHOD FOR PRODUCING THE SAME
  申请人：Asahi Glass Company, Limited

  公开号：EP2023169A1

  公开（公告）日：2009-02-11

  The present invention provides a wire-grid polarizer showing high polarization separation ability in the visible light region and is excellent in heat resistance and durability; and a process for producing such a wire-grid polarizer with high productivity, which enables to produce a polarizer of large area. A process for producing a wire-grid polarizer, comprising a step of coating a supporting substrate with a photocurable composition, a step of pressing a mold having a plurality of parallel grooves at a constant pitch against the photocurable composition so that the grooves contact with the photocurable composition, a step of curing the photocurable composition in a state that the mold is pressed against the photocurable composition, to form a light-transmitting substrate having a plurality of ridges corresponding to the grooves of the mold, a step of separating the mold from the light-transmitting substrate, and a step of forming fine metalic wires on the ridges of the light-transmitting substrate.

  本发明提供了一种在可见光区域具有高偏振分离能力、耐热性和耐久性优异的线栅偏振片；以及一种生产这种线栅偏振片的工艺，其生产效率高，可生产大面积的偏振片。 一种生产线栅式偏光片的工艺，包括在支撑基板上涂覆光固化组合物的步骤；将具有多个间距恒定的平行凹槽的模具压向光固化组合物，使凹槽与光固化组合物接触的步骤、在模具压在光固化组合物上的状态下固化光固化组合物，以形成透光基板，该基板具有多个与模具凹槽相对应的脊，将模具与透光基板分离，以及在透光基板的脊上形成细金属丝。
• PHOTOCURABLE COMPOSITION AND PROCESS FOR PRODUCING MOLDED OBJECT HAVING FINE PATTERN IN SURFACE
  申请人：Asahi Glass Company, Limited

  公开号：EP2159236A1

  公开（公告）日：2010-03-03

  To provide a photocurable composition from which a cured product excellent in mold release characteristics and mechanical strength can be obtained, and a method for producing a molded product excellent in durability, with a fine pattern having a reverse pattern of a mold precisely transferred on its surface. A photocurable composition 20 comprising from 15 to 60 mass% of a compound (A) which is an aromatic compound having at least two rings or an alicyclic compound having at least two rings and which has two (meth)acryloyloxy groups, from 5 to 40 mass% of a compound (B) having a fluorine atom and having at least one carbon-carbon unsaturated double bond (excluding the compound (A)), from 10 to 55 mass% of a compound (C) having one (meth)acryloyloxy group (excluding the compound (B)) and from 1 to 12 mass% of a photopolymerization initiator (D) (provided that (A)+(B)+(C)+(D)=100 mass%) is used.

  提供一种光固化组合物，该组合物可获得脱模特性和机械强度优异的固化产品，并提供一种生产耐久性优异的模制产品的方法，该模制产品表面具有精确转印模具反向图案的精细花纹。 一种光固化组合物 20，包含 15 至 60 质量％的化合物 (A)，该化合物为至少有两个环的芳香族化合物或至少有两个环的脂环族化合物，且具有两个 (甲基)丙烯酰氧基、5 至 40 质量％的化合物 (B)，该化合物具有一个氟原子和至少一个碳碳不饱和双键 （不包括化合物 (A)）；10 至 55 质量％的化合物 (C)，该化合物具有一个 (甲基) 丙烯酰氧基（不包括化合物 (B)）；以及 1 至 12 质量％的光聚合引发剂 (D)（条件是 (A)+(B)+(C)+(D)=100 质量％）。
• PHOTOCURABLE COMPOSITION AND MANUFACTURING METHOD FOR A MOLDED BODY HAVING A FINE PATTERN ON THE SURFACE
  申请人：Asahi Glass Company, Limited

  公开号：EP2289955A1

  公开（公告）日：2011-03-02

  To provide a photocurable composition whereby it is possible to obtain a cured product provided with both release property and high refractive index, and a process whereby it is possible to produce a molded product having a high refractive index and having on its surface a fine pattern having a reverse pattern of a mold precisely transferred. A photocurable composition comprising from 61 to 90 mass% of a compound (A) having a refractive index of at least 1.55 at a wavelength of 589 nm before curing and having at least two (meth)acryloyloxy groups, from 2 to 15 mass% of a compound (B) having fluorine atoms and at least one carbon-carbon unsaturated double bond (provided that the compound (A) is excluded), from 5 to 35 mass% of a compound (C) having one (meth)acryloyloxy group (provided that the compound (B) is excluded), and from 1 to 12 mass% of a photopolymerization initiator (D) (provided (A)+ (B)+ (C)+(D)=100 mass%).

  提供一种光固化组合物，通过该组合物可以获得既具有脱模性又具有高折射率的固化产品；还提供一种工艺，通过该工艺可以生产出具有高折射率的模制产品，该模制产品的表面具有精确转印模具反向图案的精细花纹。 一种光固化组合物，包含 61 至 90 质量％的化合物 (A)，其折射率至少为 1.55 的化合物 (A)，该化合物在固化前波长为 589 纳米时的折射率至少为 1.55，并具有至少两个 (甲基)丙烯酰氧基；2 至 15 质量％的化合物 (B)，该化合物具有氟原子和至少一个碳碳不饱和双键（但不包括化合物 (A)）、5 至 35 质量％的具有一个（甲基）丙烯酰氧基的化合物 (C)（前提是不包括化合物 (B)），以及 1 至 12 质量％的光聚合引发剂 (D)（前提是 (A)+ (B)+ (C)+(D)=100 质量％）。