2-hydrodecafluoro-2-pentanol | 377-53-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: 2-hydrodecafluoro-2-pentanol
• 英文别名: 2H-decafluoro-pentan-2-ol；2H-Decafluor-pentan-2-ol；1,1,1,3,3,4,4,5,5,5-Decafluoropentan-2-ol
• CAS: 377-53-7
• 化学式: C₅H₂F₁₀O
• 分子量: 268.054
• InChiKey: PXCDCUCIBBLALY-UHFFFAOYSA-N

物化性质

• 沸点：
  51-52 °C(Press: 209 Torr)
• 密度：
  1.638±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  1,1,1,3,3,4,4,5,5,5-decafluoropentan-2-ol;N,N-diethylethanamine 生成 2-hydrodecafluoro-2-pentanol
  参考文献：
  名称：

  Saloutina L. W., Kodess M. I., Sapewalow A. Ja., Isw. AN. Ser. khim, (1994) N 12, S 2177- 2181

  摘要：

  DOI：

文献信息

• Reactions of 2,3-epoxypolyfluoroalkanes with triethylamine
  作者：L. V. Saloutina、M. I. Kodess、A. Ya. Zapevalov

  DOI：10.1007/bf00700169

  日期：1994.12

  The reactions of 2,3-epoxyperfluoro- and 2,3-epoxy-ω-hydropolyfluoroalkanes with excess triethylamine at elevated temperatures yield secondary alcohols, which are the reduction products of intermediate isomeric ketones. Ring-opening occurs preferentially from the side of the less bulky trifluoromethyl group in all compounds except 2,3-epoxy-6-hydroundecafluorohexane.

  2,3-环氧全氟和 2,3-环氧-ω-氢多氟烷烃与过量三乙胺在升高的温度下反应生成仲醇，仲醇是中间体异构酮的还原产物。在除 2,3-环氧-6-氢十一氟己烷外的所有化合物中，开环优先发生在体积较小的三氟甲基一侧。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.4, 2.2.4, page 68 - 115
  作者：

  DOI：——

  日期：——
• Haszeldine, R. N., Journal of the Chemical Society
  作者：Haszeldine, R. N.

  DOI：——

  日期：——
• A model of therapeutic intervention with Indigenous Australians
  作者：David Vicary、Henry Andrews

  DOI：10.1111/j.1467-842x.2001.tb00592.x

  日期：2001.8

  Many non-Aboriginal mental health practitioners are confronted by the lack of practical information pertaining to interventions with Aboriginal clientele. Subsequently, this may have engendered uncertainty in potential therapists and counsellors due to the lack of reliable, practical and culturally appropriate information. Those non-Aboriginal mental health practitioners working in the field with Aboriginal clients do so with varying degrees of success and build upon their knowledge base through personal experience and anecdotal information. Unfortunately, this information is often not made available to others working in the field through journal publication. This Practice Note examines a model of intervention aimed at developing relationships to enhance therapeutic interventions at the individual, family and systems level. As a way of clarification, the model is described via a case study involving a psychological intervention with a remote Aboriginal community.
• Saloutina L. W., Kodess M. I., Sapewalow A. Ja., Isw. AN. Ser. khim, (1994) N 12, S 2177- 2181
  作者：Saloutina L. W., Kodess M. I., Sapewalow A. Ja.

  DOI：——

  日期：——