(E)-2-(2-hexylidene)cyclohexanone | 103517-12-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-2-(2-hexylidene)cyclohexanone
• 英文别名: 2-Hexylidenecyclohexan-1-one；(2E)-2-hexylidenecyclohexan-1-one
• CAS: 103517-12-0
• 化学式: C₁₂H₂₀O
• 分子量: 180.29
• InChiKey: VDZBUTVYLIWRCT-DHZHZOJOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  苄胺 在 磷酸二乙酯 作用下， 以 二氯甲烷 为溶剂， 反应 19.0h， 生成 (E)-2-(2-hexylidene)cyclohexanone
  参考文献：
  名称：

  磷酸介导的亚胺互变异构：向醛中添加仲烯胺中间体

  摘要：

  磷酸衍生物已显示出通过烯胺中间体促进亚胺和几种醛底物之间的加成反应，从而生成交联的羟醛缩合产物。将介绍反应范围和初步的机理研究。

  DOI：

  10.1016/j.tetlet.2014.04.002

文献信息

• Catalytic preparation of optically active ketones
  申请人：Takasago International Corporation

  公开号：EP0409530B1

  公开（公告）日：1993-12-08
• A METHOD OF MINIMIZING ALDEHYDE-BASED IMPURITIES IN A PROCESS STREAM
  申请人：BASF AKTIENGESELLSCHAFT

  公开号：EP1853543A1

  公开（公告）日：2007-11-14
• A method of minimizing aldehyde-based impurities in a process stream
  申请人：BASF SE

  公开号：EP1853543B1

  公开（公告）日：2013-04-10
• METHOD OF MINIMIZING ALDEHYDE BASED IMPURITIES IN A PROCESS STREAM
  申请人：Burlone A. Dominick

  公开号：US20060189829A1

  公开（公告）日：2006-08-24

  Oxidation of an alkane to an alkanone in a process stream forms aldehyde-based impurities. A method of minimizing the aldehyde-based impurities introduces an amine into the process stream to minimize the aldehyde-based impurities. The amine interacts with the alkanone and the aldehyde-based impurities thereby forming heavy products. The method separates the heavy products from the alkanones to reduce a level of the aldehyde-based impurities. The process stream preferably includes cyclohexyl ketone as the alkanone and n-hexanal as the aldehyde-based impurity. The method is typically involved in synthesis of a caprolactam.
• METHOD OF MINIMIZING ALDEHYDE-BASED IMPURITIES IN A PROCESS STREAM
  申请人：Burlone Dominick A.

  公开号：US20090114522A1

  公开（公告）日：2009-05-07

  Oxidation of an alkane to an alkanone in a process stream forms aldehyde-based impurities. A method of minimizing the aldehyde-based impurities introduces an amine into the process stream to minimize the aldehyde-based impurities. The amine interacts with the alkanone and the aldehyde-based impurities thereby forming heavy products. The method separates the heavy products from the alkanones to reduce a level of the aldehyde-based impurities. The process stream preferably includes cyclohexyl ketone as the alkanone and n-hexanal as the aldehyde-based impurity. The method is typically involved in synthesis of a caprolactam.