2-[4-chlorophenylmercury(II)]-1,4-benzoquinone | 251319-97-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-[4-chlorophenylmercury(II)]-1,4-benzoquinone
• CAS: 251319-97-8
• 化学式: C₁₂H₇ClHgO₂
• 分子量: 419.229
• InChiKey: ALXSLFBQCKCWBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.64
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-氯苯基氯化汞 、 对苯醌 在 aluminum oxide 作用下， 以9.1%的产率得到2-[4-chlorophenylmercury(II)]-1,4-benzoquinone
  参考文献：
  名称：

  Microwave assisted synthesis of novel organomercurials in ‘dry media’

  摘要：

  New organomercurials of benzoquinone, barbituric acid and thiobarbituric acid with substituted aryl mercuric chloride have been synthesised using microwave irradiation under dry conditions in a domestic microwave oven in a few minutes with improved yields as compared to conventional heating. These organomercurials have a 1.1 stoichiometric ratio of aryl mercury and benzoquinone/barbituric acid/thiobarbituric acid moiety. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00159-x

文献信息

• Microwave assisted synthesis of novel organomercurials in ‘dry media’
  作者：Mazaahir Kidwai、Preeti Misra、Kumar Ranjan Bhushan

  DOI：10.1016/s0277-5387(99)00159-x

  日期：1999.8

  New organomercurials of benzoquinone, barbituric acid and thiobarbituric acid with substituted aryl mercuric chloride have been synthesised using microwave irradiation under dry conditions in a domestic microwave oven in a few minutes with improved yields as compared to conventional heating. These organomercurials have a 1.1 stoichiometric ratio of aryl mercury and benzoquinone/barbituric acid/thiobarbituric acid moiety. (C) 1999 Elsevier Science Ltd. All rights reserved.