3-benzoyl-octane-2,6-dione | 1234476-69-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-benzoyl-octane-2,6-dione
• 英文别名: 3-Benzoyloctane-2,6-dione
• CAS: 1234476-69-7
• 化学式: C₁₅H₁₈O₃
• 分子量: 246.306
• InChiKey: HZOKWOIROXWXGL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-戊烯-3-酮 、 1-苯基-1,3-丁二酮 在 salmon testes DNA 作用下， 以 水 为溶剂， 反应 24.0h， 生成 3-benzoyl-octane-2,6-dione
  参考文献：
  名称：

  Genomic salmon testes DNA as a catalyst for Michael reactions in water

  摘要：

  The DNA molecule, recognized as the carrier of genetic information in vivo, can function as an efficient organocatalyst for Michael additions of 1,3-dicarbonyl compounds to activated alkenes in aqueous media. The procedure described here is environmentally benign and offers several advantages in terms of simplicity, generality and efficiency. We have used fluorescence spectroscopy to evaluate the catalytic activity of a molecule of DNA. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.02.007

文献信息

• Genomic salmon testes DNA as a catalyst for Michael reactions in water
  作者：Margherita De Rosa、Sara Di Marino、Anna Maria D’Ursi、Maria Strianese、Annunziata Soriente

  DOI：10.1016/j.tet.2012.02.007

  日期：2012.4

  The DNA molecule, recognized as the carrier of genetic information in vivo, can function as an efficient organocatalyst for Michael additions of 1,3-dicarbonyl compounds to activated alkenes in aqueous media. The procedure described here is environmentally benign and offers several advantages in terms of simplicity, generality and efficiency. We have used fluorescence spectroscopy to evaluate the catalytic activity of a molecule of DNA. (C) 2012 Elsevier Ltd. All rights reserved.