(Z)-3,4,4,5,5,6,6,7,7,8,8,8-dodecafluorooct-2-enal | 142502-67-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (Z)-3,4,4,5,5,6,6,7,7,8,8,8-dodecafluorooct-2-enal
• CAS: 142502-67-8
• 化学式: C₈H₂F₁₂O
• 分子量: 342.084
• InChiKey: IRFCYNBOXLFPAS-IWQZZHSRSA-N

物化性质

• 沸点：
  134.7±40.0 °C(Predicted)
• 密度：
  1.576±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  全氟己基碘烷 在 氢氧化钾 、 锌 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 7.0h， 生成 (Z)-3,4,4,5,5,6,6,7,7,8,8,8-dodecafluorooct-2-enal
  参考文献：
  名称：

  Synthése de fluoroalkyl éthanl : RFCH2CHO

  摘要：

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.

  DOI：

  10.1016/s0040-4039(00)92222-6

文献信息

• Synthesis of Per(poly)fluoroalkyl aldehydes RF(CH2)nCHO
  作者：Laurence Le´veˆque、Maurice Le Blanc、Raphae¨l Pastor

  DOI：10.1016/s0040-4039(98)02029-2

  日期：1998.11

  We report the preparation of polyfluoroalkyl aldehydes RF(CH2)nCHO in high yields by direct oxidation of polyfluoroalkyl alcohols; the Swern oxidation, pyridinium chlorochromate and Dess-Martin periodinane are used and compared

  我们报道了通过直接氧化多氟烷基醇来制备高产率的多氟烷基醛R F（CH 2）n CHO；比较了Swern氧化法，氯铬酸吡啶鎓盐和Dess-Martin高碘烷
• Synthése de fluoroalkyl éthanl : RFCH2CHO
  作者：Ph. Laurent、H. Blancou、A. Commeyras

  DOI：10.1016/s0040-4039(00)92222-6

  日期：1992.4

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.