bis-(1,1-dimethyl-allyl)-ether | 89328-58-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis-(1,1-dimethyl-allyl)-ether
• 英文别名: Bis-(1.1-dimethyl-propen-(2)-yl)-aether；Bis-(1,1-dimethyl-allyl)-aether；3-Methyl-3-[(2-methylbut-3-en-2-yl)oxy]but-1-ene；3-methyl-3-(2-methylbut-3-en-2-yloxy)but-1-ene
• CAS: 89328-58-5
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: QRQXBVDDGHHWCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  异戊烯醇 生成 bis-(1,1-dimethyl-allyl)-ether
  参考文献：
  名称：

  MARTON, DANIELE;SLAVIERO, PIERANGELO;TAGLIAVINI, GIUSEPPE, TETRAHEDRON, 45,(1989) N2, C. 7099-7108

  摘要：

  DOI：

文献信息

• Azabicyclic compounds for the treatment of disease
  申请人：——

  公开号：US20030232853A1

  公开（公告）日：2003-12-18

  The invention provides compounds of Formula I: 1 wherein Azabicyclo is 2 These compounds may be in the form of pharmaceutical salts or compositions, may be in pure enantiomeric form or racemic mixtures, and are useful in pharmaceuticals in which &agr;7 is known to be involved.

  这项发明提供了Formula I的化合物： 其中Azabicyclo是 这些化合物可以是药用盐或组合物的形式，可以是纯对映体形式或混合物，对已知涉及α7的药物具有用处。
• A Mild Synthesis of Unsymmetrical Bisalkoxysilanes through Catalyzed Alcoholysis of Hydridosilanes Containing C−C Multiple Bonds and Aryl Halides
  作者：Colleen N. Scott、Craig S. Wilcox

  DOI：10.1021/jo9022765

  日期：2010.1.1

  The synthesis of unsymmetrical bisalkoxysilanes containing unsaturated C−C bonds and alkyl and aryl bromides has been developed. This method is a modification of our previously reported two-step procedure that utilizes readily available catalysts (rhodium acetate dimer and manganese pentacarbonyl bromide) under mild neutral aprotic conditions. Good to moderate yields of the products were obtained in

  已经开发了包含不饱和CC键以及烷基和芳基溴化物的不对称双烷氧基硅烷的合成。该方法是对我们先前报道的两步程序的改进，该程序使用了在中性非质子条件下易于获得的催化剂（乙酸铑二聚体和五羰基锰锰）。在短时间内获得了良好至中等产量的产品。在该两步合成中，可以有效地制备具有可以进一步官能化的基团的不对称双烷氧基硅烷，而无需分离中间体。
• POLYVINYL ETHER COMPOUND
  申请人：NAGAO Satoshi

  公开号：US20080108850A1

  公开（公告）日：2008-05-08

  The present invention provides a polyvinyl ether compound containing an alkylene glycol or polyoxyalkylene glycol unit and a vinyl ether unit in a molecule and having a molecular weight in the range of 300 to 3,000. It shows high volume resistivity and a high viscosity index, so it can be favorably used as lubricating oil for a compression refrigerator.

  本发明提供了一种聚乙烯醚化合物，其分子中含有一种烷基二醇或聚氧烷二醇单元和一种乙烯醚单元，并且分子量在300至3,000范围内。它表现出高体积电阻率和高粘度指数，因此可以优选用作压缩式制冷剂的润滑油。
• Organotins as etherification catalysts. III. Etherifications and hydro-hydroxy-eliminations promoted by butyltin trichloride
  作者：Daniele Marton、Pierangelo Slaviero、Giuseppe Tagliavini

  DOI：10.1016/s0040-4020(01)89178-x

  日期：——

  Butyltin trichloride, as a catalyst precursor, promotes the following processes: (i) etherification of 2,3-unsaturated alcohols, (ii) etherification of functional diols, (iii) cyclization of 2,5-hexanedione, and (iv) dehydration of cyclic diols. Many examples are reported.

  丁基锡三氯化物作为催化剂前体，可促进以下过程：（i）2,3-不饱和醇的醚化，（ii）功能性二醇的醚化，（iii）2,5-己二酮的环化和（iv）脱水环状二醇。报告了许多示例。
• Polyimide compositions
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0469684A1

  公开（公告）日：1992-02-05

  Curable compositions which comprise: a) polyimides of the general formula (I) wherein B signifies a bivalent radical containing a carbon-carbon double bond, and wherein A represents an X-valent radical, but at least a bivalent radical; and b) alkenylphenoxyalkanes of the general formula (II) wherein D represents a Y-valent radical, Y is 1,2 or 3 and wherein E signifies a radical of the following formulae wherein R represents an alkyl group with 1 to 6 carbon atoms and R' a 1,2 or 2,3 alkenyl group with 3 to 8 carbon atoms.

  可治愈组合物，包括：a) 通式（I）中B表示含有碳-碳双键的二价基团，A表示X-价基团，但至少为二价基团的聚酰亚胺；b) 通式（II）中D表示Y-价基团，Y为1、2或3，E表示以下式子的基团：其中R表示1至6个碳原子的烷基，R'表示3至8个碳原子的1,2或2,3烯基基团的烷基。