Methacrylsaeure-(2-chlor-allylester) | 687-70-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Methacrylsaeure-(2-chlor-allylester)
• 英文别名: methacrylic acid-(2-chloro-allyl ester)；2-Chloroprop-2-en-1-yl 2-methylprop-2-enoate；2-chloroprop-2-enyl 2-methylprop-2-enoate
• CAS: 687-70-7
• 化学式: C₇H₉ClO₂
• 分子量: 160.6
• InChiKey: PVJURXSHCCASBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Methacrylsaeure-(2-chlor-allylester) 、 在 三甲基氯硅烷 、 2,4,5,6-四(9H-咔唑-9-基)异酞腈 作用下， 以 乙腈 为溶剂， 反应 20.0h， 生成
  参考文献：
  名称：

  通过爱尔兰–克莱森重排实现α-取代丙烯酸的光氧化还原活化的1,2-二烷基化

  摘要：

  在本文中，我们报告了通过合并Giese型自由基加成物与Ireland-Claisen重排而合成的简单原料丙烯酸酯的1,2-二烷基化，以合成有价值的叔羧酸。成功的关键是在光催化反应条件下利用还原性自由基-极性交叉概念来强迫在将烷基自由基加成丙烯酸烯丙酯后强制[3,3]-σ重排。使用容易获得的烷基硼酸作为自由基祖细胞，该氧化还原中性，无过渡金属的方案允许轻度形成两个C（sp 3）–C（sp 3）键，因此只需一步即可快速获得复杂的叔羧酸。此外，当将α-甲硅烷基胺用作自由基前体时，这种策略能够高效合成高度有吸引力的α，α-二烷基化γ-氨基丁酸（GABA）–在相关转化中仍无法获得的结构性基序。根据自由基前体的性质及其固有的氧化电势，建议采用光氧化还原诱导的自由基链或单独的光氧化还原机理。

  DOI：

  10.1039/d0sc06385a
• 作为产物：
  描述：

  2-氯-2-丙烯-1-醇 、 甲基丙烯酸甲酯 在 sodium methylate 作用下， 生成 Methacrylsaeure-(2-chlor-allylester)
  参考文献：
  名称：

  Polymerization of allylic methacrylates. Part 2.—Substituted allyl methacrylates

  摘要：

  DOI：

  10.1039/tf9585401064

文献信息

• TRANSFER SHEET
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1710077A1

  公开（公告）日：2006-10-11

  In a transfer sheet which comprises a support and a transfer layer releasable from the support, the transfer layer comprises (i) an adhesive layer formed on one surface of the support and (ii) a masking layer formed on the adhesive layer and containing a masking agent and a binder resin which may have a crosslinking group, and the transfer layer is adjusted to have an elongation at break of not less than 30% (e.g., 30 to 200%). The masking layer may comprise a white pigment such as a titanium oxide and a urethane-series resin which may have an isocyanate group. The transfer sheet may comprise an image-receiving layer at least containing a urethane-series resin particle formed on the masking layer. Moreover, the transfer sheet may comprise an anchor layer between the masking layer and the image-receiving layer. The transfer layer is capable of recording an image thereon the image being transferred from a recording sheet. These transfer sheets may be used for forming the image on a colored object by transferring to the object.

  在转印片材中，转印片材包括支撑物和可从支撑物上释放的转印层，转印层包括(i)在支撑物的一个表面上形成的粘合剂层和(ii)在粘合剂层上形成的掩蔽层，掩蔽层含有掩蔽剂和粘合剂树脂，粘合剂树脂可带有交联基团，转印层经调整后的断裂伸长率不小于30%（如30%至200%）。遮蔽层可包括白色颜料（如氧化钛）和聚氨酯系列树脂（可带有异氰酸酯基团）。转印纸可包括一个图像接收层，该层至少含有形成在遮蔽层上的聚氨酯系列树脂颗粒。此外，转印纸还可包括位于遮蔽层和图像接收层之间的锚定层。转印层能够在其上记录图像，图像是从记录片转印过来的。这些转印片可用于通过转印到彩色物体上在该物体上形成图像。
• Moulded body
  申请人：DAICEL CORPORATION

  公开号：US10676644B2

  公开（公告）日：2020-06-09

  Provided is a shaped article including a hardcoat layer, where the hardcoat layer has surface hardness, flexibility, and heat resistance at high levels and offers excellent workability. The shaped article according to the present invention is a shaped article including a hardcoat layer, a substrate layer, and a thermoplastic resin layer and having a curved shape. The hardcoat layer defines an outermost surface of the shaped article. The hardcoat layer includes a cure product of a curable composition. The curable composition includes a cationically curable silicone resin and a leveling agent. The cationically curable silicone resin includes a silsesquioxane unit. The cationically curable silicone resin includes an epoxy-containing monomeric unit in a proportion of 50 mole percent or more of the totality of all monomeric units and has a number-average molecular weight of 1000 to 3000.

  本发明提供了一种包括硬涂层的异型制品，硬涂层具有较高的表面硬度、柔韧性和耐热性，并具有优异的加工性能。根据本发明的异型制品是一种异型制品，包括硬涂层、基材层和热塑性树脂层，并具有弯曲形状。硬涂层限定了异型制品的最外表面。硬涂层包括可固化组合物的固化产物。固化组合物包括阳离子固化硅树脂和流平剂。阳离子固化硅树脂包括硅倍半氧烷单元。阳离子可固化硅树脂包括含环氧单体单元，其比例为所有单体单元总量的 50 摩尔%或更多，并且具有 1000 至 3000 的数均分子量。
• Method for forming electrophotographic image and electrographic device
  申请人：——

  公开号：US20030138718A1

  公开（公告）日：2003-07-24

  A method for forming an electrophotographic image and a device for forming an image on a transfer material by the steps for charging, exposing, developing and transferring, and recovering the toner remained untransferred in the step for cleaning by recovering, wherein the toner used in the step for developing has a total surface area ratio Z of additive, which is calculated by Z=(Ht·Wt)/(H·W), satisfies 0.5≦Z≦1.5, the electrophotographic photoconductor used comprises at least a photosensitive layer and a filler-containing protective layer provided on a conductive support in that order, and the angle of repose of the toner to the protective layer surface of the electrophotographic photoconductor is 30° or less.

  一种通过充电、曝光、显影和转印步骤在转印材料上形成电子照相图像的方法和在转印材料上形成图像的装置，以及通过回收清洁步骤回收未转印的墨粉，其中在显影步骤中使用的墨粉具有添加剂的总表面积比Z，其计算公式为Z&等于;(Ht-Wt)/(H-W)，满足0.5≦Z≦1.5，所用的电子照相光电导体至少包括一个感光层和一个含填料的保护层，保护层依次设置在导电支架上，墨粉与电子照相光电导体的保护层表面的倾角为30°或更小。
• Blood reservoir, blood delivery instrument, and blood delivery apparatus
  申请人：TERUMO KABUSHIKI KAISHA

  公开号：EP0766974B1

  公开（公告）日：2006-09-06
• Transfer Sheets
  申请人：Sumita Katsuhiko

  公开号：US20080302470A1

  公开（公告）日：2008-12-11

  In a transfer sheet which comprises a support and a transfer layer releasable from the support, the transfer layer comprises (i) an adhesive layer formed on one surface of the support and (ii) a masking layer formed on the adhesive layer and containing a masking agent and a binder resin which may have a crosslinking group, and the transfer layer is adjusted to have an elongation at break of not less than 30% (e.g., 30 to 200%). The masking layer may comprise a white pigment such as a titanium oxide and a urethane-series resin which may have an isocyanate group. The transfer sheet may comprise an image-receiving layer at least containing a urethane-series resin particle formed on the masking layer. Moreover, the transfer sheet may comprise an anchor layer between the masking layer and the image-receiving layer. The transfer layer is capable of recording an image thereon the image being transferred from a recording sheet. These transfer sheets may be used for forming the image on a colored object by transferring to the object.