1-phenyl-3-N-(p-methoxyphenylimino)-1-butanone | 39137-44-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-phenyl-3-N-(p-methoxyphenylimino)-1-butanone
• 英文别名: N-(1-Methyl-2-benzoylethylidene)-4-methoxyaniline；3-(4-methoxyphenyl)imino-1-phenylbutan-1-one
• CAS: 39137-44-5
• 化学式: C₁₇H₁₇NO₂
• 分子量: 267.327
• InChiKey: VXFNYAXDGMQGLW-UHFFFAOYSA-N

物化性质

• 沸点：
  412.4±45.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-phenyl-3-N-(p-methoxyphenylimino)-1-butanone 、 三甲基镓 以 环己烷 、 苯 为溶剂， 以85.2%的产率得到dimethyl[1-phenyl-3-N-(p-methoxyphenylimino)-1-butanonato]gallium
  参考文献：
  名称：

  Synthesis, characterization and luminescence study of dimethyl(β-ketoiminato)gallium (-indium) complexes: crystal structure of dimethyl[1-phenyl-3-N-(4-methoxyphenylimino)-1-butanonato]gallium

  摘要：

  Six dimethylgallium (indium) complexes of type Me2ML [M = Ga, L = 1-phenyl-3-N-(phenylimino)-1-butanonato (1), 1-phenyl-3-N-(p-methoxyphenylimino)-1-butanonato (2), 1-phenyl-3-N-(o-chloro phenylimino)-1-butanonato (3); M = In, L = 1-phenyl-3-N-(phenyl imino)-1-butanonato (4), 1-phenyl-3-N-(p-methoxyphenylimino)-1-butanonato (5), 1-phenyl-3-N-(o-chloro-phenylimino)-1-butanonato (6)] have been synthesized by reaction of trimethylgallium (indium) with appropriate 1-phenyl-3-N-(arylimino)-1-butanones. The complexes obtained have been characterized by elemental analysis, H-1 NMR, IR and mass spectroscopy. Structure of 2 has been determined by X-ray single-crystal analysis, in which Ga atom is four coordinated. Complexes 1-6 emit colors from blue to green (463-491 nm) when irradiated by UV light. The electroluminescent (EL) properties of 1-6 were examined by fabricating EL devices using 1-6 as emitter, respectively. The EL bands are located in the green region (509-522 nm). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.058
• 作为产物：
  描述：

  甲氧苯胺 、 1-苯基-1,3-丁二酮 在 montmorillonite K-10 作用下， 反应 6.0h， 生成 1-phenyl-3-N-(p-methoxyphenylimino)-1-butanone
  参考文献：
  名称：

  Multicomponent reactions leading to symmetric and asymmetric multi-substituted 1,4-dihydropyridines on montmorillonite

  摘要：

  Highly functionalized multi-substituted symmetric and asymmetric 1,4-dihydropyridines were concisely synthesized in moderate to good yields via one-pot multicomponent reactions (MCRs) of beta-dicarbonyl compounds, aldehydes and amines at room temperature on montmorillonite. The merits of this method include the environmentally friendly reaction conditions, simple operation, broad substrate, satisfied yields and the reuse of the montmorillonite. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.04.006