sodium isopropyl sulfate | 52096-25-0

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: sodium isopropyl sulfate
• 英文别名: sodium isopropylsulfate；sulfuric acid monoisopropyl ester; sodium-salt；Schwefelsaeure-monoisopropylester; Natrium-Salz；Sodiumisopropylsulfate；sodium;propan-2-yl sulfate
• CAS: 52096-25-0
• 化学式: C₃H₇O₄S*Na
• 分子量: 162.142
• InChiKey: YHVRBEAAJOBGSQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.12
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335
• 储存条件：
  存于室温下，密封、干燥，并置于惰性气体中。

反应信息

• 作为反应物：
  描述：

  氯化镝(III) 、 sodium isopropyl sulfate 以 乙醇 为溶剂， 生成 dysprosium isopropyl sulfate
  参考文献：
  名称：

  Synthesis and mesogenic properties of azomethine complexes of lanthanides with alkyl sulfate anions

  摘要：

  Liquid-crystalline cationic complexes of lanthanides with azomethines containing the alkyl sulfate anion as the counterion were synthesized. The temperatures of existence of the mesophase of the complexes with the alkyl sulfate anion were by 80-100 degrees C lower than those of similar complexes with the Cl- and NO3- counterions.

  DOI：

  10.1007/bf02494572

文献信息

• ——
  作者：L. V. Malykhina、A. V. Prosvirin、W. Haase、Yu. G. Galyametdinov

  DOI：10.1023/a:1011373510384

  日期：——

  The reaction of Schiff's base L with lanthanide alkylsulfates affords liquid crystalline complexes with the general formula L(3)Ln(CnH2n+1OSO3)(3). The liquid crystalline structure and magnetic proper-ties are studied by polarization thermal microscopy, differential scanning calorimetry, X-ray diffraction, and measurement of magnetic susceptibility. The temperatures of the existence of the mesophase and magnetic anisotropy of the complexes with the same lanthanide depend on the chain length of the alkyl fragment in the Sulfate anion.
• Synthesis and mesogenic properties of azomethine complexes of lanthanides with alkyl sulfate anions
  作者：Yu. G. Galyametdinov、G. I. Ivanova、I. V. Ovchinnikov、K. Binnemans、D. V. Bruce

  DOI：10.1007/bf02494572

  日期：1999.2

  Liquid-crystalline cationic complexes of lanthanides with azomethines containing the alkyl sulfate anion as the counterion were synthesized. The temperatures of existence of the mesophase of the complexes with the alkyl sulfate anion were by 80-100 degrees C lower than those of similar complexes with the Cl- and NO3- counterions.