(2,4-dinitro-phenyl)-o-tolyl sulfide | 33668-00-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (2,4-dinitro-phenyl)-o-tolyl sulfide
• 英文别名: (2,4-Dinitro-phenyl)-o-tolyl-sulfid；2,4-Dinitro-1-<2-methyl-phenylmercapto>-benzol；2,4-Dinitro-<2-methyl-phenylmercapto>-benzol；<2,4-Dinitro-phenyl>-o-tolyl-sulfid；1-(2-methylphenyl)sulfanyl-2,4-dinitrobenzene
• CAS: 33668-00-7
• 化学式: C₁₃H₁₀N₂O₄S
• 分子量: 290.299
• InChiKey: HLECZTWDAHSNOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.96
• 重原子数：
  20.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  86.28
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  (2,4-dinitro-phenyl)-o-tolyl sulfide 在 potassium permanganate 、 溶剂黄146 作用下， 生成 (2,4-dinitro-phenyl)-o-tolyl sulfone
  参考文献：
  名称：

  The Identification of Mercaptans with 2,4-Dinitrochlorobenzene. II

  摘要：

  DOI：

  10.1021/ja01339a040
• 作为产物：
  描述：

  2,4-二硝基苯磺酰氯 在 三甲胺 作用下， 以 四氢呋喃 、 aq. phosphate buffer 、 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 11.02h， 生成 (2,4-dinitro-phenyl)-o-tolyl sulfide
  参考文献：
  名称：

  A rapid and visible colorimetric fluorescent probe for benzenethiol flavor detection

  摘要：

  Benzenethiols are a class of flavoring ingredients used in the food, pharmaceutical, cosmetics and chemical industries. A rapid and visible colorimetric fluorescent probe was developed for the detection of benzenethiol flavors. It provides rapid quantitative detection of benzenethiols at low levels, down to a limit of 10 nM. Test paper containing the probe changes color according to benzenethiol concentration (from colorless to pink, visible with the naked eye). The probe was also successfully used to test benzenethiol concentrations in real food samples. This study demonstrates that this novel probe can be employed as a benzenethiol testing tool.

  DOI：

  10.1016/j.foodchem.2019.02.033

文献信息

• KATIYAR, M.;RANI, S.;GUPTA, S. P., CHIM. ACTA TURC., 1981, 9, N 2, 395-399
  作者：KATIYAR, M.、RANI, S.、GUPTA, S. P.

  DOI：——

  日期：——
• A rapid and visible colorimetric fluorescent probe for benzenethiol flavor detection
  作者：Hao Wang、Xiaoming Wu、Shaoxiang Yang、Hongyu Tian、Yongguo Liu、Baoguo Sun

  DOI：10.1016/j.foodchem.2019.02.033

  日期：2019.7

  Benzenethiols are a class of flavoring ingredients used in the food, pharmaceutical, cosmetics and chemical industries. A rapid and visible colorimetric fluorescent probe was developed for the detection of benzenethiol flavors. It provides rapid quantitative detection of benzenethiols at low levels, down to a limit of 10 nM. Test paper containing the probe changes color according to benzenethiol concentration (from colorless to pink, visible with the naked eye). The probe was also successfully used to test benzenethiol concentrations in real food samples. This study demonstrates that this novel probe can be employed as a benzenethiol testing tool.
• The Identification of Mercaptans with 2,4-Dinitrochlorobenzene. II
  作者：R. W. Bost、J. O. Turner、M. W. Conn

  DOI：10.1021/ja01339a040

  日期：1933.12