5,6-dichloro-2-hexanone | 89581-02-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,6-dichloro-2-hexanone
• 英文别名: Methyl-<3.4-dichlor-butyl>-keton；5,6-dichloro-hexan-2-one；5,6-Dichlorohexan-2-one
• CAS: 89581-02-2
• 化学式: C₆H₁₀Cl₂O
• mdl: MFCD19234550
• 分子量: 169.051
• InChiKey: PDLSFSRYHOPESF-UHFFFAOYSA-N

物化性质

• 沸点：
  55 °C(Press: 0.25 Torr)
• 密度：
  1.143±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.833
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  5-已烯-2-酮 在 草酰氯 、 二苯基亚砜 作用下， 以 二氯甲烷 为溶剂， 以87%的产率得到5,6-dichloro-2-hexanone
  参考文献：
  名称：

  烯烃与二苯亚砜/草酰氯的二氯化

  摘要：

  摘要 利用二苯亚砜和草酰氯的组合实现烯烃的二氯化，提出原位生成的氯二苯锍盐作为氯鎓离子源的真正活性物质。图形概要

  DOI：

  10.1080/00397911.2020.1774901

文献信息

• HYDRAZINE STORAGE RESIN
  申请人：Otsuka Chemical Co., Ltd.

  公开号：EP2042524A1

  公开（公告）日：2009-04-01

  A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.

  在合成树脂的侧链中引入可释放固定肼的酮基、甲酰基、氯甲基或酰胺基等肼固定基团，并将肼固定在肼固定基团上。由于本发明的肼储存树脂具有能够释放肼的肼释放基团，因此能够稳定地储存肼。此外，还可以通过从可释放肼的基团中释放肼来供应肼。因此，肼储存树脂可广泛应用于需要供应肼的各种工业领域。
• Beyer,H. et al., Chemische Berichte, 1962, vol. 95, p. 1989 - 1991
  作者：Beyer,H. et al.

  DOI：——

  日期：——
• DERIVES DE BIS(PERFLUOROSULFONYL)METHANES, LEUR PROCEDE DE PREPARATION, ET LEURS UTILISATIONS
  申请人：Etablissement Public dit: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)

  公开号：EP0567637A1

  公开（公告）日：1993-11-03
• Hydrazine storage resin
  申请人：Taniguchi Masatoshi

  公开号：US20090318662A1

  公开（公告）日：2009-12-24

  A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.
• METHOD FOR STORING A HYDRAZINE RESIN
  申请人：TANIGUCHI Masatoshi

  公开号：US20120121496A1

  公开（公告）日：2012-05-17

  A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.