2,6-dihydroxydecahydronaphthalene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,6-dihydroxydecahydronaphthalene
• 英文别名: decalin-2,6-diol；2,6-Decahydronaphthalenediol；1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene-2,6-diol
• 化学式: C₁₀H₁₈O₂
• mdl: MFCD09751138
• 分子量: 170.252
• InChiKey: OIXGILBUABDWRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,6-dihydroxydecahydronaphthalene 、 在 甲基磺酰氯 、 N,N-二异丙基乙胺 、 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以19.6 g的产率得到
  参考文献：
  名称：

  エステル結合を有するビスフェノール誘導体

  摘要：

  本发明旨在解决的问题是提供一种用于获得具有酯键的化合物的有用制造中间体，以及利用该中间体简便高纯度地获得具有酯键的化合物的制造方法。换言之，本发明提供了具有酯键的双酚衍生物、其制造方法以及作为中间体制造的化合物。此外，通过聚合含有作为中间体制造的双酚衍生物的化合物的聚合性组合物，可获得聚合物，并提供利用该聚合物制备的光学异性体。【解决手段】本申请发明是一种具有酯键的双酚衍生物，其由通式（I-C）表示，并且至少A1和A2中的一个被一个取代基L取代。【选择图】无

  公开号：

  JP2018070546A

文献信息

• Resist lower-layer composition containing thermal acid generator, resist lower layer film-formed substrate, and patterning process
  申请人：Ohsawa Youichi

  公开号：US20100119970A1

  公开（公告）日：2010-05-13

  There is disclosed a resist lower-layer composition configured to be used by a multi-layer resist method used in lithography to form a layer lower than a photoresist layer acting as a resist upper layer film, wherein the resist lower-layer composition becomes insoluble or poorly-soluble in an alkaline developer after formation of the lower layer, and wherein the resist lower-layer composition comprises, at least, a thermal acid generator for generating an acid represented by the general formula (1) by heating at a temperature of 100° C. or higher. RCOO—CH 2 CF 2 SO 3 − H + (1) There can be provided a resist lower-layer composition in a multi-layer resist method (particularly, a two-layer resist method and a three-layer resist method), which composition is used to form a layer lower than a photoresist layer acting as a resist upper layer film, which composition becomes insoluble or poorly-soluble in an alkaline developer after formation of the lower layer, and which composition is capable of forming a resist lower layer film, intermediate-layered film, and the like having a higher anti-poisoning effect and exhibiting a lower load to the environment.

  揭示了一种抗性下层组合物，配置为在光刻中使用的多层抗性方法中使用，用于形成低于作为抗性上层膜的光刻胶层的一层，其中抗性下层组合物在形成下层后变得不溶解或难溶解于碱性显影剂中，且抗性下层组合物至少包括用于通过在100°C或更高温度下加热生成由通式（1）表示的酸的热酸发生剂。 可以提供一种抗性下层组合物，用于多层抗性方法（特别是双层抗性方法和三层抗性方法），该组合物用于形成低于作为抗性上层膜的光刻胶层的一层，该组合物在形成下层后变得不溶解或难溶解于碱性显影剂中，并且该组合物能够形成具有更高抗毒性效果并表现出对环境负荷较低的抗性下层膜、中间层膜等。
• METHOD OF PRODUCING POLYMERIZABLE COMPOUND, AND SOLUTION OF POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20200283399A1

  公开（公告）日：2020-09-10

  Disclosed is a method of producing a polymerizable compound that enables production of, in high yield, a polymerizable compound used for producing an optical film or the like. The disclosed method of producing a polymerizable compound comprises reacting a compound represented by formula (I) with a compound represented by formula (II) in an organic solvent in which a base having a pKa from 6.1 to 9.5 is present, so as to obtain a reaction solution containing a polymerizable compound represented by formula (III).

  公开了一种生产可聚合化合物的方法，该方法能够高产地生产用于制备光学薄膜等的可聚合化合物。所公开的生产可聚合化合物的方法包括在含有具有pKa值在6.1至9.5之间的碱的有机溶剂中，将式(I)所代表的化合物与式(II)所代表的化合物反应，以获得含有式(III)所代表的可聚合化合物的反应溶液。
• Process for preparing monoesters
  申请人：Wicki A. Markus

  公开号：US20050143599A1

  公开（公告）日：2005-06-30

  A process for preparing monoesters comprises the step of reacting at least one diol with at least one carboxylic acid in a biphasic solvent system, the carboxylic acid being sufficiently water soluble to allow esterification to occur, and the biphasic solvent system comprising water and at least one aprotic solvent in which the resulting monoester has greater solubility than in water.

  制备单酯的过程包括在两相溶剂系统中，将至少一种二醇与至少一种羧酸反应的步骤，其中羧酸足够水溶性以允许发生酯化反应，而两相溶剂系统包括水和至少一种无质子溶剂，其中得到的单酯比水具有更大的溶解度。
• OPTICAL FILM
  申请人：Motoyoshi Tetsuya

  公开号：US20110288261A1

  公开（公告）日：2011-11-24

  The object of this invention is to provide an optical film formed of a copolycarbonate having a desired chromatic dispersion and low photoelasticity and having excellent melt processability. The optical film comprises a copolycarbonate composed of 25 to 90 mol % of unit (A) of the following formula, wherein each of R 1 and R 2 is independently a hydrogen atom, a hydrocarbon group having 1 to 10 carbon atoms or a halogen atom, each of R 3 and R 4 is independently a hydrocarbon group having 1 to 10 carbon atoms, each of m and n is independently an integer of 0 to 4, and each of p and q is independently an integer of 0 or more, and 10 to 75 mol % of unit (B) of the following formula, wherein R a is a monocyclic or polycyclic alicyclic hydrocarbon group having 4 to 20 carbon atoms, the alicyclic hydrocarbon group may contain a hetero atom or may have a bridge structure, and q is 0 or 1, the optical film satisfying the following expression (1), R (450)< R (550)< R (650)  (1) wherein R(450), R(550) and R(650) are in-plane retardation values of the film at wavelengths of 450 nm, 550 nm and 650 nm.

  本发明的目的是提供一种光学薄膜，其由具有所需色散和低光弹性以及优异的熔融加工性的共聚碳酸酯形成。该光学薄膜包括由以下式中25至90摩尔％的(A)单元组成的共聚碳酸酯，其中R1和R2各自独立地为氢原子，具有1至10个碳原子的烃基或卤素原子，R3和R4各自独立地为具有1至10个碳原子的烃基，m和n各自独立地为0至4的整数，p和q各自独立地为0或更多的整数，并且由以下式中10至75摩尔％的(B)单元组成，其中Ra是具有4至20个碳原子的单环或多环脂环烃基，脂环烃基可以含有杂原子或具有桥式结构，q为0或1，该光学薄膜满足以下式(1)，R(450)
• Curable epoxy resin composition
  申请人：ASAHI DENKA KOGYO KABUSHIKI KAISHA

  公开号：EP0197458A2

  公开（公告）日：1986-10-15

  A thermosetting epoxy resin composition of one pack type is provided which contains as indispensable constituents (I) an epoxy resin containing more than one adjacent epoxy groups on the average in the molecule and (II) curing amount or curing-accelerating amount of a compound obtained by reacting (a) a specified amine/epoxy adduct with (b) phenolic , resin(s) and/or polyhydric phenol compound(s) in a weight ratio of (a) to (b) of 1/0.1 to 1/0.8. The composition of the present invention has excellent storage stability and it is curable at a relatively low temperature to form a cured product having excellent mechanical strength, adhesiveness and water resistance.

  本发明提供了一种单组分热固性环氧树脂组合物，其不可或缺的成分包括：(I) 分子中平均含有一个以上相邻环氧基团的环氧树脂；(II) 固化量或固化加速量的化合物，该化合物由(a)特定的胺/环氧加合物与(b)酚醛树脂和/或多羟基酚化合物反应而得，(a)与(b)的重量比为 1/0.1 至 1/0.8。本发明的组合物具有极佳的储存稳定性，可在相对较低的温度下固化，形成具有极佳机械强度、粘合性和耐水性的固化产品。