6-pentylheptadecane

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: 6-pentylheptadecane
• 英文别名: Heptadecane, 6-pentyl
• 化学式: C₂₂H₄₆
• 分子量: 310.607
• InChiKey: YFLPDJOGEQEDDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  22
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  5,5'-(dodecane-1,1-diyl)bis(2-methylfuran) 在 氢气 作用下， 以 环己烷 为溶剂， 170.0 ℃ 、5.0 MPa 条件下， 反应 12.0h， 以91%的产率得到6-pentylheptadecane
  参考文献：
  名称：

  FURAN BASED COMPOSITIONS AND METHODS OF MAKING THEREOF

  摘要：

  本文公开了一种从一个或多个生物衍生反应物制备式（I）化合物的过程，并将其用作基础油：（R1-A）b-（CHx）a（CHR2）m-（C（R4R5））n-（CHR3）o-（CHy）c-（A-R1'）d（I），其中a和c独立地为0或1，b和d独立地为1或2，x和y独立地为1或2，取决于a-d的值，m和o独立地为0或1，n为0-6的整数，每个A独立地为不饱和呋喃环，部分饱和呋喃环，饱和呋喃环或-（CH2）4-。此外，R1、R1'、R2、R3、R4和R5独立地选自H和具有1至18个碳原子的烷基基团的群，但其中至少一个R2、R3、R4和R5不是氢，并且式（I）化合物的总碳含量在20-62的范围内。

  公开号：

  US20210040055A1

文献信息

• [EN] RENEWABLE OILS: COMPOSITION, PROCESS OF MAKING AND FORMULATION<br/>[FR] HUILES RENOUVELABLES : COMPOSITION, PROCÉDÉ DE FABRICATION ET FORMULATION
  申请人：RIKARBON INC

  公开号：WO2022093748A1

  公开（公告）日：2022-05-05

  This invention relates to processes for making bio-based renewable oils from non-food biomass sources. Such renewable oils are used for cosmetics formulations. More specifically, disclosed are processes of preparation of furan-based compounds of the formula: (R1-A)a-CH(R2)-CH2-CH(R3)(A-R1)bwherein: a and b are independently 1 or 2 and 0 or 1; A is: independently an unsaturated, a partially hydrogenated, or a fully hydrogenated saturated fur an ring; -(CH2)4-; a saturated fur an ring-opened moiety containing a hydroxyl or a ketonic group: -CH2-CH2-CH2-CH2- OH or -CH2-CH2-CH2-CH=O; or a partially saturated furan-ring opened moiety containing a hydroxyl or a ketonic group: -CH2-CH2- CH=CH-OH or -CH2-CH=CH-CH=O where the position of the double bond is anywhere within the chain; R1, R2, and R3are: independently selected from H, a furan ring, a tetrahydrofuran ring and alky1 groups having carbon atoms of 1 to 18; and the total carbon content of the compound is from 10 to 40.

  本发明涉及从非食品生物质来源制造生物可再生油的过程。这种可再生油用于化妆品配方中。更具体地说，揭示了制备基于呋喃化合物的过程，其化学式为：（R1-A）a-CH（R2）-CH2-CH（R3）（A-R1）b，其中：a和b独立地为1或2和0或1；A独立地为：不饱和的、部分氢化的或完全氢化的饱和呋喃环；-（CH2）4-；含有羟基或酮基的饱和呋喃环开放基团：-CH2-CH2-CH2-CH2-OH或-CH2-CH2-CH2-CH=O；或含有羟基或酮基的部分饱和呋喃环开放基团：-CH2-CH2-CH=CH-OH或-CH2-CH=CH-CH=O，其中双键的位置可以在链的任何地方；R1、R2和R3分别为：H、呋喃环、四氢呋喃环和碳原子为1至18的烷基基团；化合物的总碳含量为10至40。
• COMPOSITION AND PROCESS OF MAKING BIO-BASED UPCYCLED OILS IN FLOW REACTORS
  申请人：[en]RIKARBON, INC.

  公开号：WO2024112439A1

  公开（公告）日：2024-05-30

  Composition and efficient manufacturing processes for making up to 100% bio-based and upcycled renewable oils in batch and flow reactors using raw-materials, sourced from non-food biomass and/or inedible oil seeds/natural oils, is described. The improved manufacturing processes with concurrent removal of process generated water (for RKBA-n) and shorter reaction time and hence reduced overall energy consumption of the manufacturing of products are exemplified. Composition of new bio-based oils containing terminal hydroxyl groups is described.
• FURAN BASED COMPOSITIONS AND METHODS OF MAKING THEREOF
  申请人：UNIVERSITY OF DELAWARE

  公开号：US20210040055A1

  公开（公告）日：2021-02-11

  Disclosed herein are processes for the preparation of compounds of formula (I) from one or more bio-derived reactants, and their use as base oils: (R 1 -A) b -(CH x ) a (CHR 2 ) m —(C(R 4 R 5 )) n —(CHR 3 ) o —(CH y ) c -(A-R 1′ ) d (I) wherein a and c are independently 0 or 1, b and d are independently 1 or 2, x and y are independently 1 or 2, dependent upon the values of a-d, m and o are independently 0 or 1, n is an integer of 0-6, and each A is independently an unsaturated furan ring, a partially saturated furan ring, a saturated furan ring, or —(CH 2 ) 4 —. Also, R 1 , R 1′ , R 2 , R 3 , R 4 and R 5 are independently selected from the group consisting of H and alkyl groups having 1 to 18 carbon atoms, with a proviso that at least one of R 2 , R 3 , R 4 , and R 5 is not hydrogen, and the total carbon content of the compound of formula (I) is in the range of 20-62.

  本文公开了一种从一个或多个生物衍生反应物制备式（I）化合物的过程，并将其用作基础油：（R1-A）b-（CHx）a（CHR2）m-（C（R4R5））n-（CHR3）o-（CHy）c-（A-R1'）d（I），其中a和c独立地为0或1，b和d独立地为1或2，x和y独立地为1或2，取决于a-d的值，m和o独立地为0或1，n为0-6的整数，每个A独立地为不饱和呋喃环，部分饱和呋喃环，饱和呋喃环或-（CH2）4-。此外，R1、R1'、R2、R3、R4和R5独立地选自H和具有1至18个碳原子的烷基基团的群，但其中至少一个R2、R3、R4和R5不是氢，并且式（I）化合物的总碳含量在20-62的范围内。