1-(β-Aminoethyl)benzene Oxide | 73971-96-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 1-(β-Aminoethyl)benzene Oxide
• 英文别名: 2-(7-Oxabicyclo[4.1.0]hepta-2,4-dien-1-yl)ethanamine
• CAS: 73971-96-7
• 化学式: C₈H₁₁NO
• mdl: MFCD19210823
• 分子量: 137.181
• InChiKey: BMUXRGRDNVVGAK-UHFFFAOYSA-N

物化性质

• 沸点：
  223.7±33.0 °C(Predicted)
• 密度：
  1.154±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  38.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(β-Aminoethyl)benzene Oxide 在 sodium azide 作用下， 以 various solvent(s) 为溶剂， 反应 0.75h， 以92%的产率得到2-(2-氨基乙基)苯酚
  参考文献：
  名称：

  Biogenesis of epidithiadiketopiperazines. Synthesis of the three isomeric (.beta.-aminoethyl)benzene oxides

  摘要：

  DOI：

  10.1021/jo01304a002
• 作为产物：
  描述：

  2-(2-(cyclohexa-1,4-dien-1-yl)ethyl)isoindoline-1,3-dione 在 溴 、 间氯过氧苯甲酸 、 肼 、 1,5-Diazabicyclo[5.4.0]undec-5-ene 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 50.5h， 生成 1-(β-Aminoethyl)benzene Oxide
  参考文献：
  名称：

  Biogenesis of epidithiadiketopiperazines. Synthesis of the three isomeric (.beta.-aminoethyl)benzene oxides

  摘要：

  DOI：

  10.1021/jo01304a002

文献信息

• Biologically-based control methods for insect pests
  申请人：The United States of America, as represented by the Secretary of Agriculture

  公开号：US10568320B2

  公开（公告）日：2020-02-25

  The present invention provides novel compositions and methods for using the insect neuromodulator tyramine and/or one or more derivatives thereof delivered to insect populations to control certain aspects of such populations. The amount of tyramine and/or one or more derivatives thereof delivered on a per insect basis is significantly greater than a naturally-occurring amount of tyramine normally found in insects and causes deleterious effects including mortality of certain insect life forms and disruption of the reproductive capacity of others in the population.

  本发明提供了使用昆虫神经调节剂酪胺和/或其一种或多种衍生物投放到昆虫种群以控制此类种群某些方面的新型组合物和方法。按每只昆虫计算，酪胺和/或其一种或多种衍生物的投放量大大高于昆虫体内通常存在的天然酪胺量，并造成有害影响，包括某些昆虫生命形式的死亡和种群中其他昆虫繁殖能力的破坏。
• Cycloaliphatic epoxy compounds containing maleimide functionality
  申请人：Henkel AG & Co. KGaA

  公开号：EP1531166B1

  公开（公告）日：2009-10-07
• BIOLOGICALLY-BASED CONTROL METHODS FOR INSECT PESTS
  申请人：The United States of America, as represented by the Secretary of Agriculture

  公开号：US20180249708A1

  公开（公告）日：2018-09-06

  The present invention provides novel compositions and methods for using the insect neuromodulator tyramine and/or one or more derivatives thereof delivered to insect populations to control certain aspects of such populations. The amount of tyramine and/or one or more derivatives thereof delivered on a per insect basis is significantly greater than a naturally-occurring amount of tyramine normally found in insects and causes deleterious effects including mortality of certain insect life forms and disruption of the reproductive capacity of others in the population.
• [EN] BIOLOGICALLY-BASED CONTROL METHODS FOR INSECT PESTS<br/>[FR] PROCÉDÉS DE LUTTE BIOLOGIQUE CONTRE LES INSECTES NUISIBLES
  申请人：US AGRICULTURE

  公开号：WO2018160802A1

  公开（公告）日：2018-09-07

  The present invention provides novel compositions and methods for using the insect neuromodulator tyramine and/or one or more derivatives thereof delivered to insect populations to control certain aspects of such populations. The amount of tyramine and/or one or more derivatives thereof delivered on a per insect basis is significantly greater than a naturally-occurring amount of tyramine normally found in insects and causes deleterious effects including mortality of certain insect life forms and disruption of the reproductive capacity of others in the population.
• Biogenesis of epidithiadiketopiperazines. Synthesis of the three isomeric (.beta.-aminoethyl)benzene oxides
  作者：William H. Rastetter、Larry J. Nummy

  DOI：10.1021/jo01304a002

  日期：1980.8