3-Methoxy-5-methyl-5-(4-methylpent-3-enyl)cyclohex-2-en-1-one | 1011301-90-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-Methoxy-5-methyl-5-(4-methylpent-3-enyl)cyclohex-2-en-1-one
• CAS: 1011301-90-8
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: WIBHWXCUJRMDIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-Methoxy-5-methyl-5-(4-methylpent-3-enyl)cyclohex-2-en-1-one 、 1-溴-3-甲基-2-丁烯 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 生成 、
  参考文献：
  名称：

  A stereodefined approach towards the bicyclo[3.3.1]nonan-9-one core of the phloroglucin natural products guttiferone A and hypersampsone F

  摘要：

  An approach towards the highly functionalized bicyclo[3.3.1]nonan-9-one core present in the phloroglucin natural products guttiferone A and hypersampsone F is disclosed in which the key C7 and C8 stereogenic centres have been successfully installed. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.12.063
• 作为产物：
  描述：

  甲醇 、 5-methyl-5-(4-methyl-3-penten-1-yl)cyclohexane-1,3-dione 在 四氯化钛 作用下， 反应 1.0h， 以90%的产率得到3-Methoxy-5-methyl-5-(4-methylpent-3-enyl)cyclohex-2-en-1-one
  参考文献：
  名称：

  A stereodefined approach towards the bicyclo[3.3.1]nonan-9-one core of the phloroglucin natural products guttiferone A and hypersampsone F

  摘要：

  An approach towards the highly functionalized bicyclo[3.3.1]nonan-9-one core present in the phloroglucin natural products guttiferone A and hypersampsone F is disclosed in which the key C7 and C8 stereogenic centres have been successfully installed. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.12.063

文献信息

• A stereodefined approach towards the bicyclo[3.3.1]nonan-9-one core of the phloroglucin natural products guttiferone A and hypersampsone F
  作者：Goverdhan Mehta、Mrinal K. Bera、Sandipan Chatterjee

  DOI：10.1016/j.tetlet.2007.12.063

  日期：2008.2

  An approach towards the highly functionalized bicyclo[3.3.1]nonan-9-one core present in the phloroglucin natural products guttiferone A and hypersampsone F is disclosed in which the key C7 and C8 stereogenic centres have been successfully installed. (C) 2007 Elsevier Ltd. All rights reserved.