2,6-Bis-p-azidobenzyliden-cyclohexanon | 20237-98-3

• 物质功能分类: 化学试剂 - 有机试剂 - 叠氮
• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,6-Bis-p-azidobenzyliden-cyclohexanon
• 英文别名: 2,6-bis-[(4-azidophenyl)methylene]-cyclohexanone；2,6-Bis(4-azidobenzylidene)cyclohexanone；(2E,6E)-2,6-bis[(4-azidophenyl)methylidene]cyclohexan-1-one
• CAS: 20237-98-3
• 化学式: C₂₀H₁₆N₆O
• 分子量: 356.387
• InChiKey: UZNOMHUYXSAUPB-UNZYHPAISA-N

物化性质

• 熔点：
  140 °C

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  5

安全信息

• 危险等级：
  4.1

反应信息

• 作为产物：
  描述：

  4-叠氮基苯甲醛 、 环己酮 以58%的产率得到
  参考文献：
  名称：

  BARTOSZEWSKA B.; SZCZEREK I., ORGANIKA. PR. NAUK. INST. PRZEM. ORGAN., 1979. WARSZAWA, 1980, 31-35

  摘要：

  DOI：

文献信息

• Polymerizable composition and formed article using the same
  申请人：Kodemura Junji

  公开号：US20060211809A1

  公开（公告）日：2006-09-21

  A polymerizable composition which comprises a cycloolefin monomer (A), a filler (B), a polymer (C) having a carboxyl group or a carboxylic acid anhydride group and having an acid value of 0.1 to 100 mgKOH/g, and a metathesis polymerization catalyst (D). The polymerizable composition comprises a cycloolefin monomer and a large amount of a filler, and has a low viscosity and is excellent in fluidity, and further can provide a molded product which is excellent in the lowness of dielectric constant, the lowness of dielectric loss tangent, the lowness of linear expansion coefficient, high heat resistance and adhesiveness, and further is free of bubble inclusion.

  一种可聚合的组合物，包括环烯烃单体（A）、填料（B）、具有羧基或羧酸酐基团且酸值为0.1至100 mgKOH/g的聚合物（C），以及一种交换聚合催化剂（D）。该可聚合组合物包括环烯烃单体和大量填料，具有低粘度和优异的流动性，并且能够提供优异的介电常数低、介电损耗正切低、线性膨胀系数低、高耐热性和粘附性的成型产品，且无气泡包含。
• NITROXIDE CONTAINING ELECTRODE MATERIALS FOR SECONDARY BATTERIES
  申请人：Nesvadba Peter

  公开号：US20100181527A1

  公开（公告）日：2010-07-22

  This invention relates to a stable secondary battery utilizing as active principle the oxidation and reduction cycle of a sterically hindered nitroxide radical, a sterically hindered oxoammonium cation, a sterically hindered hydroxylamine or a sterically hindered aminoxide anion containing a piperazin-2,6-dione, a piperazin-2-one or morpholin-2-one structural unit. Further aspects of the invention are a method for providing such a secondary battery, the use of the respective compounds as active elements in secondary batteries and selected novel compounds.

  本发明涉及一种稳定的二次电池，利用空间位阻的亚硝基自由基、空间位阻的氧代铵阳离子、空间位阻的羟胺或空间位阻的氨氧阴离子，其中包含哌嗪-2,6-二酮、哌嗪-2-酮或吗啉-2-酮结构单元的氧化还原循环作为活性原理。发明的其他方面包括提供这种二次电池的方法，使用相应化合物作为二次电池中的活性元素以及选择的新化合物。
• DIVERSITY-ORIENTED POLYMERS OF INTRINSIC MICROPOROSITY AND USES THEREOF
  申请人：The Regents of the University of California

  公开号：US20210309802A1

  公开（公告）日：2021-10-07

  The present disclosure is directed to raicroporous ladder polymers containing amine-functionalized monomer segments, amidoxime-functionalized monomer segments, or a combination thereof. Monomer compounds for preparation of the polymers are also described, as well as membranes and electrochemical cells containing the polymers.

  本公开涉及含有胺基化单体段、酰胺肟化单体段或两者组合的多孔梯形聚合物。还描述了用于制备聚合物的单体化合物，以及包含聚合物的膜和电化学电池。
• Insulating material containing cycloolefin polymer
  申请人：——

  公开号：US20040157039A1

  公开（公告）日：2004-08-12

  An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 &mgr;m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.

  一种绝缘材料，包括环氧烷基聚合物，具体地说，这是一种用于高密度组装板的层间绝缘材料，其间层连接的经孔直径最多为200微米，包括至少50摩尔％来自环氧烷基单体的重复单元的环氧烷基聚合物; 由可固化树脂组成的可干膜，其聚合物的数量平均分子量在1,000至1,000,000之间（通过凝胶渗透色谱法测量），以及硬化剂; 以及通过在金属箔的一侧形成环氧烷基聚合物膜而获得的树脂附着金属箔。利用这些材料制成的层压板，多层层压板和堆叠多层层压板以及其生产工艺。
• Bioadhesive Composition Formed Using Click Chemistry
  申请人：Kapiamba Mbiya

  公开号：US20090247651A1

  公开（公告）日：2009-10-01

  The present disclosure provides compositions which may be utilized as adhesives or sealants in medical and surgical applications. The compositions may, in embodiments, be formed from the cycloaddition reaction of a first component possessing at least one azide group with a second component possessing at least one alkyne group.

  本公开提供的组合物可用作医疗和外科应用中的粘合剂或密封剂。这些组合物可以通过第一组分至少具有一个偶氮基团的环加成反应与第二组分至少具有一个炔基团的反应产生，以实现某些实施方式下的形成。

表征谱图