(1S,2R)-2-(cyclohexen-1-yl)cyclohexan-1-ol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1S,2R)-2-(cyclohexen-1-yl)cyclohexan-1-ol
• 化学式: C₁₂H₂₀O
• 分子量: 180.29
• InChiKey: AWDPUMYRKBQMIL-NEPJUHHUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(1-环己烯基)环己酮 、 甲醇 、 硼氢化钠 生成 (1S,2R)-2-(cyclohexen-1-yl)cyclohexan-1-ol
  参考文献：
  名称：

  BELL, THOMAS W.;VARGAS, J. RAMON;CRISPINO, GERARD A., J. ORG. CHEM., 54,(1989) N, C. 1978-1987

  摘要：

  DOI：

文献信息

• COMPLEX CATALYSTS BASED ON AMINO-PHOSPHINE LIGANDS FOR HYDROGENATION AND DEHYDROGENATION PROCESSES
  申请人：GOUSSEV Dmitri

  公开号：US20160023200A1

  公开（公告）日：2016-01-28

  The present application discloses novel PWNN and PWNWP metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, enals, enones, enolates, oils and fats, resulting in alcohols, enols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.