2,9-Dimethyl-4,7-diphenyl-4a,10b-dihydro-1,10-phenanthroline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,9-Dimethyl-4,7-diphenyl-4a,10b-dihydro-1,10-phenanthroline
• 英文别名: 2,9-dimethyl-4,7-diphenyl-4a,10b-dihydro-1,10-phenanthroline
• 化学式: C₂₆H₂₂N₂
• 分子量: 362.5
• InChiKey: ZRPQGIMKPJNRHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• HETEROLEPTIC IRIDIUM CARBENE COMPLEXES AND LIGHT EMITTING DEVICE USING THEM
  申请人：Universal Display Corporation

  公开号：EP3178832A1

  公开（公告）日：2017-06-14

  The invention is directed to the use of a compound comprising a heteroleptic iridium complex having the formula: wherein X is selected from the group consisting of CRR', SiRR', C=O, N-R, B-R, O, S, SO, SO2, and Se; wherein R2, Rx, R5, and R6 represent mono, di, tri, tetra substitutions or no substitution; wherein R, R', R1, R2, Rx, R4, R5, and R6 are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;wherein any two adjacent substituents are optionally joined together to form a ring; and wherein n is 1 or 2, as an emitters in an organic light emitting device.

  本发明涉及一种化合物的用途，该化合物包含具有以下式子的杂烯丙基铱络合物： 其中X选自由CRR'、SiRR'、C＝O、N-R、B-R、O、S、SO、SO2和Se组成的组；其中R2、Rx、R5和R6代表单取代、二取代、三取代、四取代或无取代；其中 R、R'、R1、R2、Rx、R4、R5 和 R6 各自独立地选自氢、氘、卤化物、烷基、环烷基、杂烷基、芳烷基、烷氧基、芳氧基、氨基、硅烷基、烯烷基、炔烷基、炔烃基和炔烃基组成的组、硅烷基、烯基、环烯基、杂烯基、炔基、芳基、杂芳基、酰基、羰基、羧酸、酯、腈、异腈、硫酰基、亚砜基、磺酰基、膦基及其组合；其中任意两个相邻取代基可选择连接在一起形成一个环；其中 n 为 1 或 2，作为有机发光器件中的发光体。
• OLED COMPRISING ORGANIC COMPOUNDS CONTAINING B-N HETEROCYCLES
  申请人：Universal Display Corporation

  公开号：EP3470494A1

  公开（公告）日：2019-04-17

  In certain embodiments, the invention provides devices, such as organic light emitting devices, that comprise boron-nitrogen heterocycles having Formula (I): wherein one of the E1 and E2 is N, and one of the E1 and E2 is B; wherein E3 and E4 is carbon; wherein ring Y and ring Z are 5-membered or 6-membered carbocyclic or heterocyclic aromatic ring fused to ring X; wherein R2 and R3 represent mono, di, tri, tetra substitutions or no substitution; wherein R2 and R3 are each independently selected from various substituents; and wherein any two adjacent R2, and R3 are optionally joined to form a ring, which may be further substituted.

  在某些实施例中，本发明提供了包含具有式（I）的硼氮杂环的器件，如有机发光器件： 其中 E1 和 E2 中的一个是 N，E1 和 E2 中的一个是 B；其中 E3 和 E4 是碳；其中环 Y 和环 Z 是与环 X 融合的 5 元或 6 元碳环或杂环芳香环；其中 R2 和 R3 代表单取代、二取代、三取代、四取代或无取代；其中 R2 和 R3 各自独立地选自各种取代基；以及其中任意两个相邻的 R2 和 R3 任选连接形成环，该环可进一步被取代。
• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：University of Southern California

  公开号：US20180033977A1

  公开（公告）日：2018-02-01

  A compound having a structure according to formula (I) is disclosed. In formula (I), Cu is a monovalent copper atom; *C is a carbene carbon; X 1 and X 2 are selected from alkyl, cycloalkyl, alkoxy, amino, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, heteroalkynyl, arylalkyl, aryloxy, aryl, heteroalkyl, heteroaryl, and combinations thereof; X 1 is bonded to *C by a C atom, and X 2 is bonded to *C by an N atom; X 1 and X 2 are optionally joined to form a ring; and Y is selected halide, alkyl, cycloalkyl, alkoxy, amino, phosphine, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, heteroalkynyl, arylalkyl, aryloxy, aryl, heteroalkyl, heteroaryl, and combinations thereof. A formulation containing compound having a structure according to formula (I), and a device with an organic layer comprising disposed between an anode and a cathode, that includes a compound having a structure according to formula (I) are also described.
• US9812656B2
  申请人：——

  公开号：US9812656B2

  公开（公告）日：2017-11-07