1-Allyloxy-2-pentoxy-ethan | 18854-53-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Allyloxy-2-pentoxy-ethan
• 英文别名: 3-(2-pentyloxy-ethoxy)-propene；1-(2-Prop-2-enoxyethoxy)pentane；1-(2-prop-2-enoxyethoxy)pentane
• CAS: 18854-53-0
• 化学式: C₁₀H₂₀O₂
• 分子量: 172.268
• InChiKey: BAUKCLLKQIBXPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(戊氧基)乙醇 、 3-溴丙烯 生成 1-Allyloxy-2-pentoxy-ethan
  参考文献：
  名称：

  Mikhant'ev,B.I. et al., Journal of Organic Chemistry USSR (English Translation), 1972, vol. 8, p. 450 - 452

  摘要：

  DOI：

文献信息

• Process for the preparation of cyclic esters and method for purification of the same
  申请人：——

  公开号：US20030191326A1

  公开（公告）日：2003-10-09

  The present invention provides a process for production of a cyclic ester by depolymerization of an aliphatic polyester. In the process, a mixture containing the aliphatic polyester and a specific polyalkylene glycol ether, which has a boiling point of 230-450° C. and a molecular weight of 150-450, is heated under normal or reduced pressure to a temperature at which depolymerization of the aliphatic polyester takes place. Then, a substantially homogeneous solution phase, consisting of the melt phase of the aliphatic polyester and the liquid phase of the polyalkylene glycol ether, is formed. Heating of the solution phase is continued to form the cyclic ester by depolymerization and distil out the cyclic ester together with the polyalkylene glycol ether, and then the cyclic ester is recovered from the distillate. The present invention also provides a process for purification of a crude cyclic ester by use of the specific polyalkylene glycol ether described above.

  本发明提供了一种通过脂肪族聚酯的降解来生产环酯的方法。在该过程中，将含有脂肪族聚酯和具有沸点在230-450°C和分子量在150-450之间的特定聚烷基乙二醇醚的混合物，在常压或减压下加热至脂肪族聚酯发生降解的温度。然后，形成由脂肪族聚酯的熔融相和聚烷基乙二醇醚的液相组成的基本均相溶液相。继续加热溶液相以通过降解形成环酯并与聚烷基乙二醇醚一起蒸馏出环酯，然后从馏出物中回收环酯。本发明还提供了一种利用上述特定聚烷基乙二醇醚对粗环酯进行纯化的方法。
• Spectrally sensitized silver halide emulsions
  申请人：AGFA-GEVAERT naamloze vennootschap

  公开号：EP0427892A1

  公开（公告）日：1991-05-22

  Method of forming a silver image by exposing a silver halide emulsion spectrally sensitized with a trinuclear merocyanine dye to light of 600-690 nm and wet-processing the emulsion with aqueous developing or activating solution and fixing solution, thereby dissolving away said dye from the resulting silver-image-containing material, said trinuclear merocyanine dye comprising at least 2 water-solubilizing groups.

  将使用三核梅洛菁染料分光感光的卤化银乳剂曝光于 600-690 纳米的光下，然后用显影或活化水溶液和定影水溶液对乳剂进行湿处理，从而将所述染料从生成的含银图像材料中溶解掉，从而形成银图像的方法，所述三核梅洛菁染料包括至少 2 个水溶解基团。
• PROCESS FOR THE PREPARATION OF CYCLIC ESTERS AND METHOD FOR PURIFICATION OF THE SAME
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP1310496A1

  公开（公告）日：2003-05-14

  The present invention provides a process for production of a cyclic ester by depolymerization of an aliphatic polyester. In the process, a mixture containing the aliphatic polyester and a specific polyalkylene glycol ether, which has a boiling point of 230-450°C and a molecular weight of 150-450, is heated under normal or reduced pressure to a temperature at which depolymerization of the aliphatic polyester takes place. Then, a substantially homogeneous solution phase, consisting of the melt phase of the aliphatic polyester and the liquid phase of the polyalkylene glycol ether, is formed. Heating of the solution phase is continued to form the cyclic ester by depolymerization and distil out the cyclic ester together with the polyalkylene glycol ether, and then the cyclic ester is recovered from the distillate. The present invention also provides a process for purification of a crude cyclic ester by use of the specific polyalkylene glycol ether described above.

  本发明提供了一种通过脂肪族聚酯解聚生产环酯的工艺。在该工艺中，将含有脂肪族聚酯和特定聚亚烷基乙二醇醚（沸点为 230-450°C，分子量为 150-450）的混合物在常压或减压下加热至脂肪族聚酯发生解聚的温度。然后形成基本均匀的溶液相，该溶液相由脂肪族聚酯的熔体相和聚亚烷基二醇醚的液相组成。继续加热溶液相，通过解聚作用形成环酯，并将环酯和聚烷基乙二醇醚一起蒸馏出来，然后从蒸馏物中回收环酯。本发明还提供了一种通过使用上述特定聚亚烷基二醇醚提纯粗环酯的工艺。
• METHOD FOR PRODUCING GLYCOLIDE
  申请人：Kureha Corporation

  公开号：EP2377858A1

  公开（公告）日：2011-10-19

  The invention provides a production process of glycolide comprising the respective steps of: Step 1 of heating a mixture containing a glycolic acid oligomer and a high boiling polar organic under normal or reduced pressure to reflux the mixture and at that time, conducting a total reflux operation in a reflux time within a range of 0.1 to 20 hours under conditions that substantially the whole amount of a distillate distilled out of a reflux system containing the mixture is refluxed into the reflux system; Step 2 of heating the mixture after the total reflux operation or a mixture obtained by adding the high boiling polar organic solvent to a glycolic acid oligomer component recovered from the mixture after the total reflux operation to conduct depolymerization; and Step 3 of collecting glycolide from a co-distillate.

  本发明提供了一种羟基乙酸的生产工艺，包括以下步骤：步骤 1 在常压或减压下加热含有羟基乙酸低聚物和高沸点极性有机物的混合物，使混合物回流，然后进行全回流操作，回流时间在 0.1至20小时的条件下，从含有该混合物的回流系统中蒸馏出的蒸馏物基本上全部回流到该回流系统中；步骤2加热全回流操作后的混合物或将高沸点极性有机溶剂加入到全回流操作后从该混合物中回收的乙醇酸低聚物组分而得到的混合物，以进行解聚；以及步骤3从共蒸馏物中收集乙二醇醚。
• Acetoacetate polymer coated aldehyde renoval filter
  申请人：Eastman Chemical Company

  公开号：EP2412422A1

  公开（公告）日：2012-02-01

  Disclosed are filter elements constructed of a filter support material coated with an acetoacetate-functional polymeric composition that reacts with and removes aldehydes, especially formaldehyde, present in gases such as air. Also disclosed are methods for the removal of aldehydes utilizing the coated filter support materials.

  所公开的过滤元件是由涂有乙酰乙酸酯功能聚合物组合物的过滤支撑材料制成的，该组合物能与空气等气体中的醛类物质，特别是甲醛发生反应并去除醛类物质。此外，还公开了利用涂层过滤支撑材料去除醛的方法。