Ethanol;pent-4-en-1-ol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Ethanol;pent-4-en-1-ol
• 英文别名: ethanol;pent-4-en-1-ol
• 化学式: C7H16O2
• 分子量: 132.2
• InChiKey: ZAMBYIMTGIPJIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.94
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• [EN] Z-SELECTIVE METATHESIS CATALYSTS<br/>[FR] CATALYSEURS DE MÉTATHÈSE SÉLECTIFS POUR Z
  申请人：CALIFORNIA INST OF TECHN

  公开号：WO2014093687A1

  公开（公告）日：2014-06-19

  A novel chelated ruthenium-based metathesis catalyst bearing an N-2,6- diisopropylphenyl group is reported and displays near-perfect selectivity for the Z-olefin (>95%), as well as unparalleled TONs of up to 7,400, in a variety of homodimerization and industrially relevant metathesis reactions. This derivative and other new catalytically-active species were synthesized using an improved method employing sodium carboxylates to induce the salt metathesis and C-H activation of these chelated complexes. All of these new ruthenium-based catalysts are highly Z-selective in the homodimerization of terminal olefins.

  报告了一种含有N-2,6-二异丙基苯基团的新型螯合钌基烯烃复分解催化剂，该催化剂在多种同二聚和工业相关复分解反应中表现出对Z-烯烃的高选择性（>95%），并且具有无与伦比的转化数（TONs）高达7,400。使用改进的方法合成了这种衍生物和其他新的催化活性物种，该方法使用钠羧酸盐诱导这些螯合配合物的盐复分解和C-H活化。所有这些新的钌基催化剂在端烯烃的同二聚反应中都具有高度Z选择性。
• Z-SELECTIVE METATHESIS CATALYSTS
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US20150299236A1

  公开（公告）日：2015-10-22

  A novel chelated ruthenium-based metathesis catalyst bearing an N-2,6-diisopropylphenyl group is reported and displays near-perfect selectivity for the Z-olefin (>95%), as well as unparalleled TONs of up to 7,400, in a variety of homodimerization and industrially relevant metathesis reactions. This derivative and other new catalytically-active species were synthesized using an improved method employing sodium carboxylates to induce the salt metathesis and C—H activation of these chelated complexes. All of these new ruthenium-based catalysts are highly Z-selective in the homodimerization of terminal olefins.
• US9586981B2
  申请人：——

  公开号：US9586981B2

  公开（公告）日：2017-03-07