3,14,25-Trioxa-11,17,31-triazatetracyclo[25.3.1.04,9.019,24]hentriaconta-1(31),4,6,8,10,17,19,21,23,27,29-undecaene | 146065-62-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,14,25-Trioxa-11,17,31-triazatetracyclo[25.3.1.04,9.019,24]hentriaconta-1(31),4,6,8,10,17,19,21,23,27,29-undecaene
• CAS: 146065-62-5
• 化学式: C₂₅H₂₅N₃O₃
• 分子量: 415.492
• InChiKey: DSHVOUCGIOLILK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  31
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  65.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  neodymium(III) nitrate hexahydrate 、 3,14,25-Trioxa-11,17,31-triazatetracyclo[25.3.1.04,9.019,24]hentriaconta-1(31),4,6,8,10,17,19,21,23,27,29-undecaene 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Infrared Luminescence of Neodymium in Complexes with Macrocyclic Schiff Bases

  摘要：

  The 4f-luminescence of neodymium in complexes with macrocyclic Schiff bases was studied. Relation between the type of the macrocyclic ligand and the luminescence efficiency was examined. The luminescence intensity depends on the number of chromophoric aromatic fragments in the ligand, that act as i.e. as accumulators of excitation energy.

  DOI：

  10.1023/b:rugc.0000016038.79975.48
• 作为产物：
  描述：

  2,6-Bis(2-formylphenoxymethyl)pyridine 、 2,2'-氧双(乙胺) 以 甲苯 为溶剂， 以40%的产率得到3,14,25-Trioxa-11,17,31-triazatetracyclo[25.3.1.04,9.019,24]hentriaconta-1(31),4,6,8,10,17,19,21,23,27,29-undecaene
  参考文献：
  名称：

  Kamalov, G. L.; Zakolodyashnaya, O. V.; Manolova, A. V., Journal of general chemistry of the USSR, 1992, vol. 62, # 6.2, p. 1147 - 1153

  摘要：

  DOI：

文献信息

• The synthesis and crystal structure of a cerium(III) complex of 2,6-bis[2-formylphenoxymethyl]pyridine
  作者：Neil A. Bailey、Cecilia O. Rodriquez de Barbarin、David E. Fenton、Yuh-Shan Ho、Gareth J. Humber

  DOI：10.1016/0020-1693(94)04371-2

  日期：1995.4

  Abstract The synthesis and X-ray crystal structure of a ten-coordinate cerium(III) nitrate complex of 2,6-bis[2-formylphenoxymethyl]-pyridine is reported.

  摘要报道了2,6-双[2-甲酰基苯氧基甲基]-吡啶的十配位硝酸铈（III）配合物的合成及X射线晶体结构。
• Infrared Luminescence of Neodymium in Complexes with Macrocyclic Schiff Bases
  作者：Yu. V. Korovin、R. N. Lozitskaya、N. V. Rusakova

  DOI：10.1023/b:rugc.0000016038.79975.48

  日期：2003.10

  The 4f-luminescence of neodymium in complexes with macrocyclic Schiff bases was studied. Relation between the type of the macrocyclic ligand and the luminescence efficiency was examined. The luminescence intensity depends on the number of chromophoric aromatic fragments in the ligand, that act as i.e. as accumulators of excitation energy.
• Kamalov, G. L.; Zakolodyashnaya, O. V.; Manolova, A. V., Journal of general chemistry of the USSR, 1992, vol. 62, # 6.2, p. 1147 - 1153
  作者：Kamalov, G. L.、Zakolodyashnaya, O. V.、Manolova, A. V.、Lozitskaya, R. N.、Gavsevich, Yu. V.

  DOI：——

  日期：——