5-降冰片烯-2-异丙醇 | 22497-08-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 5-降冰片烯-2-异丙醇
• 中文别名: 2-(6-双环[2.2.1]-2-庚烯)-2-丙醇
• 英文名称: 2-(bicyclo[2.2.1]hept-5-en-2-yl)propan-2-ol
• 英文别名: 2-bicyclo[2.2.1]hept-5-en-2-ylpropan-2-ol；5-(α-Hydroxy-isopropyl)-bicyclo<2.2.1>hepten-(2)；5-(α-Hydroxy-isopropyl)-bicyclo[2.2.1]hepten-(2)；2-(5-Bicyclo[2.2.1]hept-2-enyl)propan-2-ol；2-(2-bicyclo[2.2.1]hept-5-enyl)propan-2-ol
• CAS: 22497-08-1
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: AJWQZRWCWAFUNX-UHFFFAOYSA-N

物化性质

• 沸点：
  213.1±9.0 °C(Predicted)
• 密度：
  1.044±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2906199090

反应信息

• 作为反应物：
  描述：

  5-降冰片烯-2-异丙醇 在 乙酸酐 作用下， 生成 5-Isopropylidene-2-norbornene
  参考文献：
  名称：

  Sopow, Zhurnal Obshchei Khimii, 1955, vol. 25, p. 2082,2087; engl. Ausg. S. 2035, 2040

  摘要：

  DOI：
• 作为产物：
  描述：

  5-降冰片烯-2-羧酸乙酯 、 甲基氯化镁 生成 5-降冰片烯-2-异丙醇
  参考文献：
  名称：

  PAYNE, G. B.

  摘要：

  DOI：

文献信息

• Enantioselective Diels−Alder Reactions with <i>N</i>-Hydroxy-<i>N</i>-phenylacrylamide
  作者：Olivier Corminboeuf、Philippe Renaud

  DOI：10.1021/ol025799t

  日期：2002.5.1

  [reaction: see text] The use of hydroxamic acids as templates for Lewis acid catalyzed enantioselective Diels-Alder reactions has been examined. A very simple chiral Lewis acid, prepared by mixing optically pure binaphthol with 3 equiv of trimethylaluminum, catalyzes the [4 + 2] cycloaddition of N-hydroxy-N-phenylacrylamide with cyclopentadiene at 0 degrees C in high yield (>96%) and with a fairly

  [反应：见正文]研究了使用异羟肟酸作为路易斯酸催化的对映选择性Diels-Alder反应的模板。通过将光学纯的联萘酚与3当量的三甲基铝混合而制得的非常简单的手性路易斯酸，可在0℃以高收率（> 96％）催化N-羟基-N-苯基丙烯酰胺与环戊二烯的[4 + 2]环加成反应，并且具有相当好的对映选择性（91％ee）。产物向相应的醇或醛的容易转化使得异羟肟酸中间体特别有用。
• GENERATION OF ENDO- AND/OR EXO-NORBORNENECARBOXALDEHYDE AS AN INTERMEDIATE TO FUNCTIONALIZED NORBORNENES
  申请人：Bell Andrew

  公开号：US20090118539A1

  公开（公告）日：2009-05-07

  Embodiments in accordance with the present invention provide for forming essentially pure diastereomers of 5/6-substituted norbornene-type monomers. Further, embodiments in accordance with the present invention encompass polymerizing such diastereomers to form addition or ROMP polymers where a desired exo-/endo-ratio of the diastereomers is provided to the polymerization, such ratio designed to provide a desired ratio of endo-/exo-structured repeating units for a resulting polymer to have desired physical or chemical properties.

  根据本发明的实施例，提供形成基本纯的5/6-取代去氢莰烯型单体的异构体。此外，根据本发明的实施例涵盖聚合这种异构体以形成加成或ROMP聚合物，其中所提供给聚合反应的异构体的期望外/内比例设计为提供所得聚合物具有期望的物理或化学性质的外/内结构重复单元的期望比例。
• Insulating material containing cycloolefin polymer
  申请人：——

  公开号：US20040157039A1

  公开（公告）日：2004-08-12

  An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 &mgr;m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.

  一种绝缘材料，包括环氧烷基聚合物，具体地说，这是一种用于高密度组装板的层间绝缘材料，其间层连接的经孔直径最多为200微米，包括至少50摩尔％来自环氧烷基单体的重复单元的环氧烷基聚合物; 由可固化树脂组成的可干膜，其聚合物的数量平均分子量在1,000至1,000,000之间（通过凝胶渗透色谱法测量），以及硬化剂; 以及通过在金属箔的一侧形成环氧烷基聚合物膜而获得的树脂附着金属箔。利用这些材料制成的层压板，多层层压板和堆叠多层层压板以及其生产工艺。
• Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
  申请人：Goodall Leslie Brian

  公开号：US20050043494A1

  公开（公告）日：2005-02-24

  A catalytic composition, including a cationic metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.

  本发明公开了一种催化组合物，包括阳离子金属配对复合物，以及其制备方法。本发明还公开了使用该催化组合物聚合乙烯类不饱和单体的方法，以及由此产生的加成聚合物。
• Negative Resists Based on Acid-Catalyzed Elimination of Polar Molecules
  申请人：Allen Robert David

  公开号：US20080233517A1

  公开（公告）日：2008-09-25

  The present invention provides polymers that are useful in negative resist compositions. Polymers of the present invention comprise (1) a first monomer having a polar functional group; (2) a second monomer; and optionally, (3) a third monomer that imparts at least one characteristic selected from crosslinkable functionality, etch resistance, and solubility modulation. The first monomer provides an acid catalyzed polarity switch upon elimination of the polar functional group, whereas, the second monomer provides aqueous dissolution. The polymers of the present invention may be incorporated into negative resist compositions, which may also include photoacid generators, crosslinking agents, basic compounds, solvents, dissolution accelerators, photobase generators, latent basic compounds, surfactants, adhesion promoters, and anti-foaming agents.

  本发明提供了在负型光刻胶组成中有用的聚合物。本发明的聚合物包含（1）具有极性官能团的第一单体；（2）第二单体；以及可选地，（3）赋予至少一种特性的第三单体，所述特性从可交联功能、蚀刻抗性和溶解度调节中选择。第一单体在极性官能团消除时提供酸催化极性转换，而第二单体提供水溶解性。本发明的聚合物可以被纳入负型光刻胶组成中，该组成物还可以包括光酸发生剂、交联剂、碱性化合物、溶剂、溶解加速剂、光碱发生剂、潜在碱性化合物、表面活性剂、粘附剂和抗泡剂。