6,6-二乙氧基-己-1-烯 | 761-59-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 6,6-二乙氧基-己-1-烯
• 英文名称: 6,6-diethoxy-hex-1-ene
• 英文别名: 6,6-Diethoxyhex-1-ene
• CAS: 761-59-1
• 化学式: C₁₀H₂₀O₂
• mdl: MFCD11554517
• 分子量: 172.268
• InChiKey: WRDVRNIPMDDMJM-UHFFFAOYSA-N

物化性质

• 沸点：
  84 °C(Press: 20 Torr)
• 密度：
  0.853±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6,6-二乙氧基-己-1-烯 生成 5-己烯醛
  参考文献：
  名称：

  Julia,M.; Dostert,P., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1964, vol. 259, p. 2872 - 2875

  摘要：

  DOI：
• 作为产物：
  描述：

  原甲酸三乙酯 、 alkaline earth salt of/the/ methylsulfuric acid 生成 6,6-二乙氧基-己-1-烯
  参考文献：
  名称：

  Julia,M.; Dostert,P., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1964, vol. 259, p. 2872 - 2875

  摘要：

  DOI：

文献信息

• Reactions of 1,2-Bis(trimethylsilyloxy)cycloalkenes with the Diethyl Acetals of Aldehydes
  作者：Fuye Gao、D. Jean Burnell

  DOI：10.1021/jo051683+

  日期：2006.1.1

  Lewis acid-mediated reactions of 1,2-bis(trimethylsilyloxy)cyclobutene with acetals derived from a variety of aldehydes, followed by treatment with Amberlyst 15 resin in TFA, yielded 1,3-cyclopentanedione products, but reactions with 3,3-dimethyl-1,2-bis(trimethylsilyloxy)cyclobutene led to 1,2-cyclopentanediones. Reactions of 1,2-bis(trimethylsilyloxy)cyclopentene gave intermediates that did not undergo

  路易斯酸介导的1,2-双（三甲基甲硅烷氧基）环丁烯与衍生自多种醛的缩醛的反应，然后在TFA中用Amberlyst 15树脂处理，得到1,3-环戊二酮产品，但与3,3-二甲基反应-1,2-双（三甲基甲硅烷氧基）环丁烯生成1,2-环戊二酮。1,2-双（三甲基甲硅烷氧基）环戊烯的反应生成的中间体在TFA中与Amberlyst 15树脂没有发生骨架重排。
• Metathesis syntheses of pheromones or their components
  申请人：——

  公开号：US20020022741A1

  公开（公告）日：2002-02-21

  The present invention relates to metathesis syntheses for insect sex-attractant pheromones or their components, such as E-5-decenyl acetate, the major component of the Peach Twig Borer pheromone; (5R, 6S)-6-acetoxy-5-hexadecanolide, the mosquito oviposition attractant pheromone; E9, Z11-hexadecadienal, the pecan nut casebearer moth pheromone; 9-tetradecenyl formate, an analog of the Diamondback Moth (DBM) pheromone; 11-tetradecenyl acetate, the Omnivorous Leafroller (OLR) pheromone; E-4-tridecenyl acetate, the major component of the Tomato Pinworm (TPW) pheromone; E,E-8,10-dodecadienol, the Codling Moth (CM) pheromone. The syntheses preferably employ a Class I-IV metathesis catalyst, entail few reaction steps, use generally commercially available starting materials, and have relatively short process times. These syntheses produce good yields without the need for expensive or sophisticated equipment. The invention also provides an inexpensive route for producing omega-haloalkenols by cross-metathesizing alpha-omega-diacetoxy alkenes and alpha-omega-dihalides to yield omega-haloalkenols, which are easily converted into omega-haloalkanols under traditional hydrogenation methods.

  本发明涉及对昆虫性诱素或其组分进行交换合成，如E-5-癸烯醇醋酸酯，桃枝蠕蛾性信息素的主要成分；（5R, 6S）-6-乙酰氧基-5-十六醇内酯，蚊子产卵引诱素；E9, Z11-癸二烯醛，山核桃果蛾性信息素；9-十四烯酸甲酯，菜青虫性信息素的类似物；11-十四烯醇醋酸酯，杂食卷叶蛾性信息素；E-4-十三烯醇醋酸酯，番茄针孔螟性信息素的主要成分；E,E-8,10-十二二烯醇，苹果蛾性信息素。这些合成通常采用I-IV类交换催化剂，步骤较少，使用通常易得的起始物质，并具有相对较短的工艺时间。这些合成产量良好，无需昂贵或复杂的设备。该发明还提供了通过交叉交换α-Ω-二乙酰基烯烃和α-Ω-二卤代烃来产生Ω-卤代烯醇的廉价途径，后者可以在传统的氢化方法下轻松转化为Ω-卤代烷醇。
• AQUEOUS EMULSION COMPOSITION
  申请人：Kuraray Co., Ltd.

  公开号：EP3318580A1

  公开（公告）日：2018-05-09

  The present invention provides an aqueous emulsion composition excellent in heat resistance, water resistance, hot water resistance, boiling water resistance, and viscosity stability and also excellent in stain resistance. The present invention relates to an aqueous emulsion composition including an aqueous emulsion (D) and a cyclic acid anhydride (E). The aqueous emulsion (D) includes a polymer (X) having an ethylenically unsaturated monomer (B), a polyvinyl alcohol resin (A), and water. At least one selected from the polyvinyl alcohol resin (A) and the polymer (X) has, in a main chain thereof, a structural unit derived from a monomer (C) represented by the following formula (I), (II), (III), or (IV). (The definitions of the symbols in the formulae are omitted.)

  本发明提供了一种耐热性、耐水性、耐热水性、耐沸水性和粘度稳定性极佳，且抗污性极佳的水性乳液组合物。本发明涉及一种水性乳液组合物，包括水性乳液（D）和环酸酐（E）。水性乳液（D）包括具有乙烯不饱和单体（B）的聚合物（X）、聚乙烯醇树脂（A）和水。聚乙烯醇树脂 (A) 和聚合物 (X) 中至少有一种在其主链中具有由下式 (I)、(II)、(III) 或 (IV) 所代表的单体 (C) 衍生的结构单元。 (式中符号的定义省略）。
• Aqueous emulsion composition
  申请人：KURARAY CO., LTD.

  公开号：US10844212B2

  公开（公告）日：2020-11-24

  The present invention provides an aqueous emulsion composition excellent in heat resistance, water resistance, hot water resistance, boiling water resistance, and viscosity stability and also excellent in stain resistance. The present invention relates to an aqueous emulsion composition including an aqueous emulsion (D) and a cyclic acid anhydride (E). The aqueous emulsion (D) includes a polymer (X) having an ethylenically unsaturated monomer (B), a polyvinyl alcohol resin (A), and water. At least one selected from the polyvinyl alcohol resin (A) and the polymer (X) has, in a main chain thereof, a structural unit derived from a monomer (C) represented by the following formula (I), (II), (III), or (IV). (The definitions of the symbols in the formulae are omitted.)

  本发明提供了一种耐热性、耐水性、耐热水性、耐沸水性和粘度稳定性极佳，且抗污性极佳的水性乳液组合物。本发明涉及一种水性乳液组合物，包括水性乳液（D）和环酸酐（E）。水性乳液（D）包括具有乙烯不饱和单体（B）的聚合物（X）、聚乙烯醇树脂（A）和水。聚乙烯醇树脂 (A) 和聚合物 (X) 中至少有一种在其主链中具有由下式 (I)、(II)、(III) 或 (IV) 所代表的单体 (C) 衍生的结构单元。 (式中符号的定义省略）。
• METATHESIS SYNTHESES OF PHEROMONES OR THEIR COMPONENTS
  申请人：Pederson, Richard L.

  公开号：EP1230207B1

  公开（公告）日：2005-06-22