6-(4-溴苯基)-4-(萘-2-基)-[2,2']联吡啶 | 1059707-02-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 6-(4-溴苯基)-4-(萘-2-基)-[2,2']联吡啶
• 英文名称: 6-(4-bromophenyl)-4-(naphthalen-2-yl)-[2,2']bipyridine
• 英文别名: 6-(4-Bromophenyl)-4-naphthalen-2-yl-[2,2']bipyridine；2-(4-bromophenyl)-4-naphthalen-2-yl-6-pyridin-2-ylpyridine
• CAS: 1059707-02-6
• 化学式: C₂₆H₁₇BrN₂
• 分子量: 437.338
• InChiKey: BYSRLHBHSCCTFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  29
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-(4-溴苯基)-4-(萘-2-基)-[2,2']联吡啶 、 5H-吡啶并[3,2-b]吲哚 在 铜 potassium carbonate 作用下， 以 十二烷 、 二甲基亚砜 为溶剂， 反应 19.0h， 以34%的产率得到6-[4-(5H-pyrido[3,2-b]indol-5-yl)phenyl]-4-(naphthalen-2-yl)-[2,2']bipyridine
  参考文献：
  名称：

  EP2128159

  摘要：

  公开号：
• 作为产物：
  描述：

  2-乙酰基吡啶 、 1-(2-(4-bromophenyl)-2-oxoethyl)pyridin-1-ium iodide 、 2-萘甲醛 在 sodium hydroxide 、 ammonium acetate 作用下， 以 甲醇 为溶剂， 反应 48.0h， 生成 6-(4-溴苯基)-4-(萘-2-基)-[2,2']联吡啶
  参考文献：
  名称：

  EP2128159

  摘要：

  公开号：

文献信息

• COMPOUND WHEREIN SUBSTITUTED BIPYRIDYL GROUP IS CONNECTED WITH PYRIDOINDOLE RING STRUCTURE THROUGH PHENYLENE GROUP, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yokoyama Norimasa

  公开号：US20100123388A1

  公开（公告）日：2010-05-20

  Objects of the present invention are to provide an organic compound having excellent properties, which is excellent in electron-injection/transport performances, has hole-blocking ability and is highly stable in a thin-film state, as a material for an organic electroluminescence device having a high efficiency and a high durability, and to provide an organic electroluminescence device having a high efficiency and a high durability using the compound. The invention relates to a compound having a substituted bipyridyl group and a pyridoindole ring structure connected with each other through a phenylene group, which is represented by the general formula (1), and an organic EL device comprising a pair of electrodes and at least one organic layer interposed between the electrodes, wherein the compound is used as a constituent material for the at least one organic layer.

  本发明的目的是提供一种具有优异性能的有机化合物，具有优异的电子注入/传输性能，具有阻挡空穴的能力，并在薄膜状态下高度稳定，作为高效和高耐久性的有机电致发光器件的材料，并提供使用该化合物的高效和高耐久性的有机电致发光器件。本发明涉及一种通过苯基连接的取代双吡啶基团和吡啶并吲哚环结构连接的化合物，其通式表示为（1），以及包括一对电极和至少一个有机层的有机EL器件，其中该化合物被用作至少一个有机层的组成材料。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yokoyama Norimasa

  公开号：US20110073852A1

  公开（公告）日：2011-03-31

  A problem of the invention is to provide an organic EL device having a high efficiency, a low driving voltage and a long life, by combining various materials for organic EL device, which are excellent in an injection or transportation performance of holes or electrons, and in stability and durability in a thin film, so as to enable the respective materials to effectively reveal their characteristics. The invention relates to an organic electroluminescent device including at least an anode electrode, a hole-injecting layer, a hole-transporting layer, an emitting layer, an electron-transporting layer and a cathode electrode in this order, in which the hole-injecting layer contains an arylamine compound having, in its molecule, a structure in which three or more triphenylamine structures are connected through a single bond or a hetero atom-free divalent group; and the hole-transporting layer contains an arylamine compound having two triphenylamine structures in its molecule.

  该发明的问题是通过结合对有机EL器件非常优秀的电子空穴注入或输运性能以及在薄膜中的稳定性和耐久性的各种材料，从而使各种材料能够有效地显示其特性，提供一种具有高效率、低驱动电压和长寿命的有机EL器件。该发明涉及一种有机电致发光器件，包括至少一个阳极电极、一个注孔层、一个输运孔层、一个发射层、一个输运电子层和一个阴极电极，其中注孔层包含一种芳基胺化合物，其分子中通过单键或异原子自由二价基连接三个或更多个三苯胺结构的结构；输运孔层包含一种芳基胺化合物，其分子中有两个三苯胺结构。
• Organic electroluminescent device
  申请人：Yokoyama Norimasa

  公开号：US08771841B2

  公开（公告）日：2014-07-08

  A problem of the invention is to provide an organic EL device having a high efficiency, a low driving voltage and a long life, by combining various materials for organic EL device, which are excellent in an injection or transportation performance of holes or electrons, and in stability and durability in a thin film, so as to enable the respective materials to effectively reveal their characteristics. The invention relates to an organic electroluminescent device including at least an anode electrode, a hole-injecting layer, a hole-transporting layer, an emitting layer, an electron-transporting layer and a cathode electrode in this order, in which the hole-injecting layer contains an arylamine compound having, in its molecule, a structure in which three or more triphenylamine structures are connected through a single bond or a hetero atom-free divalent group; and the hole-transporting layer contains an arylamine compound having two triphenylamine structures in its molecule.

  本发明的问题是通过组合各种在有机EL器件中具有孔或电子注入或传输性能、稳定性和耐久性的优秀材料，使各种材料有效地展现其特性，提供一种具有高效率、低驱动电压和长寿命的有机EL器件。本发明涉及一种有机电致发光器件，包括至少依次设置的阳极电极、孔注入层、孔传输层、发光层、电子传输层和阴极电极，其中孔注入层包含一种芳基胺化合物，其分子中通过单键或无杂原子的二价基团连接三个或更多的三苯胺结构；孔传输层包含一种芳基胺化合物，其分子中有两个三苯胺结构。
• Compound wherein substituted bipyridyl group is connected with pyridoindole ring structure through phenylene group, and organic electroluminescent device
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：US08252431B2

  公开（公告）日：2012-08-28

  An organic compound is provided having excellent electron-injection/transport performance, hole-blocking ability, and high stability in a thin-film state. An organic electroluminescence device having a high efficiency and a high durability is provided, using the compound. The compound has a substituted bipyridyl group and a pyridoindole ring structure connected with each other through a phenylene group, is of formula (1). The organic EL device has a pair of electrodes and at least one organic layer interposed between the electrodes, wherein the compound is a constituent material for an organic layer therein.

  提供了一种具有优异的电子注入/输运性能、阻挡空穴能力和在薄膜状态下高稳定性的有机化合物。使用该化合物，提供了一种具有高效率和高耐久性的有机电致发光器件。该化合物具有一个取代的联吡啶基团和一个通过苯基连接在一起的吡啶并吲哚环结构，其化学式为（1）。有机EL器件具有一对电极和至少一个夹在电极之间的有机层，其中该化合物是有机层的组分材料之一。
• ARYLAMINE COMPOUND USEFUL IN AN ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：US20140039221A1

  公开（公告）日：2014-02-06

  A problem of the invention is to provide an organic EL device having a high efficiency, a low driving voltage and a long life, by combining various materials for organic EL device, which are excellent in an injection or transportation performance of holes or electrons, and in stability and durability in a thin film, so as to enable the respective materials to effectively reveal their characteristics. The invention relates to an organic electroluminescent device including at least an anode electrode, a hole-injecting layer, a hole-transporting layer, an emitting layer, an electron-transporting layer and a cathode electrode in this order, in which the hole-injecting layer contains an arylamine compound having, in its molecule, a structure in which three or more triphenylamine structures are connected through a single bond or a hetero atom-free divalent group; and the hole-transporting layer contains an arylamine compound having two triphenylamine structures in its molecule.

  本发明的问题是通过组合对有机EL器件具有注入或输运电子空穴的优异材料，以及在薄膜中稳定耐久的材料，从而使各种材料有效地展现其特性，提供一种具有高效率、低驱动电压和长寿命的有机EL器件。本发明涉及一种有机电致发光器件，包括至少依次设置的阳极电极、注入空穴层、输运空穴层、发射层、输运电子层和阴极电极，其中注入空穴层包含一种芳基胺化合物，其分子中通过单键或无杂原子双价基团连接三个或更多个三苯胺结构，而输运空穴层包含一种芳基胺化合物，其分子中有两个三苯胺结构。