bis[6-bromo-N-(2-ethylhexyl)carbazole-3-yl] | 946489-41-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: bis[6-bromo-N-(2-ethylhexyl)carbazole-3-yl]
• 英文别名: 3-Bromo-6-[6-bromo-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazole；3-bromo-6-[6-bromo-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazole
• CAS: 946489-41-4
• 化学式: C₄₀H₄₆Br₂N₂
• 分子量: 714.627
• InChiKey: VXBWTUAJGARKRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.9
• 重原子数：
  44
• 可旋转键数：
  13
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis[6-bromo-N-(2-ethylhexyl)carbazole-3-yl] 、 咔唑 在 铜 、 potassium carbonate 作用下， 以 硝基苯 为溶剂， 反应 40.0h， 以78%的产率得到3-Carbazol-9-yl-6-[6-carbazol-9-yl-9-(2-ethylhexyl)carbazol-3-yl]-9-(2-ethylhexyl)carbazole
  参考文献：
  名称：

  Synthesis and characterization of high Tg carbazole-based amorphous hole-transporting materials for organic light-emitting devices

  摘要：

  Novel hole-transporting materials based on carbazole dendrimers, namely G1CBC and G2CBC were synthesized and characterized. They are thermally stable with high glass transition temperatures (T-g) up to 245 degrees C and exhibit chemically-stable redox processes. Double-layer green OLEDs using these materials as the hole-transporting layer (HTL) with the device configuration of ITO/HTL/Alq3/LiF:Al emit brightly (lambda(em) 522-534 nm) from the Alq3 layer with a maximum luminance and low turn-on voltage of 15,890 cd/m(2) and 3.0 V. respectively. Their ability as HTLs in terms of device performance is comparable to the common hole-transporter N,N'-diphenyl-N,N'-bis(1-naphthyl)-(1,1'-biphenyl)-4,4'-diamine (NPB), however their thermal properties were far greater than both NPB and N,N'-bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine (TPD). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.07.002
• 作为产物：
  描述：

  9-(2-乙基己基)咔唑 在 N-溴代丁二酰亚胺(NBS) 、 三氯化铁 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 生成 bis[6-bromo-N-(2-ethylhexyl)carbazole-3-yl]
  参考文献：
  名称：

  Alternating Copolymers ofN-(2-Ethylhexyl)-Carbazole Derivatives with Aniline Units: Synthesis and Properties

  摘要：

  DOI：

  10.1080/15421400600932272