cis-2,3-bis(hydroxymethyl)bicyclo[2.2.2]-octane | 65942-08-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: cis-2,3-bis(hydroxymethyl)bicyclo[2.2.2]-octane
• 英文别名: cis-2,3-Bis-hydroxymethyl-bicyclo[2.2.2]octan；[(2S,3R)-3-(hydroxymethyl)-2-bicyclo[2.2.2]octanyl]methanol
• CAS: 65942-08-7
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: CPIZOXNOIVZVGA-OXYCZDQYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cis-2,3-bis(hydroxymethyl)bicyclo[2.2.2]-octane 生成 (2S,6R)-4-Oxa-tricyclo[5.2.2.0^2,6]undecan-3-one
  参考文献：
  名称：

  LOK, K. P.;JAKOVAC, I. J.;JONES, J. B., J. AMER. CHEM. SOC., 1985, 107, N 8, 2521-2526

  摘要：

  DOI：
• 作为产物：
  描述：

  meso-endo-tetrahydro-4,7-ethanoisobenzofuran-1,3-dione 在 lithium aluminium tetrahydride 、 镍 、 对甲苯磺酸 作用下， 生成 cis-2,3-bis(hydroxymethyl)bicyclo[2.2.2]-octane
  参考文献：
  名称：

  Cyclic Dienes. XIX. 2,3-Dimethylenebicyclo[2.2.2]octane¹

  摘要：

  DOI：

  10.1021/ja01563a046

文献信息

• Catalytic asymmetric oxidative lactonizations of meso-diols using a chiral iridium complex
  作者：Takeyuki Suzuki、Kenji Morita、Yoshimi Matsuo、Kunio Hiroi

  DOI：10.1016/s0040-4039(03)00228-4

  日期：2003.3

  A chiral amino alcohol/Ir complex catalyzes the asymmetric oxidative lactonizations of meso-diols to give the corresponding lactones in up to 81% ee.

  手性氨基醇/ Ir配合物催化内消旋二醇的不对称氧化内酯化反应，得到相应的内酯，其内酯含量高达81％ee。
• Preparation and Physical Properties of Sulfur Compounds Related to Petroleum. VI. endo-4,7-Methano-cis-2-thiahydrindan and endo-4,7-Ethano-cis-2-thiahydrindan
  作者：STANLEY F. BIRCH、NEVILLE J. HUNTER、DAVID T. McALLAN

  DOI：10.1021/jo01115a012

  日期：1956.9
• Pirsch, Monatshefte fur Chemie, 1957, vol. 88, p. 578,585
  作者：Pirsch

  DOI：——

  日期：——
• SACRIFICIAL POLYMER COMPOSITIONS INCLUDING POLYCARBONATES HAVING REPEAT UNITS DERIVED FROM STEREOSPECIFIC POLYCYCLIC 2,3-DIOL MONOMERS
  申请人：Sumitomo Bakelite Co.,Ltd.

  公开号：EP2601238B1

  公开（公告）日：2015-10-07
• Sacrificial Polymer Compositions Including Polycarbonates Having Repeat Units Derived from Stereospecific Polycyclic 2,3-Diol Monomers
  申请人：Bell Andrew

  公开号：US20120031556A1

  公开（公告）日：2012-02-09

  Embodiments according to the present invention relate to sacrificial polymer compositions that include polycarbonate polymers having repeat units derived from stereospecific polycyclic 2,3-diol monomers. The sacrificial polymer compositions also include an acid generator that is selected from at least one photoacid generator and/or at least one thermal acid generator. In addition, embodiments according to the present invention relate to a method of forming a structure that includes a three-dimensional space interposed between a substrate and an overcoat layer, and a method of temporarily bonding first and second substrates together, which make use of the polycarbonate polymers.