1-Butyloxy-cyclohexen | 24159-57-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-Butyloxy-cyclohexen
• 英文别名: 1-Butoxycyclohexene
• CAS: 24159-57-7
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: VCGVJLPFNCZECQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-Butyloxy-cyclohexen 、 丙烯醛 生成 8A-butoxy-4a,5,6,7,8,8a-hexahydro-4H-chromene
  参考文献：
  名称：

  The 1,4-Addition of Vinyl Ethers to α,β-Unsaturated Carbonyl Compounds

  摘要：

  DOI：

  10.1021/ja01163a076
• 作为产物：
  描述：

  对甲苯磺酸 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1-Butyloxy-cyclohexen
  参考文献：
  名称：

  Johannissijan; Akunijan, 1930, # 5, p. 245

  摘要：

  DOI：

文献信息

• Non-Cryogenic, Ammonia-Free Reduction of Aryl Compounds
  申请人：University of Pittsburgh - Of the Commonwealth System of Higher Education

  公开号：US20220089508A1

  公开（公告）日：2022-03-24

  A method of reducing an aromatic ring or a cyclic, allylic ether in a compound includes preparing a reaction mixture including a compound including an aromatic moiety or a cyclic, allylic ether moiety, an alkali metal, and either ethylenediamine, diethylenetriamine, triethylenetetramine, or a combination thereof, in an ether solvent; and reacting the reaction mixture at from −20° C. to 30° C. for a time sufficient to reduce a double bond in the aromatic moiety to a single bond or to reduce the cyclic, allylic ether moiety.

  在化合物中减少芳香环或环状烯丙基醚的方法包括准备反应混合物，其中包括含有芳香基团或环状烯丙基醚基团的化合物，一种碱金属，以及乙二胺、二乙二胺、三乙二胺或其组合物之一，在醚溶剂中；并将反应混合物在-20°C至30°C的温度下反应一段足够时间，以将芳香基团中的双键还原为单键，或减少环状烯丙基醚基团。
• Process for the production of secondary alkoxy-1-alkenes
  申请人：Creanova Inc.

  公开号：EP1022266A1

  公开（公告）日：2000-07-26

  The present invention relates to a general synthesis for producing secondaryalkoxy-1-alkenes in commercial quantities in good yields by reacting cyclic and acyclic ketones and the corresponding alcohol with a secondary alkyl orthoformate ester in the presence of an acid catalyst, Lewis acids, and recovering the product as a liquid of high purity.

  本发明涉及一种通用合成方法，通过在酸催化剂、路易斯酸存在下，使环酮和无环酮及相应的醇与仲烷基原甲酸酯反应，并以高纯度液体形式回收产物，从而以良好的收率生产出商品量的仲烷氧基-1-烯烃。
• ANTIFOULING COATING COMPOSITION
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3284783A1

  公开（公告）日：2018-02-21

  A resin composition, formed to have a polymer (A) containing at least one monomer-derived structural unit having the structure represented by formula (1), (2) or (3) below, and after the resin composition is stored at 40°C for 30 days, the decomposition rate of the structure represented by formula (1), (2) or (3) in the polymer (A) is 20% or lower.

  一种树脂组合物，含有至少一种单体衍生结构单元的聚合物（A），该单体衍生结构单元具有下式（1）、（2）或（3）所代表的结构，且该树脂组合物在 40°C 下储存 30 天后，聚合物（A）中式（1）、（2）或（3）所代表结构的分解率为 20% 或更低。
• (METH)ACRYLIC COPOLYMER, POLYMER SOLUTION, POLYMER-CONTAINING COMPOSITION, ANTIFOULING COATING COMPOSITION, AND METHOD FOR PRODUCING (METH)ACRYLIC COPOLYMER
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3354667A1

  公开（公告）日：2018-08-01

  First embodiment of a (meth)acrylic copolymer in the present invention includes following: a (meth)acrylic copolymer having at least one kind of constitutional unit selected from the group consisting of a constitutional unit (A1) having at least one kind of structure (I) selected from the group consisting of structures represented by the following formula (1), formula (2), or formula (3) and a constitutional unit (A2) having a triorganosilyloxycarbonyl group and a constitutional unit (B) derived from a macromonomer (b): (where, X represents -O-, -S-, or -NR14-, R14 represents a hydrogen atom or an alkyl group, R1 and R2 each represent a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, R3 and R5 each represent an alkyl group having from 1 to 20 carbon atoms, a cycloalkyl group, or an aryl group, and R4 and R6 each represent an alkylene group having from 1 to 10 carbon atoms).

  本发明中(甲基)丙烯酸共聚物的第一种实施方式包括：一种(甲基)丙烯酸共聚物，其至少具有一种结构单元，该结构单元选自具有至少一种结构(I)的结构单元(A1)，该结构单元选自由式(1)、式(2)或式(3)代表的结构组成的组，以及具有三有机硅氧基羰基的结构单元(A2)和由大单体(b)衍生的结构单元(B)： (其中，X 代表-O-、-S-或-NR14-，R14 代表氢原子或烷基，R1 和 R2 分别代表氢原子或具有 1 至 10 个碳原子的烷基，R3 和 R5 分别代表具有 1 至 20 个碳原子的烷基、环烷基或芳基，R4 和 R6 分别代表具有 1 至 10 个碳原子的亚烷基）。
• (METH)ACRYLIC COPOLYMER, METHOD FOR PRODUCING SAME, RESIN COMPOSITION AND ANTIFOULING PAINT COMPOSITION
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3604364A1

  公开（公告）日：2020-02-05

  A (meth)acrylic copolymer of the present invention includes a constituent unit (B) derived from a polysiloxane block-containing polymerizable monomer (b) represented by Formula (b1). In Formula (b1), R30 represents a hydrogen atom or a methyl group, a represents an integer of 2 to 5, b represents a number of 0 to 50, c represents an integer of 0 to 18, d represents a number of 1 to 1000, e represents a number of 1 to 80, R31 to R39 each represents an alkyl group, an alkoxy group, a phenyl group, a substituted phenyl group, a phenoxy group, or a substituted phenoxy group.

  本发明的(甲基)丙烯酸共聚物包括由式(b1)代表的含聚硅氧烷嵌段可聚合单体(b)衍生的组成单元(B)。在式(b1)中，R30 代表氢原子或甲基，a 代表 2 至 5 的整数，b 代表 0 至 50 的整数，c 代表 0 至 18 的整数，d 代表 1 至 1000 的整数，e 代表 1 至 80 的整数，R31 至 R39 各自代表烷基、烷氧基、苯基、取代苯基、苯氧基或取代苯氧基。