5-Amino-hexan-2-ol | 344240-80-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-Amino-hexan-2-ol
• 英文别名: 5-Amino-2-hexanol；5-aminohexan-2-ol
• CAS: 344240-80-8
• 化学式: C₆H₁₅NO
• mdl: MFCD08454490
• 分子量: 117.191
• InChiKey: XHKYHXSLZPTQLZ-UHFFFAOYSA-N

物化性质

• 沸点：
  182.7±23.0 °C(Predicted)
• 密度：
  0.904±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  46.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (1-甲基戊基)氢过氧化物 在 lithium aluminium tetrahydride 、 copper(II) azide 、 iron(II) sulfate 作用下， 以 水 、 溶剂黄146 、 乙腈 为溶剂， 生成 5-Amino-hexan-2-ol
  参考文献：
  名称：

  在铜盐存在下，亚铁离子诱导的烷基氢过氧化物分解而使δ-碳原子官能化

  摘要：

  在亚铜离子在卤化铜或假卤化物的存在下诱导的烷基氢过氧化物的分解中，实现了分子内功能化，配体从铜盐转移到δ-碳原子。

  DOI：

  10.1016/s0040-4039(00)87708-4

文献信息

• [EN] PROCESS FOR PRODUCING ISOCYANATES<br/>[FR] PROCÉDÉ DE PRODUCTION D'ISOCYANATES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2011130032A1

  公开（公告）日：2011-10-20

  The invention relates a process for producing isocyanates comprising the steps of a) providing an azolide and optionally a solvent, and b) adding an acid at a temperature below about 40C. The invention also relates to the isocyanate obtainable by such a process.

  该发明涉及一种生产异氰酸酯的方法，包括以下步骤：a)提供一种氮杂环酯和可选的溶剂，b)在约40摄氏度以下的温度下加入酸。该发明还涉及通过这种方法获得的异氰酸酯。
• Process for producing isocyanates
  申请人：3M Innovative Properties Company

  公开号：EP2377847A1

  公开（公告）日：2011-10-19

  The invention relates a process for producing isocyanates comprising the steps of a) providing an azolide and optionally a solvent, and b) adding an acid at a temperature below about 40°C. The invention also relates to the isocyanate obtainable by such a process.

  该发明涉及一种生产异氰酸酯的方法，包括以下步骤：a)提供一种环氧酮酯和可选的溶剂，b)在低于约40°C的温度下加入酸。该发明还涉及通过这种方法获得的异氰酸酯。
• PROCESS FOR PRODUCING ISOCYANATES
  申请人：Steiger Wolf

  公开号：US20130023694A1

  公开（公告）日：2013-01-24

  The invention relates a process for producing isocyanates comprising the steps of a) providing an azolide and optionally a solvent, and b) adding an acid at a temperature below about 40 C. The invention also relates to the isocyanate obtainable by such a process.

  该发明涉及一种制备异氰酸酯的过程，包括以下步骤：a）提供一个氮杂酚盐和可选的溶剂，b）在低于约40℃的温度下加入酸。该发明还涉及由这种过程获得的异氰酸酯。
• Textile materials, methods of manufacture and compositions for use therein
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0241127A2

  公开（公告）日：1987-10-14

  Textile materials having improved physical properties comprise woven and/or non-woven fiber assemblies, the fibers of which are bound to a polymer composition containing polymerized carboxylic acid ester monomers and pendant functional groups attached to a polymer backbone and having the formula: in which R1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano. Such polymers markedly increase wet and dry strengths and shape retention of textile materials, and they improve other physical properties without the necessity of employing formaldehyde-releasing monomers, such as the N-methylolamides, or cross-linking agents. Methods for producing such textile materials by applying solutions or dispersions of the described polymers to fiber assemblies are also provided. Aqueous dispersions of these polymers are particularly useful forthe manufacture of loose-weaves, knits and non-wovens.

  具有更好物理性能的纺织材料包括机织和/或无纺布纤维组件，其纤维与聚合物组合物结合，该聚合物组合物含有聚合羧酸酯单体和连接到聚合物主干上的悬垂官能团，其结构式如下： 其中 R1 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基。这种聚合物能显著提高纺织材料的干湿强度和形状保持力，并能改善其他物理性能，而无需使用释放甲醛的单体（如 N-甲基酰胺）或交联剂。此外，还提供了通过将所述聚合物的溶液或分散体应用于纤维组件来生产此类纺织材料的方法。这些聚合物的水性分散体尤其适用于生产松织、针织和无纺布。
• Pressure sensitive adhesives and manufactured articles
  申请人：UNION OIL COMPANY OF CALIFORNIA

  公开号：EP0244997A2

  公开（公告）日：1987-11-11

  Normally tacky, pressure sensitive adhesive compositions comprise one or more polymers having a Tg of about 0° C. or less containing at least about 40 weight percent polymerized, olefinically unsaturated carboxylic acid esters monomers and pendant functional groups attached to a polymer backbone and having the formula: in which R₁ is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano. Such polymers have markedly improved cohesive strength (shear holding value) with little or no detriment to adhesive tack or adhesion (peel resistance), and these improvements are realized without the necessity of incorporating cross-linking monomers such as N-methylol­amides or other cross-linking agents. Pressure sensitive adhesives, water-based emulsions containing such polymers and adhesive articles having at least a portion of one surface thereof coated with such adhesive are also provided.

  通常具有粘性的压敏粘合剂组合物由一种或多种聚合物组成，其 Tg 约为 0°C 或更低，含有至少约 40 重量百分比的聚合烯烃不饱和羧酸酯单体和连接到聚合物骨架上的悬挂官能团，并具有以下式子： 其中 R₁ 是长度至少为 3 个原子的二价有机基，X 是有机酰基或氰基。这种聚合物的内聚强度（剪切保持值）显著提高，而对粘合剂的粘性或附着力（抗剥离性）几乎没有影响，而且无需加入交联单体（如 N-甲基酰胺或其他交联剂）即可实现这些改进。此外，还提供了压敏型粘合剂、含有此类聚合物的水基乳液以及至少有一部分表面涂有此类粘合剂的粘合物品。