3-iodo-9-(4-biphenylyl)carbazole | 894791-47-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-iodo-9-(4-biphenylyl)carbazole
• 英文别名: 9H-Carbazole, 9-[1,1'-biphenyl]-4-yl-3-iodo-；3-iodo-9-(4-phenylphenyl)carbazole
• CAS: 894791-47-0
• 化学式: C₂₄H₁₆IN
• 分子量: 445.302
• InChiKey: KLKDSRMOQUCFFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-iodo-9-(4-biphenylyl)carbazole 、 9-(4-biphenyl)-N-phenyl-9H-carbazol-3-amine 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 xylene 为溶剂， 反应 3.0h， 以19%的产率得到3-{N-[9-(4-biphenylyl)carbazole-3-yl]-N-phenylamino}-9-(4-biphenylyl)carbazole
  参考文献：
  名称：

  WO2006/70912

  摘要：

  公开号：
• 作为产物：
  描述：

  9-(4-苯基苯基)咔唑 在 N-碘代丁二酰亚胺 作用下， 以 溶剂黄146 、 乙酸乙酯 、 甲苯 为溶剂， 反应 24.0h， 以98%的产率得到3-iodo-9-(4-biphenylyl)carbazole
  参考文献：
  名称：

  WO2006/70912

  摘要：

  公开号：

文献信息

• Carbazole derivative, light-emitting element material obtained by using carbazole derivative, light-emitting element, and electronic device
  申请人：Nakashima Harue

  公开号：US20070031701A1

  公开（公告）日：2007-02-08

  It is an object to provide a carbazole derivative which is useful as a raw material for forming a light-emitting element material which has resistance to repeated oxidation reactions. It is an object to provide a carbazole derivative represented by a general formula (G-1). In the general formula (G-1), each of Ar 1 and Ar 2 represents an aryl group having 1 to 12 carbon atoms such as phenyl, biphenyl, or naphthyl. Also, R 1 represents any one of hydrogen, an alkyl group having 1 to 4 carbon atoms such as methyl, ethyl, or tert-butyl, and an aryl group having 6 to 12 carbon atoms such as phenyl, biphenyl, or naphthyl. Further, the aryl group may have a substituent, or is not required to have a substituent.

  本发明旨在提供一种卡巴唑衍生物，其可用作形成耐受重复氧化反应的发光元素材料的原材料。本发明旨在提供一种由通式（G-1）表示的卡巴唑衍生物。在通式（G-1）中，Ar1和Ar2各自表示具有1至12个碳原子的芳基基团，例如苯基、联苯基或萘基。此外，R1表示氢、具有1至4个碳原子的烷基基团，例如甲基、乙基或叔丁基，以及具有6至12个碳原子的芳基基团，例如苯基、联苯基或萘基。此外，芳基基团可以具有取代基，也可以不需要取代基。
• Carbazole Derivative, and Light-Emitting Element and Light-Emitting Device Using the Carbzole Derivative
  申请人：Nakashima Harue

  公开号：US20080254318A1

  公开（公告）日：2008-10-16

  The present invention provides a material having excellent hole injecting and hole transporting properties. Moreover, the present invention provides a light-emitting element and a light-emitting device using the material having excellent hole injecting and hole transporting properties. The present invention provides a carbazole derivative represented by the general formula (1). By applying the carbazole derivative of the present invention to a light-emitting element or a light-emitting device, a lower driving voltage, enhanced emission efficiency, a longer lifetime and enhanced reliability of the light-emitting element or the light-emitting device can be realized.

  本发明提供了一种具有优异的孔注入和孔传输性能的材料。此外，本发明还提供了一种使用具有优异的孔注入和孔传输性能的材料的发光元件和发光装置。本发明提供了一种由通式（1）表示的咔唑衍生物。通过将本发明的咔唑衍生物应用于发光元件或发光装置中，可以实现更低的驱动电压、增强的发射效率、更长的寿命和增强的可靠性。
• COMPOSITE MATERIAL, AND LIGHT EMITTING ELEMENT AND LIGHT EMITTING DEVICE USING THE COMPOSITE MATERIAL
  申请人：Iwaki Yuji

  公开号：US20090309093A1

  公开（公告）日：2009-12-17

  An object is to provide a light emitting element with low drive voltage which contains an organic compound and an inorganic compound. One feature of a light emitting element of the present invention is to include a layer containing a light emitting material between a pair of electrodes, in which the layer containing a light emitting material has a layer containing a carbazole derivative represented by General Formula (1) and an inorganic compound which exhibits an electron accepting property to the carbazole derivative represented by General Formula (1). With such a structure, the inorganic compound accepts electrons from the carbazole derivative, carriers are generated internally, and a drive voltage of the light emitting element can be reduced.

  本发明的目的是提供一种具有低驱动电压的发光元件，其中包含有机化合物和无机化合物。本发明的一种发光元件的特点是在一对电极之间包含一层含有发光材料的层，其中该层包含一个由通用公式（1）表示的咔唑衍生物和一种对咔唑衍生物具有电子受体性质的无机化合物。通过这样的结构，无机化合物从咔唑衍生物中接受电子，内部产生载流子，发光元件的驱动电压可以降低。
• Composite material, and light emitting element and light emitting device using the composite material
  申请人：Iwaki Yuji

  公开号：US08405070B2

  公开（公告）日：2013-03-26

  An object is to provide a light emitting element with low drive voltage which contains an organic compound and an inorganic compound. One feature of a light emitting element of the present invention is to include a layer containing a light emitting material between a pair of electrodes, in which the layer containing a light emitting material has a layer containing a carbazole derivative represented by General Formula (1) and an inorganic compound which exhibits an electron accepting property to the carbazole derivative represented by General Formula (1). With such a structure, the inorganic compound accepts electrons from the carbazole derivative, carriers are generated internally, and a drive voltage of the light emitting element can be reduced.

  本发明的目标是提供一种具有低驱动电压的发光元件，其中包含有机化合物和无机化合物。本发明的一种发光元件的特点是，在一对电极之间包含一层含有发光材料的层，其中该层包含一个由通式（1）表示的咔唑衍生物和一种对该咔唑衍生物具有电子受体性质的无机化合物。通过这样的结构，无机化合物从咔唑衍生物中接受电子，内部产生载流子，发光元件的驱动电压可以降低。
• Amine-based compound, organic light emitting device comprising the amine-based compound, and flat panel display device including the organic light emitting device
  申请人：Samsung Mobile Display Co., Ltd.

  公开号：EP2149555A1

  公开（公告）日：2010-02-03

  The invention is directed to an amine-based compound represented by Formula 1, an organic light emitting device with an organic film including the same, and a flat panel display device including the organic light emitting device.

  本发明涉及一种由式 1 表示的胺基化合物、一种带有包括其在内的有机薄膜的有机发光器件，以及一种包括该有机发光器件的平板显示器件。