2,6-Bis-(2,2,3,3,4,4,5,5,5-nonafluoro-pentanoyl)-cyclohexanone | 672956-77-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,6-Bis-(2,2,3,3,4,4,5,5,5-nonafluoro-pentanoyl)-cyclohexanone
• 英文别名: 2,6-Bis(2,2,3,3,4,4,5,5,5-nonafluoropentanoyl)cyclohexan-1-one；2,6-bis(2,2,3,3,4,4,5,5,5-nonafluoropentanoyl)cyclohexan-1-one
• CAS: 672956-77-3
• 化学式: C₁₆H₈F₁₈O₃
• 分子量: 590.209
• InChiKey: UPVZEVFUBVSPCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  37
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为产物：
  描述：

  九氟戊酸甲酯 、 2-perfluoropentanoylcyclohexanone 在 lithium hydride 作用下， 以 乙二醇二甲醚 为溶剂， 生成 2,6-Bis-(2,2,3,3,4,4,5,5,5-nonafluoro-pentanoyl)-cyclohexanone
  参考文献：
  名称：

  2,4-Bridged 1,5-bis(fluoroalkyl)-1,3,5-triketones: synthesis and properties

  摘要：

  Symmetrical and unsymmetrical bis-fluoroacylcyclopentanones and cyclohexanones were synthesized. NMR data reveal that the keto-enol tautomeric equilibrium is changed markedly by the presence of a trimethylene bridge compared to an ethylene moiety. A considerable influence of the fluoroalkyl chain length was found for 2,6-(bisfluoroacyl)cyclohexanones. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(03)00164-7

文献信息

• 2,4-Bridged 1,5-bis(fluoroalkyl)-1,3,5-triketones: synthesis and properties
  作者：D.L. Chizhov、K.I. Pashkevich、G.-V. Röschenthaler

  DOI：10.1016/s0022-1139(03)00164-7

  日期：2003.10

  Symmetrical and unsymmetrical bis-fluoroacylcyclopentanones and cyclohexanones were synthesized. NMR data reveal that the keto-enol tautomeric equilibrium is changed markedly by the presence of a trimethylene bridge compared to an ethylene moiety. A considerable influence of the fluoroalkyl chain length was found for 2,6-(bisfluoroacyl)cyclohexanones. (C) 2003 Elsevier B.V. All rights reserved.