5-[4-(4-oxo-2,3,5,6-tetrahydro-1H-benzo[a]phenanthridin-5-yl)phenyl]-2,3,5,6-tetrahydro-1H-benzo[a]phenanthridin-4-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5-[4-(4-oxo-2,3,5,6-tetrahydro-1H-benzo[a]phenanthridin-5-yl)phenyl]-2,3,5,6-tetrahydro-1H-benzo[a]phenanthridin-4-one
• 化学式: C₄₀H₃₂N₂O₂
• 分子量: 572.706
• InChiKey: SLPPDUYQQHGBGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  44
• 可旋转键数：
  2
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,3-环己二酮 、 (naphthalen-1-ylimino)methylbenzylidene-naphthalen-1-amine 以 乙醇 为溶剂， 以64%的产率得到5-[4-(4-oxo-2,3,5,6-tetrahydro-1H-benzo[a]phenanthridin-5-yl)phenyl]-2,3,5,6-tetrahydro-1H-benzo[a]phenanthridin-4-one
  参考文献：
  名称：

  Reactions of Bisazomethines of the Naphtalene Series with 1,3-Diketones

  摘要：

  Bisazomethines prepared from aromatic dialdehydes and 2-naphthylamine were for the first time reacted with the following diketones: 1,3-cyclohexanedione, 5,5-dimethyl-1,3-cyclohexanedione, 5-phenyl-1,3 -cyclohexanedione, indandione, and 2,2-dimethyl-1,3-dioxane-4,6-dione was studied. The reactions with 1,3-diketones of the cyclohexane series yield benzophenanthridine derivatives. The reactions with indandione, depending on conditions, give either bisarylideneindandiones or bisdihydrobenzo[f]indenoquinoline. As evidenced by the C-13 NMR and IR spectra, in the case of biphenyl-4,4'-dicarbaldehyde bis[N-(2-naphthyl)imine] and 2,2-dimethyl-1,3-dioxane-4,6-dione, 4,4'-bis(3-oxo-1,2,3,4-tetrahydrobenzo[f]quinolin-1-yl)biphenyl is formed.

  DOI：

  10.1023/b:rugc.0000015994.57381.23