allyl Δ²-cyclopentyl ether | 63163-50-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: allyl Δ²-cyclopentyl ether
• 英文别名: allyl-cyclopent-2-enyl ether；Allyl-2-cyclopentenyl-aether；Allyl-Δ²-cyclopentenylaether；Allyl-cyclopent-2-enyl-aether；3-Prop-2-enoxycyclopentene
• CAS: 63163-50-8
• 化学式: C₈H₁₂O
• 分子量: 124.183
• InChiKey: DXYFAVKCJFPXIY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  allyl Δ²-cyclopentyl ether 在 tris(triphenylphosphine)ruthenium(II) chloride 作用下， 生成 2-(Δ²-Cyclopentenyl)-propanal
  参考文献：
  名称：

  Ruthenium(II) catalyzed rearrangement of diallyl ethers. A synthesis of .gamma.,.delta.-unsaturated aldehydes and ketones

  摘要：

  DOI：

  10.1021/jo00441a009
• 作为产物：
  描述：

  3-碘苄胺 、 烯丙醇 在 碳酸氢钠 作用下， 生成 allyl Δ²-cyclopentyl ether
  参考文献：
  名称：

  Ruthenium(II) catalyzed rearrangement of diallyl ethers. A synthesis of .gamma.,.delta.-unsaturated aldehydes and ketones

  摘要：

  DOI：

  10.1021/jo00441a009

文献信息

• Synthesis of Some Epoxy Vinyl Monomers by Epoxidation with Peracetic Acid¹
  作者：Frederick C. Frostick、Benjamin Phillips、Paul S. Starcher

  DOI：10.1021/ja01522a048

  日期：1959.7
• GHOSH SUBRATA; RAYCHAUDHURI SWADESH R.; SALOMON R. G., J. ORG. CHEM., 52,(1987) N 1, 83-90
  作者：GHOSH SUBRATA、 RAYCHAUDHURI SWADESH R.、 SALOMON R. G.

  DOI：——

  日期：——
• Zr-Catalyzed Kinetic Resolution of Aliphatic Cyclic Allylic Ethers. Carbocycles to Heterocycles by Ru- and Mo-Catalyzed Ring-Opening and Ring-Closing Metathesis
  作者：Jeffrey A. Adams、J. Gair Ford、Paul J. Stamatos、Amir H. Hoveyda

  DOI：10.1021/jo991323k

  日期：1999.12.1

  The Zr-catalyzed kinetic resolution of aliphatic allylic ethers derived from five-, six-, seven-, and eight-membered ring allylic alcohols is reported. The level of resolution efficiency varies as a function of ring size and substitution pattern of the pendant alkene. The metal-catalyzed transformation of the above unsaturated ethers to dihydrofurans is also disclosed. Seven- and eight-membered ring substrates are readily converted to furans; in the presence of 10 mol % Ru catalyst 16. In contrast, the less reactive cyclopentenol systems demand the more potent Mo-based metathesis catalyst 3. The selectivity and reactivity patterns in the Zr-catalyzed process and the Ru- or Mo-catalyzed reactions differ from the previously reported reactions of the related styrenyl ethers.
• US4134924A
  申请人：——

  公开号：US4134924A

  公开（公告）日：1979-01-16
• US4156097A
  申请人：——

  公开号：US4156097A

  公开（公告）日：1979-05-22