2-Methyl-oxirane-2-carboxylic acid oxiranylmethyl ester | 140914-84-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2-Methyl-oxirane-2-carboxylic acid oxiranylmethyl ester
• 英文别名: Oxiran-2-ylmethyl 2-methyloxirane-2-carboxylate
• CAS: 140914-84-7
• 化学式: C₇H₁₀O₄
• 分子量: 158.154
• InChiKey: DEAZWKIEKMOIGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  51.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  甲基丙烯酸烯丙酯 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 生成 2-Methyl-oxirane-2-carboxylic acid oxiranylmethyl ester
  参考文献：
  名称：

  Cock, Christian J. C. De; Keyser, Jean-Luc De; Poupaert, Jacques H., Bulletin des Societes Chimiques Belges, 1987, vol. 96, # 10, p. 783 - 786

  摘要：

  DOI：

文献信息

• [EN] MANUFACTURE OF AN EPOXYETHYL CARBOXYLATE OR GLYCIDYL CARBOXYLATE<br/>[FR] FABRICATION D'UN CARBOXYLATE D'ÉPOXYÉTHYLE OU D'UN CARBOXYLATE DE GLYCIDYLE
  申请人：MOMENTIVE SPECIALTY CHEMICALS RES S A

  公开号：WO2011095294A1

  公开（公告）日：2011-08-11

  The invention relates to a process for the manufacture of an epoxyethyl carboxylate or glycidyl carboxylate, including reacting a vinyl carboxylate or an allyl carboxylate using an oxidant and a water-soluble manganese complex in an aqueous reaction medium, and the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX3]Y, or a binuclear species of the general formula (II): [LMn(μ-X)3MnL]Yn, wherein Mn is a manganese; L is a ligand and each L is independently a polydentate ligand, each X is independently a coordinating species and each μ-X is independently a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 7.0.

  本发明涉及一种生产环氧乙基羧酸酯或环氧丙基羧酸酯的方法，包括在水相反应介质中使用氧化剂和水溶性锰配合物反应乙烯基羧酸酯或烯丙基羧酸酯，其中水溶性锰配合物包括氧化催化剂，其特征在于所述水溶性锰配合物是通式(I)的单核物种：[LMnX3]Y，或通式(II)的双核物种：[LMn(μ-X)3MnL]Yn，其中Mn是锰，L是配体，每个L独立地是多齿配体，每个X独立地是配位物种，每个μ-X独立地是桥联配位物种，Y是非配位的反离子，环氧化反应在pH为1.0至7.0的范围内进行。
• METHOD FOR PRODUCING A POROUS POLYMER STRUCTURE
  申请人：Surface Innovations Limited

  公开号：EP2734578A2

  公开（公告）日：2014-05-28
• METHOD
  申请人：Badyal Jas Pal S.

  公开号：US20140243440A1

  公开（公告）日：2014-08-28

  A method for producing a porous polymer structure involves (i) forming a polymer; (ii) subsequently contacting the polymer with a nonsolvent and inducing the formation of an emulsion in which the nonsolvent is present as the dispersed phase and the polymer as the continuous phase; and (iii) removing at least some of the nonsolvent so as to leave pores within the polymer, wherein the polymer is formed by exciting one or more molecules in an exciting medium, in particular by pulsed plasma deposition. Emulsion formation in step (ii) may be induced by or in the presence of an emulsion stabilising agent. Also provided is a porous polymer structure produced using the method, and a polymer which is impregnated with an emulsion stabilising agent, for use in the emulsion formation step of the method.
• US4388448A
  申请人：——

  公开号：US4388448A

  公开（公告）日：1983-06-14
• [EN] METHOD<br/>[FR] PROCÉDÉ
  申请人：SURFACE INNOVATIONS LTD

  公开号：WO2013011302A2

  公开（公告）日：2013-01-24

  A method for producing a porous polymer structure involves (i) forming a polymer; (ii) subsequently contacting the polymer with a nonsolvent and inducing the formation of an emulsion in which the nonsolvent is present as the dispersed phase and the polymer as the continuous phase; and (iii) removing at least some of the nonsolvent so as to leave pores within the polymer, wherein the polymer is formed by exciting one or more molecules in an exciting medium, in particular by pulsed plasma deposition. Emulsion formation in step (ii) may be induced by or in the presence of an emulsion stabilising agent. Also provided is a porous polymer structure produced using the method, and a polymer which is impregnated with an emulsion stabilising agent, for use in the emulsion formation step of the method.