6-甲基十三烷 | 13287-21-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 中文名称: 6-甲基十三烷
• 英文名称: 6-methyltridecane
• 英文别名: 6-Methyl-tridecan
• CAS: 13287-21-3
• 化学式: C₁₄H₃₀
• 分子量: 198.392
• InChiKey: SOMJQWRITYTQJL-UHFFFAOYSA-N

物化性质

• 沸点：
  145.3 °C(Press: 37 Torr)
• 密度：
  0.7641 g/cm3
• 保留指数：
  1352.6

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2901100000

反应信息

• 作为产物：
  描述：

  (Z)-2-戊基壬-2-烯醛 在 Pt/Al₂O₃ 、 氢气 作用下， 以 正己烷 为溶剂， 290.0 ℃ 、3.0 MPa 条件下， 反应 6.0h， 生成 6-甲基十三烷
  参考文献：
  名称：

  Selective conversion of castor oil derived ricinoleic acid methyl ester into jet fuel

  摘要：

  将蓖麻油酸甲酯选择性转化为喷气燃料，而不损失脂肪酸链中的碳。

  DOI：

  10.1039/c6gc00942e

文献信息

• [EN] SYNTHESIS OF HIGH CALORIC FUELS AND CHEMICALS<br/>[FR] SYNTHÈSE DE COMBUSTIBLES ET DE PRODUITS CHIMIQUES À FORT POUVOIR CALORIFIQUE
  申请人：PIONEER ENERGY

  公开号：WO2013070966A1

  公开（公告）日：2013-05-16

  In one embodiment, the present application discloses methods to selectively synthesize higher alcohols and hydrocarbons useful as fuels and industrial chemicals from syngas and biomass. Ketene and ketonization chemistry along with hydrogenation reactions are used to synthesize fuels and chemicals. In another embodiment, ketene used to form fuels and chemicals may be manufactured from acetic acid which in turn can be synthesized from synthesis gas which is produced from coal, biomass, natural gas, etc.

  在一种实施例中，本申请公开了一种从合成气和生物质中选择性合成高级醇类和烃类的方法，这些物质可用作燃料和工业化学品。酮烯和酮化学以及加氢反应被用来合成燃料和化学品。在另一种实施例中，用于形成燃料和化学品的酮烯可以从乙酸制造，而乙酸可以从煤、生物质、天然气等生产的合成气中合成。
• Landa,S. et al., Collection of Czechoslovak Chemical Communications, 1960, vol. 25, p. 1165 - 1173
  作者：Landa,S. et al.

  DOI：——

  日期：——
• Petrow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1959, p. 1091,1094;engl.Ausg.S.1053,1056
  作者：Petrow et al.

  DOI：——

  日期：——
• Landa; Mostecky, Collection of Czechoslovak Chemical Communications, 1956, vol. 21, p. 1177,1180
  作者：Landa、Mostecky

  DOI：——

  日期：——
• Dependence of Finger Flexion Force on the Posture of the Nonperforming Fingers During Key Pressing Tasks
  作者：Zong-Ming Li、Guang H. Yue

  DOI：10.1080/00222890209601951

  日期：2002.12

  The influence of different positions of the non-performing (idle) fingers on the maximal force contraction of flexion (master) fingers during key pressing tasks was investigated. Ten participants performed maximal voluntary flexion contractions with various combinations of the index, middle, ring, and little fingers while the idle fingers rested on or were lifted away from the supporting surface. The effect of idle finger posture on total finger force production of master fingers was dependent on finger combination. In general, force production by master fingers was higher when the idle fingers were lifted away from the supporting surface than when they rested on it. The average increase in total force production by master fingers caused by the lifting of idle fingers was +12.4% (from -8.3% to +30.2%). Force-production capability of individual master fingers can be facilitated (as high as 34.1%), unchanged, or depressed (as high as -29.0%) by lifting the idle fingers. The effect of idle finger posture on finger force production of master fingers led to changes in force deficit. Neural, anatomical, and mechanical factors might account for the dependence of finger flexion force of master fingers on the posture of the idle fingers.

表征谱图