4-O-Methylhexonic acid | 4132-39-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-O-Methylhexonic acid
• 英文别名: 4-O-methyl-D-gluconic acid；4-O-Methyl-D-gluconsaeure；4-O-methyl d-gluconic acid；(2R,3R,4R,5R)-2,3,5,6-tetrahydroxy-4-methoxyhexanoic acid
• CAS: 4132-39-2
• 化学式: C₇H₁₄O₇
• 分子量: 210.184
• InChiKey: JRNABBHNYINIEE-KVTDHHQDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.8
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  127
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 溴 作用下， 生成 4-O-Methylhexonic acid
  参考文献：
  名称：

  198.单甲基己糖。第一部分。假定的4-甲基葡萄糖的组成

  摘要：

  DOI：

  10.1039/jr9350000873

文献信息

• 2-C-carboxyaldoses and aldonic acids from cellobiose, maltose, and 4-O-methyl-d-glucose with 2-anthraquinone-sulfonic acid
  作者：Tapani Vuorinen

  DOI：10.1016/s0008-6215(00)90462-2

  日期：1985.9

  Abstract Cellobiose, maltose, and 4- O -methyl- d -glucose were treated with 0.1–20m m 2-anthraquinonesulfonic acid in 0.1 m sodium hydroxide at 40°. The hydroxy carboxylic acids formed were separated by ion-exchange, and analyzed by g.l.c.-m.s. as their per(trimethylsilyl) derivatives. The acidic oxidation products of cellobiose were further fractionated into aldonic acids and carboxylaldoses by ion-exchange

  摘要在0.1 m氢氧化钠中于40°C用0.1–20m m 2-蒽醌磺酸处理纤维二糖，麦芽糖和4-O-甲基-d-葡萄糖。通过离子交换分离形成的羟基羧酸，并通过glc-ms分析其全（三甲基甲硅烷基）衍生物。通过离子交换色谱将纤维二糖的酸性氧化产物进一步分馏为醛糖酸和羧醛糖。用硼氢化钠还原分离的羧基醛糖，然后在水解之前和之后通过glc-ms进行分析。糖的O-d-葡萄糖基和O-甲基取代的产物除了2-C-羧基戊糖外，还由赤藓酸，阿拉伯酸，核糖酸，葡糖酸和甘露酸组成。还原性d-葡萄糖单元的未取代产物为甲酸，乙醇酸，2-脱氧电子，
• Immune-enhancing composition comprising arabinoxylan from corn or corn processing by-product
  申请人：Shin Kwang-Soon

  公开号：US10729164B2

  公开（公告）日：2020-08-04

  The present invention relates to an immuno-enhancing composition including a corn-derived polysaccharide. The immuno-enhancing composition may be a food composition, a feed composition, or a pharmaceutical composition.

  本发明涉及一种包括玉米衍生多糖的免疫增强组合物。该免疫增强组合物可以是食品组合物、饲料组合物或药物组合物。
• IMMUNE-ENHANCING COMPOSITION COMPRISING ARABINOXYLAN FROM CORN OR CORN PROCESSING BY-PRODUCT
  申请人：KYONGGI UNIVERSITY INDUSTRY & ACADEMIA COOPERATION FOUNDATION

  公开号：US20180325156A1

  公开（公告）日：2018-11-15

  The present invention relates to an immuno-enhancing composition including a corn-derived polysaccharide. The immuno-enhancing composition may be a food composition, a feed composition, or a pharmaceutical composition.
• 198. Monomethyl hexoses. Part I. The constitution of the supposed 4-methyl glucose
  作者：John Munro、Edmund G. V. Percival

  DOI：10.1039/jr9350000873

  日期：——