bis(cyclohex-3-enyloxy)methane | 105554-11-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(cyclohex-3-enyloxy)methane
• 英文别名: Cyclohexene, 4,4'-[methylenebis(oxy)]bis-；4-(cyclohex-3-en-1-yloxymethoxy)cyclohexene
• CAS: 105554-11-8
• 化学式: C₁₃H₂₀O₂
• 分子量: 208.301
• InChiKey: ZGGKJLJWLZDMHB-UHFFFAOYSA-N

物化性质

• 沸点：
  284.9±40.0 °C(Predicted)
• 密度：
  1.01±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(氯甲氧基)乙酸乙酯 、 3-cyclohexen-1-ol 在 sodium hydroxide 、 4 A molecular sieve 、 silver carbonate 作用下， 生成 2-(cyclohex-3-enyloxymethoxy)ethanol 、 bis(cyclohex-3-enyloxy)methane
  参考文献：
  名称：

  Aitken, David J.; Alijah, Renate; Onyiriuka, Samuel O., Journal of the Chemical Society. Perkin transactions I, 1993, # 5, p. 597 - 608

  摘要：

  DOI：

文献信息

• PROCESS FOR THE EPOXIDATION OF OLEFINS
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160083360A1

  公开（公告）日：2016-03-24

  The subject invention is related to a process for the epoxidation of olefin with peroxide, comprising reacting peroxide with olefin in the presence a solvent, wherein the solvent has Hansen Solubility Parameters (HSPs) of δ T,solvent and δ H,solvent and the epoxide product has Hansen Solubility Parameters (HSPs) of δ T,product and δ H,product , and wherein: δ T,product −6≦δ T,solvent ≦δ T,product +6, and δ H,product −6≦δ H,solvent .

  该发明涉及一种过氧化物与烯烃进行环氧化反应的方法，包括在溶剂存在的情况下，将过氧化物与烯烃反应，其中溶剂具有Hansen溶解度参数（HSPs）δT，溶剂和δH，溶剂，环氧产物具有Hansen溶解度参数（HSPs）δT，产物和δH，产物，并且满足以下条件：δT，产物-6≦δT，溶剂≦δT，产物+6，以及δH，产物-6≦δH，溶剂。
• Novel reactivity of 2-(chloromethoxy)ethyl acetate
  作者：David J. Aitken、Lilias Rees、Colin J. Suckling、Hamish C.S. Wood

  DOI：10.1016/s0040-4039(00)84811-x

  日期：1986.1

  2-(Chloromethoxy)ethyl acetate reacts with alcohols in the presence of silver carbonate to produce 2-(alkoxymethoxy)ethyl acetates and bis(alkoxy)methanes. A mechanism which involves neighbouring group participation of a chloromethyl ether oxygen atom is proposed to account for the formation of the latter products.

  2-（氯甲氧基）乙酸乙酯在碳酸银的存在下与醇反应，生成2-（烷氧基甲氧基）乙酸乙酯和双（烷氧基）甲烷。提出了涉及氯甲基醚氧原子的相邻基团参与的机理以解释后者产物的形成。
• AITKEN D. J.; REES L.; SUCKLING C. J.; WOOD H. C. S., TETRAHEDRON LETT., 27,(1986) N 29, 3417-3420
  作者：AITKEN D. J.、 REES L.、 SUCKLING C. J.、 WOOD H. C. S.

  DOI：——

  日期：——
• CONTINUOUS PROCESS OF OLEFINIC EPOXIDATION BY SUPPORTED HETEROPOLY ACID
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US20160177023A1

  公开（公告）日：2016-06-23

  The subject invention is related to a continuous process of epoxidation of an olefin with supported heteropoly acid catalyst, which does not involve the use of an additive(s). The subject invention separates the products and oxides through a continuous process to reduce backmixing, thereby achieving an efficacy equal to that of a process involving the use of an additive. By excluding additives from the process, the subject invention has a lower cost, and avoids the need for additional wastewater treatment since no alkali metal or alkali earth metal compound is formed during the reaction. Moreover, the continuous process of the invention is also beneficial in industrial manufacturing.
• US9499505B2
  申请人：——

  公开号：US9499505B2

  公开（公告）日：2016-11-22