1,12-diallyloxydodecane | 144266-47-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,12-diallyloxydodecane
• 英文别名: 1,12-Bis(prop-2-enoxy)dodecane
• CAS: 144266-47-7
• 化学式: C₁₈H₃₄O₂
• 分子量: 282.467
• InChiKey: XJBUBOXYWPMMDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,12-diallyloxydodecane 在 titanium(III) chloride 、 lithium 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以62%的产率得到1,12-十二烷二醇
  参考文献：
  名称：

  Low-valent titanium : A new approach to deprotection of allyl and benzyl groups

  摘要：

  A novel method for the deprotection of allyl and benzyl derivatives of alcohols and phenols by low-valent titanium [Ti(0)] is reported. The possible mechanism is discussed.

  DOI：

  10.1016/s0040-4039(00)61209-1

文献信息

• Composition containing unsaturated silicone compounds, dental materials containing them and use thereof
  申请人：3M Deutschland GmbH

  公开号：EP1650263B1

  公开（公告）日：2013-10-23
• COMPOSITION CONTAINING UNSATURATED SILICONE COMPOUNDS, DENTAL MATERIALS CONTAINING THEM AND USE THEREOF
  申请人：Bissinger Peter

  公开号：US20100331444A1

  公开（公告）日：2010-12-30

  The invention relates to a curable composition comprising addition curable silicone component (A) having a linear siloxane backbone at least one unsaturated, non-activated side group pendant from the Si atom or atoms in the backbone, component (A) having an equivalent weight in the range of about 68 to about 1000, crosslinker component (B) comprising at least 2SiH groups, catalyst component (C) being able to catalyse the reaction between component (A) and component (B), filler component (D), wherein the equivalent weight is defined as (molecular weight of the molecule)/(number of unsaturations in the molecule).
• US7807730B2
  申请人：——

  公开号：US7807730B2

  公开（公告）日：2010-10-05
• US8143362B2
  申请人：——

  公开号：US8143362B2

  公开（公告）日：2012-03-27
• Low-valent titanium : A new approach to deprotection of allyl and benzyl groups
  作者：S.M. Kadam、S.K. Nayak、A. Banerji

  DOI：10.1016/s0040-4039(00)61209-1

  日期：1992.8

  A novel method for the deprotection of allyl and benzyl derivatives of alcohols and phenols by low-valent titanium [Ti(0)] is reported. The possible mechanism is discussed.