1-Chlor-2-methyl-1-phenyl-propen-3-saeure | 91552-10-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 1-Chlor-2-methyl-1-phenyl-propen-3-saeure
• 英文别名: 3-chloro-2-methyl-3-phenyl-acrylic acid；β-Chlor-α-methyl-zimtsaeure；3-Chlor-2-methyl-3-phenyl-acrylsaeure；3-Chloro-2-methyl-3-phenylprop-2-enoic acid；3-chloro-2-methyl-3-phenylprop-2-enoic acid
• CAS: 91552-10-2
• 化学式: C₁₀H₉ClO₂
• 分子量: 196.633
• InChiKey: GFMIDNOITJPCQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Chlor-2-methyl-1-phenyl-propen-3-saeure 在 硫酸 作用下， 生成 3-chloro-2-methyl-inden-1-one
  参考文献：
  名称：

  Simonis; Wojack, Chemische Berichte, 1937, vol. 70, p. 1837,1846

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲基-3-氧代-3-苯基丙酸乙酯 在 五氯化磷 、 三氯氧磷 作用下， 生成 1-Chlor-2-methyl-1-phenyl-propen-3-saeure 、 3-chloro-2-methyl-3-phenyl-acrylic acid ethyl ester
  参考文献：
  名称：

  Perkin; Calman, Journal of the Chemical Society, 1886, vol. 49, p. 160

  摘要：

  DOI：

文献信息

• FLUIDITY-IMPROVING AGENT, AROMATIC POLYCARBONATE RESIN COMPOSITION, AND SHAPED ARTICLE THEREOF
  申请人：Matsuoka Shinji

  公开号：US20100029855A1

  公开（公告）日：2010-02-04

  A large sized thin-walled shaped article having a complicated shape can be realized by improving fluidity at the time of shaping without deterioration of the intrinsic characteristic properties of an aromatic polycarbonate resin, namely, transparency, resistance to exfoliation of surface layer, thermal resistance, impact resistance, and chemical resistance. Specifically disclosed is a fluidity-improving agent containing 0.5 to 99.5 parts by mass of a polymer (A) which is obtained by polymerizing a monomer mixture (a) containing 0.5 to 99% by mass of (a1) an aromatic vinyl monomer, 0.5 to 99% by mass of (a2) a phenyl(meth)acrylate or a phenyl(meth)acrylate having a substituent in a phenyl group, and 0.5 to 5% by mass of (a3) a vinyl monomer having a functional group (X), and 0.5 to 99.5 parts by mass of a polymer (B) which is obtained by polymerizing a monomer mixture (b) comprising (b1) a phenyl (meth)acrylate or a phenyl (meth)acrylate having a substituent in a phenyl group with a compound having a functional group (Y) capable of reacting with the functional group (X), with the proviso that a total of the polymer (A) and the polymer (B) is 100 parts by mass.
• Polyorganosiloxane-Containing Graft Copolymer, Resin Composition, and Molded Article
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：US20150267048A1

  公开（公告）日：2015-09-24

  A graft copolymer capable of providing impact resistance, flame retardance, and color rendering properties to a thermoplastic resin is described. The graft copolymer contains a polyorganosiloxane, and is obtained by graft-polymerizing vinyl monomers including a (meth)acrylate ester (b 1 ) having an alkyl group or an aromatic group and an aromatic vinyl monomer (b 2 ) on a polyorganosiloxane-based rubber. The graft copolymer has a volume average particle diameter of 200-2000 nm, and contains 0.1-69 mass % of polyorganosiloxane. A thermoplastic resin composition is also described, containing a thermoplastic resin (A), the graft copolymer, a fluorine resin (C) and a flame retardant (D). A molded article is also described, which is obtained by molding the thermoplastic resin composition.
• US8202943B2
  申请人：——

  公开号：US8202943B2

  公开（公告）日：2012-06-19
• US8729205B2
  申请人：——

  公开号：US8729205B2

  公开（公告）日：2014-05-20
• US9527997B2
  申请人：——

  公开号：US9527997B2

  公开（公告）日：2016-12-27