O-β-D-Galactopyranosyl-(1->4)-O-β-D-glucopyranosyl-(1->6)-O-<β-D-galactopyranosyl-(1->4)>-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1->3)-O-β-D-galactopyranosyl-(1->4)-D-glucopyranose

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: O-β-D-Galactopyranosyl-(1->4)-O-β-D-glucopyranosyl-(1->6)-O-<β-D-galactopyranosyl-(1->4)>-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1->3)-O-β-D-galactopyranosyl-(1->4)-D-glucopyranose
• 英文别名: Gal(b1-4)Glc(b1-6)[Gal(b1-4)]GlcNAc(b1-3)Gal(b1-4)Glc；N-[(2S,3R,4R,5S,6R)-2-[(2R,3S,4S,5R,6S)-3,5-dihydroxy-2-(hydroxymethyl)-6-[(2R,3S,4R,5R)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-4-yl]oxy-6-[[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]oxymethyl]-4-hydroxy-5-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-3-yl]acetamide
• 化学式: C₃₈H₆₅NO₃₁
• 分子量: 1031.92
• InChiKey: CIHCIELQPRKLJY-ZUEBOGACSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -12.2
• 重原子数：
  70
• 可旋转键数：
  17
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  515
• 氢给体数：
  20
• 氢受体数：
  31

反应信息

• 作为产物：
  描述：

  O-(2,3,4,6-Tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-O-(2,3,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->6)-O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)>-O-(2-acetamido-3-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-acetyl-β... 在 ammonium hydroxide 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 以97%的产率得到O-β-D-Galactopyranosyl-(1->4)-O-β-D-glucopyranosyl-(1->6)-O-<β-D-galactopyranosyl-(1->4)>-O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1->3)-O-β-D-galactopyranosyl-(1->4)-D-glucopyranose
  参考文献：
  名称：

  Koeman, Franciscus A. W.; Meissner, Johannes W. G.; Ritter, Hendrik R. P. van, Journal of Carbohydrate Chemistry, 1994, vol. 13, # 1, p. 1 - 26

  摘要：

  DOI：

文献信息

• Koeman, Franciscus A. W.; Meissner, Johannes W. G.; Ritter, Hendrik R. P. van, Journal of Carbohydrate Chemistry, 1994, vol. 13, # 1, p. 1 - 26
  作者：Koeman, Franciscus A. W.、Meissner, Johannes W. G.、Ritter, Hendrik R. P. van、Kamerling, Johannis P.、Vliegenthart, Johannes F. G.

  DOI：——

  日期：——