Dichlorocopper;quinolin-8-amine | 14751-45-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Dichlorocopper;quinolin-8-amine
• CAS: 14751-45-2
• 化学式: C₉H₈Cl₂CuN₂
• 分子量: 278.628
• InChiKey: SAIIAAMWGXXEDU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.19
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.9
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  以 not given 为溶剂， 生成 Dichlorocopper;quinolin-8-amine
  参考文献：
  名称：

  Thermal investigation of cobalt, nickel and copper complexes with 8-aminoquinoline

  摘要：

  Complexes of Co(II), Ni(II) and Cu(II) with 8-aminoquinoline were prepared and characterized, and their thermal behaviour and decomposition pathways were studied. The thermal stabilities are discussed in terms of ionic radii, crystal field splitting energy and steric hindrance. The effective roles of the counter-ions (Cl- and NO3-) on the decomposition temperatures and the final products were also clarified. The energies of activation (E-a) and the orders of some decomposition reactions were determined. Light is shed on the nature of the interaction of the water of crystallization and the polymorphic transformation phenomenon.

  DOI：

  10.1007/bf01983443

文献信息

• Thermal investigation of cobalt, nickel and copper complexes with 8-aminoquinoline
  作者：A. M. Donia、H. A. El-Boraey

  DOI：10.1007/bf01983443

  日期：1997.6

  Complexes of Co(II), Ni(II) and Cu(II) with 8-aminoquinoline were prepared and characterized, and their thermal behaviour and decomposition pathways were studied. The thermal stabilities are discussed in terms of ionic radii, crystal field splitting energy and steric hindrance. The effective roles of the counter-ions (Cl- and NO3-) on the decomposition temperatures and the final products were also clarified. The energies of activation (E-a) and the orders of some decomposition reactions were determined. Light is shed on the nature of the interaction of the water of crystallization and the polymorphic transformation phenomenon.